QuEChERS-高效液相色谱-串联质谱法同时测定芝麻油中7种农药残留

徐芷怡 陈梦婷 侯锡爱 刘丹

引用本文: 徐芷怡,  陈梦婷,  侯锡爱,  刘丹. QuEChERS-高效液相色谱-串联质谱法同时测定芝麻油中7种农药残留[J]. 分析化学, 2020, 48(7): 928-936. doi: 10.19756/j.issn.0253-3820.191644 shu
Citation:  XU Zhi-Yi,  CHEN Meng-Ting,  HOU Xi-Ai,  LIU Dan. Simultaneous Determination of Seven Pesticide Residues in Sesame Oil Using QuEChERS-High Performance Liquid Chromatography-Tandem Mass Spectrometry[J]. Chinese Journal of Analytical Chemistry, 2020, 48(7): 928-936. doi: 10.19756/j.issn.0253-3820.191644 shu

QuEChERS-高效液相色谱-串联质谱法同时测定芝麻油中7种农药残留

摘要: 采用分散固相萃取QuEChERS前处理方法,结合高效液相色谱-串联质谱(HPLC-MS/MS),建立了精甲霜灵、丁草胺、乙草胺、异丙甲草胺、氟环唑、嘧菌酯、高效氟吡甲禾灵7种常用于油料作物的农药在芝麻油中的多残留分析方法。针对芝麻油基质的复杂性,对目标农药在芝麻油基质中的提取溶剂、净化剂种类进行筛选及优化,最终确定用10 mL乙腈涡旋提取一次,组合60 mg N-丙基乙二胺(PSA)和20 mg石墨化碳黑(GCB)去除芝麻油中脂肪、色素等干扰物,并利用HPLC-MS/MS进行定量分析。芝麻油中7种目标农药在0.001~10 mg/L浓度范围内呈良好线性关系,线性相关系数R2>0.99;7种目标农药在芝麻油中3个添加水平的平均回收率在86.9%~106.3%之间,RSD<5.2%,准确度、精密度和灵敏度均满足农药残留检测的要求。本研究建立的快速、简便、环保的方法适用于芝麻油中目标残留农药定量分析。

English


    1. [1]

      LI Na.China Grain Economy,2008,(3):17-18 李娜.中国粮食经济,2008,(3):17-18

    2. [2]

      Moreno-González D, Huertas-Pérez J F, García-Campaña A M, Gámiz-Gracia L. Talanta,2014,128:299-304

    3. [3]

      Parrilla Vázquez P, Hakme E, Uclés S, Cutillas V, Martínez Galera M, Mughari A R, Fernández-Alba A R. J. Chromatogr. A, 2016,1463:20-31

    4. [4]

      LIU Bing-Ge, WANG Xue-De, HUANG Wei, HU Hua-Li. Journal of Henan University of Technology(Natural Science Edition),2013,34(6):32-36 刘兵戈, 汪学德, 黄维, 胡华丽.河南工业大学学报(自然科学版), 2013, 34(6):32-36

    5. [5]

      Manirakiza P, Covaci A, Schepens P. Chromatographia,2000,52(11-12):787-790

    6. [6]

      Gebreegzi Y T, Foster G D, Khan S U. J.Agric. Food Chem.,2000,48(11):5165-5168

    7. [7]

      GUO Lan, XIE Ming-Yong, YAN Ai-Ping, WAN Yi-Qun. Journal of Instrumental Analysis,2009,28(1):67-71 郭岚, 谢明勇, 鄢爱平, 万益群.分析测试学报, 2009,28(1):67-71

    8. [8]

      Farajzadeh M A, Feriduni B, Mogaddam M R A. J. Sep. Sci.,2015,38(6):1002-1009

    9. [9]

      Zayats M F, Leschev S M, Zayats M A. Anal. Chem. Res.,2015,3:37-45

    10. [10]

      Zayats M F, Leschev S M, Zayats M A. Food Addit. Contam. A,2016,33(8):1337-1345

    11. [11]

