重金属离子的电化学检测研究进展

引用本文: 吴倩, 毕洪梅, 韩晓军. 重金属离子的电化学检测研究进展[J]. 分析化学, 2021, 49(3): 330-340. doi: 10.19756/j.issn.0253-3820.201352 shu

Citation: WU Qian, BI Hong-Mei, HAN Xiao-Jun. Research Progress of Electrochemical Detection of Heavy Metal Ions[J]. Chinese Journal of Analytical Chemistry, 2021, 49(3): 330-340. doi: 10.19756/j.issn.0253-3820.201352 shu

重金属离子的电化学检测研究进展

吴倩 ^1, ,
毕洪梅 ^{2,
,} ,
韩晓军 ^{1,
,}

1.
哈尔滨工业大学化学与化工学院, 城市水资源与水环境国家重点实验室, 哈尔滨 150001;
2.
广东石油化工学院生物与食品工程学院, 茂名 525000

通讯作者: 毕洪梅,E-mail:hongmei_bi@126.com; 韩晓军,E-mail:hanxiaojun@hit.edu.cn

基金项目:
国家重点研发计划项目（No.2016YFC0401104）、哈尔滨市杰出青年基金项目（No.2017RAYXJ024）、城市水资源与水环境国家重点实验室（No.2020DX03）、广东省自然科学基金项目（No.2020A1515010522）和广东省普通高校特色创新项目（No.2019KTSCX109）资助。

摘要: 重金属离子对人体健康和生态系统都具有极大危害，建立快速、便捷、准确、灵敏的重金属离子检测技术，对于保护人类健康及维护生态系统平衡具有重要的理论意义和应用价值。电化学分析方法在检测重金属离子方面具有灵敏度高、分析速度快、设备简单、便于携带等优点。对工作电极进行适当修饰是提高检测灵敏度的有效途径。无机材料、有机材料和生物材料等被广泛用于修饰电极，并在重金属离子等污染物的检测方面取得了很大发展。本文对近年来有关重金属离子的电化学检测研究进展进行了综述，着重介绍了电极的修饰材料如无机材料、有机材料及生物材料等的研究进展，对电极检测离子的线性范围和灵敏度的影响，以及各种修饰材料的优点、局限性及发展前景等做了简要阐述。

关键词:

English

Research Progress of Electrochemical Detection of Heavy Metal Ions

WU Qian ^1, ,
BI Hong-Mei ^{2,
,} ,
HAN Xiao-Jun ^{1,
,}

1.
State Key tate Key Laboratory of Urban Water Resource and Environment, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, China;
2.
College of Biological and Food Engineering, Guangdong University of Petrochemical Technology, Maoming 525000, China

Corresponding author: BI Hong-Mei, ; HAN Xiao-Jun,

Received Date: 16 June 2020
Revised Date: 26 December 2020
Fund Project:
National Key R&D Program of China (No. 2016YFC0401104), the Harbin Distinguished Young Scholars Fund (No. 2017RAYXJ024), State Key Laboratory of Urban Water Resource and Environment (No. 2020DX03), the Guangdong Provincial Natural Science Foundation (No. 2020A1515101522) and the Characteristic Innovation Projects of Universities in Guangdong Province (No. 2019KTSCX109).

Abstract: Heavy metal ions are extremely harmful to human health and ecosystems. The establishment of fast, convenient, accurate and sensitive detection techniques for heavy metal ion has important theoretical and application significance for protecting human health and maintaining ecosystem balance. The electrochemical analytical method has many advantages such as high sensitivity, fast analysis speed, simple equipment, and portability in detecting heavy metal ions. The appropriate modification of the working electrode is an effective way to improve the detection sensitivity. A variety of organic and inorganic materials have been widely used to modify the working electrode for this purpose with great progresses. This article reviews recent progresses on electrochemical detection of heavy metal ions, focusing on the influence of the electrode modification of material (inorganic materials, organic materials and biological materials) on the ion detection range and sensitivity. The advantages, limitations and prospects of various modified materials are also briefly described.

Key words:

1. [1]
  LI P H, YANG M, LI Y X, SONG Z Y, LIU J H, LIN C H, ZENG J, HUANG X J. Anal. Chem., 2020, 92(8):6128-6135.
2. [2]
  SINGH S, VAISHNAV J K, MUKHERJEE T K. ACS Appl. Nano Mater., 2020, 3(4):3604-3612.
3. [3]
  KUMAR N, HU Y, SINGH S, MIZAIKOFF B. Analyst, 2018, 143:359-373.
4. [4]
  ZHANG Y, XIAO J Y, ZHU Y, TIAN L J, WANG W K, ZHU T T, LI W W, YU H Q. Anal. Chem., 2020, 92(5):3990-3997.
5. [5]
  FERREIRA S L C, BBZERRA M A, SANTOS A S, SANTOS W N, RUI L G. TrAC-Trends Anal. Chem., 2017, 100:1-6.
6. [6]
  GAO W, NYEIN H Y, SHAHPAR Z, FAHAD H M, CHEN K, EMAMINEJAD S, GAO Y, TAI L C, OTA H, WU E, BULLOCK J, ZENG Y, LIEN D H, JAVEY A. ACS Sens., 2016, 1(7):866-874.
7. [7]
  FUKAYA Y, TSUKAMOTO A, KURODA K, OHNO H. Chem. Commun., 2011, 47(7):1994-1996.
8. [8]
  PASSOS M L C, SARAIVA M L. Measurement, 2019, 135:896-904.
9. [9]
  LIU D R, PAN X Y, MU W, LI C, HAN X J. Anal. Sci., 2019, 35:367-370.
10. [10]
  KOKAB T, SHAH A, NISAR J, KHAN A M, KHAN S B, SHAH A H. ACS Omega, 2020, 5(17):10123-10132.
11. [11]
  LIU X X, YAO Y, YING Y B, PING J F. TrAC-Trends Anal. Chem., 2019, 115:187-202.
12. [12]
  ECONOMOU A. Sensors, 2018, 18(4):1032.
13. [13]
  SHOUB S A B, YUSOF N A, HAJIAN R. Sens. Mater., 2017, 29(5):555-565.
14. [14]
  LEE Y G, JANG A. J. Coastal Res., 2017, 79:45-49.
15. [15]
  FANG Y S, WANG H Y, WANG L S, WANG J F. Biosens. Bioelectron., 2014, 51:310-316.
16. [16]
  WAN H, SUN Q Y, LI H B, SUN F, HU N, WANG P. Sens. Actuators, B, 2015, 209:336-342.
17. [17]
  DIMOVASILIS P A, PRODROMIDIS M I. Anal. Lett., 2016, 49(7):979-989.
18. [18]
  RIMAN D, JIROVSKY D, HRBAC J, PRODROMIDIS M I. Electrochem. Commun., 2015, 50:20-23.
19. [19]
  FINŠGAR M, PETOVAR B, VODOPIVEC K. Microchem. J., 2019, 145:676-685.
20. [20]
  LU Z W, ZHANG J J, DAI W L, LIN X N, YE J P, YE J S. Microchim. Acta, 2017, 184(12):4731-4740.
21. [21]
  NS A K, SIDDARAMANNA A, MALINGAPPA P. J. Environ. Chem. Eng., 2018, 6(6):6939-6946.
22. [22]
  LEE P M, CHEN Z, LI L, LIU E J. Electrochim. Acta, 2015, 174:207-214.
23. [23]
  NIU P F, FERNÁNDEZ-SÁNCHEZ C, GICH M, AYORA C, ROIG A. Electrochim. Acta, 2015, 165:155-161.
24. [24]
  PÉREZ-RÁFOLS C, SERRANO N, DÍAZ-CRUZ J M, ARIÑO C, ESTEBAN M. Anal. Chim. Acta, 2016, 916:17-23.
25. [25]
  PEREZ-RAFOLS C, BASTOS-ARRIETA J, SERRANO N, DIAZ-CRUZ J M, ARINO C, DE PABLO J, ESTEBAN M. Sensors, 2017, 17(6):1458.
26. [26]
  MATJAŽ F, DAVID M, UROŠ M, TINA M. Sensors-Basel., 2018, 18(11):3976.
27. [27]
  SHANG J, ZHAO M, QU H, LI H, GAO R, CHEN S. J. Electroanal. Chem., 2019, 855:113624.
28. [28]
  LI S S, ZHOW W Y, JIANG M, GUO Z, LIU J H, ZHANG L, HUANG X J. Anal. Chem., 2018, 90(7):4569-4577.
29. [29]
  ATAPOUR M, AMOABEDINY G, AHMADZADEH-RAJI M. RSC Adv., 2019, 9(16):8882-8893.
30. [30]
  DESHMUKH S, BANERJEE D, BHATTACHARYA G, FISHLOCK S J, BARMAN A, MCLAUGHLIN J, ROY S S. ACS Appl. Nano Mater., 2020, 3(5):4084-4090.
31. [31]
  MOLINERO-ABAD B, IZQUIERDOD, PÉREZ L, ESCUDERO I, ARCOS-MARTÍNEZ M J. Talanta, 2018, 182:549-557.
