土壤埋藏对常见彩绘文物蛋白胶料形貌和结构的影响

引用本文: 马珍珍, 王丽琴, 张亚旭, 由蕊, 郭芷彤, 杨璐. 土壤埋藏对常见彩绘文物蛋白胶料形貌和结构的影响[J]. 分析化学, 2020, 48(7): 896-902. doi: 10.19756/j.issn.0253-3820.191620 shu

Citation: MA Zhen-Zhen, WANG Li-Qin, ZHANG Ya-Xu, YOU Rui, GUO Zhi-Tong, YANG Lu. Morphological and Structural Study of Several Polychromy Artworks Proteinaceous Binders after Soil Aging[J]. Chinese Journal of Analytical Chemistry, 2020, 48(7): 896-902. doi: 10.19756/j.issn.0253-3820.191620 shu

土壤埋藏对常见彩绘文物蛋白胶料形貌和结构的影响

1.
西北大学文化遗产学院, 西安 710069;
2.
陕西省考古研究院, 西安 710054;
3.
文化遗产研究与保护技术教育部重点实验室, 西安 710069
基金项目:
本文系国家重点研发计划项目（No.2019YFC1520100）、陕西省重点产业创新链（群）项目（No.2019ZDLSF07-05）、陕西省重点科技创新团队项目（No.2015KCT-12）和陕西省文物局文物保护专项资金项目（No.专项-2019-012）资助

摘要: 利用扫描电子显微镜（SEM）、X-射线衍射法（XRD）和红外光谱法（FTIR）对猪皮胶、全蛋、蛋清、蛋黄、牛奶5种常见彩绘文物蛋白胶料老化前后的形貌、结晶度、红外光谱吸收特征和蛋白质二级结构含量进行了对比研究。结果表明，5种胶料老化后，表面规则的结构和纹理遭到破坏，整体变得松散；结晶度降低，尤以牛奶最显著；老化后，5种蛋白胶酰胺Ⅰ、Ⅱ、Ⅲ带红外吸收的阶梯状特征仍然明显，但螺旋结构已经解离，且均呈现α-螺旋含量降低、β-折叠和无规则卷曲含量增高的趋势，说明分子结构从有序趋于无序状态。

关键词:

English

Morphological and Structural Study of Several Polychromy Artworks Proteinaceous Binders after Soil Aging

1.
School of Cultural Heritage, Northwest University, Xi'an 710069, China;
2.
Shaanxi Academy of Archaeology, Xi'an 710054, China;
3.
Key Laboratory of Cultural Heritage Research and Conservation, Ministry of Education, Northwest University, Xi'an 710069, China
Received Date: 21 October 2019
Revised Date: 27 April 2020
Fund Project:
This work was supported by the National Key R&D Program of China (No. 2019YFC1520100), the Key Industry Innovation Chain (Group) Project of Shaanxi Province (No. 2019ZDLSF07-05), the Key Scientific and Technological Team from Innovation Shaanxi Province (No. 2015KCT-12) and the Cultural Relics Protection Project of Shaanxi Provincial Cultural Heritage Administration (No. 2019-012).

Abstract: For overall study of the soil aging influence on the common polychromy artworks proteinaceous binders, scanning electron microcopy, X-ray diffraction and infrared spectroscopy were applied to characterize the morphology, crystallinity, and proteins secondary structure contents of the common-used five binders (pig glue, whole egg, egg white, egg yolk and milk) in ancient China before and after soil aging. The results illustrated that the regular structures had deteriorated to the loosing states. The crystallinity all decreased, with milk declining the most. The binders still possessed the stair-stepped amide I, Ⅱ, Ⅲ FTIR absorbance while the helical structures had dissociated. Moreover, the content of α-helix declined while those at of β-sheet and random coils climbed, suggesting binders' structures had transformed to unordered states.

Key words:

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沈阳化工大学材料科学与工程学院沈阳 110142

土壤埋藏对常见彩绘文物蛋白胶料形貌和结构的影响

English

Morphological and Structural Study of Several Polychromy Artworks Proteinaceous Binders after Soil Aging

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

土壤埋藏对常见彩绘文物蛋白胶料形貌和结构的影响

English

Morphological and Structural Study of Several Polychromy Artworks Proteinaceous Binders after Soil Aging

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

CCS Chemistry：颜徐州、鲍哲南： 你的皮肤可能是一片SPMs

CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

CCS Chemistry：静电组装导向聚合- 聚电解质纳米凝胶量化制备新策略

CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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