      SHI Xiao-Mei, ZHANG Qing, YANG Yong-Tan, YANG You-You. Journal of the Chinese Cereals and Oils Association,2017,32(10):156-162 史晓梅, 章晴, 杨永坛, 杨悠悠.中国粮油学报, 2017,32(10):156-162

    12. [12]

      ZHANG Yun, CHEN Jun-Yu, CHEN Ze-Yu, ZHANG Xin-Ren. Journal of the Chinese Cereals and Oils Association,2017,32(8):118-122 张云, 陈俊玉, 陈泽宇, 张信仁.中国粮油学报, 2017,32(8):118-122

    13. [13]

      Yagüe C, Bayarri S, Conchello P, Lázaro R, Pérez-Arquillué C, Herrera A, Ariño A. J. Agric. Food Chem.,2005,53(13):5105-5109

    14. [14]

      Yu X, Ang H C, Yang H, Zheng C, Zhang Y. Food Control,2017, 74:112-120

    15. [15]

      GAO Yao-Hua, TENG Shuang, SONG Wei-De, LIU Bing. Soybean Science,2018,37(2):284-294 高尧华, 滕爽, 宋卫得, 刘冰.大豆科学, 2018,37(2):284-294

    16. [16]

      ZHANG Fan, ZHANG Ying, HUANG Zhi-Qiang, BAI Shan, XI Hui, CAI Qing-Yun. Journal of Instrumental Analysis, 2019, 38(4):411-416 张帆, 张莹, 黄志强, 白珊, 席慧, 蔡青云.分析测试学报, 2019,38(4):411-416

    17. [17]

      XU Juan, WANG Lan, HUANG Hua-Jun, CHEN Jie, CHEN Wen-Rui, XIANG Da-Peng. Chinese Journal of Chromatography,2015,33(3):242-249 徐娟, 王岚, 黄华军, 陈捷, 陈文锐, 相大鹏.色谱, 2015,33(3):242-249

    18. [18]

      Dias J V, Cutillas V, Lozano A, Pizzutti I R, Fernandez-Alba A R. J. Chromatogr. A,2016,1462:8-18

    19. [19]

      SHEN Wei-Jian, WU Bin, WANG Hong, WANG Xiao-Yan, YU Ke-Yao, LU Hui-Yuan, HU Guo-Shen, Li Jing-Jing. Chinese Journal of Chromatography,2019,37(1):27-31 沈伟健, 吴斌, 王红, 王晓研, 余可垚, 陆慧媛, 胡国绅, 李静静.色谱, 2019,37(1):27-31

    20. [20]

      Katarzyna M, Katarzyna J, Wojciech P. J. Anal. Methods Chem.,2018,2018:1-8

    21. [21]

      Li J, Liu D, Wu T, Zhao W, Zhou Z, Wang P. Food Chem.,2014,151:47-52

    22. [22]

      Tuzimski T, Rejczak T. Food Chem.,2016,190:71-79

    23. [23]

      Rejczak T, Tuzimski T. Food Anal. Methods,2017,10(11):3572-3588

    24. [24]

      Fang Y, Tian W, Pei F, Li P, Shao X L, Fan Y. Food Chem.,2017, 229:347-353

    25. [25]

      Hua J, Fayyaz A, Song H, Tufail M R, Gai Y. Quality Assur. Safety Crops Foods,2019,11(6):511-516

    26. [26]

      SHEN Xiang-Zhen, ZHANG Hong-Xia, WANG Yan-Li, CHEN Ke-Yun, SUN Yu-Lin, LIU Yan-Ming. Journal of the Chinese Cereals and Oils Association,2019,34(9):125-129 沈祥震, 张红霞, 王艳丽, 陈克云, 孙嵛林, 刘艳明.中国粮油学报, 2019,34(9):125-129

    27. [27]

