QuEChERS-高效液相色谱-串联质谱法同时测定芝麻油中7种农药残留

徐芷怡 陈梦婷 侯锡爱 刘丹

引用本文: 徐芷怡,  陈梦婷,  侯锡爱,  刘丹. QuEChERS-高效液相色谱-串联质谱法同时测定芝麻油中7种农药残留[J]. 分析化学, 2020, 48(7): 928-936. doi: 10.19756/j.issn.0253-3820.191644 shu
Citation:  XU Zhi-Yi,  CHEN Meng-Ting,  HOU Xi-Ai,  LIU Dan. Simultaneous Determination of Seven Pesticide Residues in Sesame Oil Using QuEChERS-High Performance Liquid Chromatography-Tandem Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, 2020, 48(7): 928-936. doi: 10.19756/j.issn.0253-3820.191644 shu

QuEChERS-高效液相色谱-串联质谱法同时测定芝麻油中7种农药残留

摘要: 采用分散固相萃取QuEChERS前处理方法,结合高效液相色谱-串联质谱(HPLC-MS/MS),建立了精甲霜灵、丁草胺、乙草胺、异丙甲草胺、氟环唑、嘧菌酯、高效氟吡甲禾灵7种常用于油料作物的农药在芝麻油中的多残留分析方法。针对芝麻油基质的复杂性,对目标农药在芝麻油基质中的提取溶剂、净化剂种类进行筛选及优化,最终确定用10 mL乙腈涡旋提取一次,组合60 mg N-丙基乙二胺(PSA)和20 mg石墨化碳黑(GCB)去除芝麻油中脂肪、色素等干扰物,并利用HPLC-MS/MS进行定量分析。芝麻油中7种目标农药在0.001~10 mg/L浓度范围内呈良好线性关系,线性相关系数R2>0.99;7种目标农药在芝麻油中3个添加水平的平均回收率在86.9%~106.3%之间,RSD<5.2%,准确度、精密度和灵敏度均满足农药残留检测的要求。本研究建立的快速、简便、环保的方法适用于芝麻油中目标残留农药定量分析。

English


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  • 收稿日期:  2019-11-01
  • 修回日期:  2020-05-10
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