基于高效液相色谱-气相色谱联用技术的矿物油分析研究进展

武彦文 李冰宁 刘玲玲 欧阳杰

引用本文: 武彦文, 李冰宁, 刘玲玲, 欧阳杰. 基于高效液相色谱-气相色谱联用技术的矿物油分析研究进展[J]. 分析化学, 2021, 49(3): 341-349. doi: 10.19756/j.issn.0253-3820.201134 shu
Citation:  WU Yan-Wen,  LI Bing-Ning,  LIU Ling-Ling,  OUYANG Jie. Research Progress of Analysis of Mineral Oil Hydrocarbons Using On-Line High Performance Liquid Chromatography Coupled with Gas Chromatography[J]. Chinese Journal of Analytical Chemistry, 2021, 49(3): 341-349. doi: 10.19756/j.issn.0253-3820.201134 shu

基于高效液相色谱-气相色谱联用技术的矿物油分析研究进展

    通讯作者: 武彦文,E-mail:wu_yanwen@163.com
  • 基金项目:

    北京市自然科学基金项目(No.2182020)和北京市科学技术研究院改革与发展经费培育类项目(No.PY2020JC38)资助。

摘要: 近年来,利用高效液相色谱-气相色谱联用技术(HPLC-GC)分析矿物油的研究发展迅速。矿物油源于石油与合成油,是涵盖一定碳数范围的碳氢化合物,主要分为烷烃和芳烃两大类。矿物油可通过多种途径迁移至食品和环境中,影响人类健康,然而其分析检测面临较大挑战。HPLC-GC (配备氢火焰离子化检测器)通过将净化、分离与检测相结合,很好地解决了矿物油分析中的选择性和灵敏度等问题。该技术的核心是通过保留间隙、Y形件接口和溶剂蒸气排出实现了GC大体积进样,将常规HPLC的洗脱流分全部转移至GC分析,将矿物油的分析灵敏度提高了两个数量级以上;同时避免了分析过程的污染引入,保证了分析的重现性和准确度。本文详细阐述了HPLC-GC的发展历程以及HPLC与GC分析条件的相互匹配,评述了基于HPLC-GC联用技术的干扰物去除与矿物油富集方法,并对HPLC-GC在矿物油分析中应用前景和发展趋势进行了展望。

English


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  • 收稿日期:  2020-03-16
  • 修回日期:  2020-09-22
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