      MA Shuang, CHENG Ni-Li, MO Min, Tan Si-Yun, XIE Ya-Qin, CAO Shu-Rui. China Oils and Fats,2019, 44(9):86-90, 94 马双, 程妮郦, 莫敏, 谭斯匀, 谢娅芹, 曹淑瑞.中国油脂, 2019,44(9):86-90, 94

    28. [28]

      GB 2763-2019, National Food Safety Standard-Maximum Residue Limits for Pesticides in Food. National Standards of the People's Republic of China食品安全国家标准-食品中农药最大残留限量. 中华人民共和国国家标准. GB 2763-2019

    29. [29]

      GB/T 14929.2-1994, Method for Determination of Aldicarb Residues in Peanut, Cottonseed Oil and Peanut Oil. National Standards of the People's Republic of China花生仁、棉籽油、花生油中涕灭威残留量测定方法. 中华人民共和国国家标准. GB/T 14929.2-1994

    30. [30]

      GB/T 5009.143-2003, Determination of Amitraz Residues in Vegetables, Fruits, Edible Oil. National Standards of the People's Republic of China蔬菜、水果、食用油中双甲脒残留量的测定. 中华人民共和国国家标准. GB/T 5009.143-2003

    31. [31]

      GB/T 5009.172-2003, Determination of Trifluralin Residues in Soybean, Peanut, Soybean Oil, Peanut Oil. National Standards of the People's Republic of China大豆、花生、豆油、花生油中的氟乐灵残留量的测定. 中华人民共和国国家标准. GB/T 5009.172-2003

    32. [32]

      GB/T 5009.176-2003, Determination of Dicofol Residues in Tea, Fruits, Edible Vegetable Oils. National Standards of the People's Republic of China茶叶、水果、食用植物油中三氯杀螨醇残留量的测定. 中华人民共和国国家标准. GB/T 5009.176-2003

    33. [33]

      LI You-Zhi, LI Fang, ZHAO Guang-Yue, HUANG Zhi-Qiang, LEI Hong-Qin, LI Yan-Mei. Chinese J. Anal. Chem.,2017,45(1):118-123 粟有志, 李芳, 赵光跃, 黄志强, 雷红琴, 李艳美.分析化学, 2017,45(1):118-123

    34. [34]

      WANG Si-Wei, LIU Yan-Ping, SUN Hai-Bin. Chinese J. Anal. Chem.,2018,46(5):704-709 王思威, 刘艳萍, 孙海滨.分析化学, 2018,46(5):704-709

    35. [35]

      ZHANG Xin-Zhong, LUO Feng-Jian, LIU Guang-Ming, LOU Zheng-Yun, CHEN Zong-Mao. Chinese J. Anal. Chem.,2011,39(9):1329-1335 张新忠, 罗逢健, 刘光明, 楼正云, 陈宗懋.分析化学, 2011,39(9):1329-1335

    36. [36]

      ZHAO Hai-Xiang, JIA Yan-Xia, DING Ming-Yu, SUN Da-Jiang, ZHAO Meng-Bin. Chinese Journal of Chromatography,2011,29(5):443-449 赵海香, 贾艳霞, 丁明玉, 孙大江, 赵孟彬.色谱,2011,29(5):443-449

    37. [37]

      Anastassiades M, Lehotay S J, Stajnbaher D, Schenck F J. J. AOAC Int.,2003,8(6):412-431

    38. [38]

      ZHANG Hong-Jun, WU Jin-Long, ZHU Wen-Da, GUO Ming-Cheng, WU Feng-Qi, WANG Lou-Ming, LI Lin. Pesticide Science and Administration,2018,39(9):34-39, 63 张宏军, 吴进龙, 朱文达, 郭明程, 吴凤琪, 王楼明, 李林.农药科学与管理,2018,39(9):34-39, 63

  • 加载中
计量
  • PDF下载量:  28
  • 文章访问数:  1474
  • HTML全文浏览量:  158
文章相关
  • 收稿日期:  2019-11-01
  • 修回日期:  2020-05-10
通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索

/

返回文章