32. [32]
  MISHRA R K, NAWAZ M H, HAYAT A, NAWAZ M A H, SHARMA V, MARTY J L. Sens. Actuators, B, 2017, 247:366-373.
33. [33]
  ZHANG W, XU Y, XIAO B Z. Anal. Methods, 2017, 9(30):4418-4424.
34. [34]
  RUENGPIRASIRI P, PUNRAT E, CHAILAPAKUL O, CHUANUWATANAKUL S. Electroanalysis, 2017, 29(4):1022-1030.
35. [35]
  WU L D, FU X C, LIU H, LI J C, SONG Y. Anal. Chim. Acta, 2014, 851:43-48.
36. [36]
  YU L Y, ZHANG Q, YANG B R, XU Q, XU Q, HU X Y. Sens. Actuators, B, 2018, 259:540-551.
37. [37]
  LU M, DENG Y, LUO Y, LV J, LI T, XU J, CHEN S W, WANG J. Anal. Chem., 2019, 91:888-895.
38. [38]
  CEROVAC S, GUZSVÁNY V, KÓNYA Z, ASHRAFI AM, ŠVANCARA I, RONEVIC' S, KUKOVECZ A, DALMACIJA B, VYTAS K. Talanta, 2015, 134:640-664.
39. [39]
  NIU P, FERNÁNDEZ-SÁNCHEZ C, GICH M, NAVARRO-HERNÁNDEZ C, FANJUL-BOLADO P, ROIG A. Microchim. Acta, 2016, 183(2):617-623.
40. [40]
  PUY-LLOVERA J, PÉREZ-RÁFOLS C, SERRANO N, DÍAZ-CRUZ JM, ARIÑO C, ESTEBAN M. Talanta, 2017, 175:501-506.
41. [41]
  YAO Y, WU H, PING J. Food Chem., 2019, 274:8-15.
42. [42]
  CHAMJANGALI M A, KOUHESTANI H, MASDAROLOMOOR F, DANESHINEJAD H. Sens. Actuators, B, 2015, 216:384-393.
43. [43]
  BUI M P N, LI C A, HAN K N, PHAM X H, SEONG G H. Analyst, 2012, 137(8):1888-1894.
44. [44]
  KUMAR S S, SANGILIMUTHU S N. Mater. Sci. Eng., 2019, 98(5):657-665.
45. [45]
  SHUAI H, LEI Y J. Int. J. Electrochem. Sci., 2016, 11(9):7430-7439.
46. [46]
  ZHANG X, ZHANG Y, DING D, ZHAO J, LIU J, YANG W, QU K. Microchem. J., 2016, 126:280-286.
47. [47]
  SAGHIRI S, EBRAHIMI M, BEYRAMABADI S A. Int. J. Pharma Res. Health Sci., 2016, 5(8):326-331.
48. [48]
  ES'HAGHI Z, HEIDARI T, MAZLOOMI E. Electrochim. Acta, 2014, 147:279-287.
49. [49]
  WARDAK C S. Sens. Actuators, B, 2015, 209:131-137.
50. [50]
  WANG Z Q, WANG H, ZHANG Z H, LIU G. Sens. Actuators, B, 2014, 199:7-14.
51. [51]
  BAGHERI H, AFKHAMI A, KHOSHSAFAR H, REZAEI M, SABOUNCHEI SJ, SARLAKIFAR M. Anal. Chim. Acta, 2015, 870:56-66.
52. [52]
  CHAIYO S, MEHMETI E, ŽAGAR K, SIANGPROH W, CHAILAPAKUL O, KALCHER K. Anal. Chim. Acta, 2016, 918:26-34.
53. [53]
  WANG H, ZHAO G, YIN Y, WANG Z, LIU G. Int. J. Electrochem. Sci., 2017, 12(6):4702-4713.
54. [54]
  WANG H, ZHAO G, YIN Y, WANG Z, LIU G. Sensors, 2018, 18(1):6.
55. [55]
  HE Y, MA L, ZHOU L Y, LIU G H, JIANG Y J, GAO J. Nanomaterials, 2020, 10(5):866.
56. [56]
  ZHU X L, LIU B C, LI L, WU L S, CHEN S J, HUANG L, YANG J K, LIANG S, XIAO K K, HU J P, HOU H J. Microchim. Acta, 2019, 186(12):776.
57. [57]
  BHANJANA G, DILBAGHI N, KUMAR R, UMAR A, KUMAR S. Electrochim. Acta, 2015, 169:97-102.
58. [58]
  DEVADAS B, SIVAKUMAR M, CHEN S M, RAJKUMAR M, HU C C. Electroanalysis, 2015, 27(11):2629-2636.
59. [59]
  OYAGI M O, ONYATTA J O, KAMAU G N, GUTO P M. Int. J. Electrochem. Sci., 2016, 11(5):3852-3861.
60. [60]
  WANG N, ZHAO W, SHEN Z Y, SUN S J, DAI H X, MA H Y, LIN M. Sens. Actuators, B, 2020, 304:127286.
61. [61]
  MARÍA-HORMIGOS R, GISMERA M J, PROCOPIO J R, SEVILLA M T. J. Electroanal. Chem., 2016, 767:114-122.
62. [62]
  YI W, HE Z, FEI J, HE X. RSC Adv., 2019, 9:17325-17334.
63. [63]
  ZHAO G, YIN Y, WANG H, LIU G, WANG Z Q. Electrochim. Acta, 2016, 220:267-275.
64. [64]
  KARADAS N, OZKAN S A. Talanta, 2014, 119:248-254.
65. [65]
  PÉREZ-RÁFOLS C, SERRANO N, MANUEL D J, ARIÑO C, ESTEBAN M. Talanta, 2015, 144:569-573.
66. [66]
  PÉREZ-RÁFOLS C, SERRANO N, DÍAZ-CRUZ J M, ARIÑO C, ESTEBAN M. Sens. Actuators, B, 2017, 250:393-401.
67. [67]
  SERRANO N, GONZÁLEZ-CALABUIG A, DEL VALLE M. Talanta, 2015, 138:130-137.
68. [68]
  RODRIGUEZ-ALBELO L M, LOPEZ-MAYA E, HAMAD S, RUIZ-SALVADOR A R, CALERO S, NAVARRO J A. Nat. Commun., 2017, 8:14457.
69. [69]
  TAN Y C, ZENG H C. Nat. Commun., 2018, 9:4326.
70. [70]
  LIU T Z, HU R, ZHANG X, ZHANG K L, LIU Y, ZHANG X B, BAI R Y, LI D, YANG Y H. Anal. Chem., 2016, 88:12516-12523.
71. [71]
  HUA Y, LV X, CAI Y, LIU H, LI S, WAN Y, WANG H. Chem. Commun., 2019, 55:1271-1274.
72. [72]
  HU R, ZHANG X, CHI K N, YANG T, YANG Y. ACS Appl. Mater. Interfaces, 2020, 12(27):30770-30778.
73. [73]
  YE W, LI Y P, WANG JT, LI B, CUI YJ, YANG Y, QIAN G D. J. Solid State Chem., 2020, 281:121032.
74. [74]
  ZHANG Y, LI C, SU Y, MU W, HANX J. Inorg. Chem. Commun., 2020, 111:107672.
75. [75]
  HAN X J, LI C, YONG D M. Sens. Mater., 2019, 31:4103-4111.
76. [76]
  LI C, ZHAO X, HAN X J. Anal. Methods, 2018, 10:4945-4950.
77. [77]
  SAIDUR M R, AZIZ A R A, BASIRUNW J. Biosens. Bioelectron., 2017, 90:125-139.
78. [78]
  TORTOLINI C, BOLLELLA P, ANTONELLI M L, ANTIOCHIA R, MAZZEI F, FAVEROG. Biosens. Bioelectron., 2015, 67:524-531.
79. [79]
  LIU S, WEI W, SUN X, WANG L. Biosens. Bioelectron., 2016, 83:33-38.
80. [80]
  LUO J Y, JIANG D F, LIU T, PENG J M, CHU Z Y, JIN W Q. Biosens. Bioelectron., 2018, 104:1-7.
81. [81]
  GUO Z, LI D D, LUO X K, LI Y H, ZHAO Q N, LI M M, ZHAO Y T, SUN T S, MA C. J. Colloid Interface Sci., 2017, 490:11-22.
82. [82]
  HWANG J, PATHAK P, WANG X C, RODRIGUEZ K L, PARK J, CHO H J, LEE W H. Sens. Actuators, B, 2019, 294:89-97.
83. [83]
  HWANG J, PATHAK P, WANG X C, RODRIGUEZ K L, CHO H J, LEE W H. Micromachines, 2019, 10(8):511.
84. [84]
  SHI J J, ZHU J C, ZHAO M, WANG Y, YANG P, HE J. Talanta, 2018, 183:237-244.

扫一扫看文章

计量

PDF下载量: 33
文章访问数: 1316
HTML全文浏览量: 304

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

重金属离子的电化学检测研究进展

通讯作者: 毕洪梅,E-mail:hongmei_bi@126.com; 韩晓军,E-mail:hanxiaojun@hit.edu.cn

English

Research Progress of Electrochemical Detection of Heavy Metal Ions

Corresponding author: BI Hong-Mei, ; HAN Xiao-Jun,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

重金属离子的电化学检测研究进展

通讯作者: 毕洪梅,E-mail:hongmei_bi@126.com; 韩晓军,E-mail:hanxiaojun@hit.edu.cn

English

Research Progress of Electrochemical Detection of Heavy Metal Ions

Corresponding author: BI Hong-Mei, ; HAN Xiao-Jun,

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

计量

文章相关

通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

CCS Chemistry：颜徐州、鲍哲南：你的皮肤可能是一片SPMs