超高效合相色谱法同时检测塑料食品接触材料中11种双酚类化合物

引用本文: 邱月, 李根容, 龙梅, 阮燕, 谭超兰, 张璐, 夏之宁. 超高效合相色谱法同时检测塑料食品接触材料中11种双酚类化合物[J]. 分析化学, 2020, 48(2): 255-261. doi: 10.19756/j.issn.0253-3820.191346 shu

Citation: QIU Yue, LI Gen-Rong, LONG Mei, RUAN Yan, TAN Chao-Lan, ZHANG Lu, XIA Zhi-Ning. Determination of 11 Kinds of Bisphenols in Plastic Food Contact Materials by Ultra-Performance Convergence Chromatography[J]. Chinese Journal of Analytical Chemistry, 2020, 48(2): 255-261. doi: 10.19756/j.issn.0253-3820.191346 shu

超高效合相色谱法同时检测塑料食品接触材料中11种双酚类化合物

邱月 ^1,2, ,
李根容 ^1, ,
龙梅 ^1, ,
阮燕 ^1, ,
谭超兰 ^1, ,
张璐 ^1, ,
夏之宁 ^2,

1.
重庆市计量质量检测研究院, 重庆 401123;
2.
重庆大学化学化工学院, 重庆 400030
基金项目:
本文系重庆市科研院所绩效激励引导专项（No.cstc2018jxj10007）资助

摘要: 建立了基于超高效合相色谱（Ultra performance convergence chromatography，UPC²）快速检测塑料食品接触材料中11种双酚类化合物的分析方法。食品接触塑料材料样品用甲醇进行超声萃取，过0.22 μm有机滤膜，采用超临界CO₂为主要流动相，甲醇为改性助溶剂，进行梯度洗脱，经ACQUITY UPC² Torus DIOL色谱柱（150 mm×3.0 mm，1.7 μm）分离，采用紫外检测器进行检测，外标法进行定量分析。在最优色谱条件下，5 min内可实现11种双酚类化合物的有效分离，11种目标化合物在各自浓度范围内线性关系良好，标准曲线相关系数（R²）>0.998，3个加标水平（1.0、25.0和50.0 mg/kg）下的回收率为75.7%~122.0%，相对标准偏差为0.6%~7.3%，检出限（LODs）为0.1~0.3 mg/kg。本方法操作简便、结果准确、绿色高效，可用于塑料食品接触材料中11种双酚类化合物的快速检测。

关键词:

English

Determination of 11 Kinds of Bisphenols in Plastic Food Contact Materials by Ultra-Performance Convergence Chromatography

1.
Chongqing Academy of Metrology and Quality Inspection, Chongqing 401123, China;
2.
College of Chemistry and Chemical Engineering, Chongqing University, Chongqing 400030, China
Received Date: 21 June 2019
Revised Date: 04 December 2019
Fund Project:
This work was supported by the Chongqing Scientific Research Institute Performance Incentive and Guidance Special Project (No. cstc2018jxj100007).

Abstract: A method for rapid detection of 11 kinds of bisphenols in plastic food contact materials based on ultra-performance convergence chromatography (UPC²) was established. Plastic food contact material sample was extracted with methanol by ultrasonic treatment, followed by clean-up through a 0.22 μm organic membrane. The separation was conducted on ACQUITY UPC² Torus DIOL chromatographic column (150 mm×3.0 mm, 1.7 mm) with supercritical carbon dioxide as the main mobile phase and methanol as a modified co-solvent for gradient elution. The 11 kinds of bisphenols were analyzed by UV detector, and quantified by external standard method. The 11 kinds of bisphenols were separated within 5 min under the optimum conditions, and exhibited a good linearity with the standard curve correlation coefficients (R²) of not less than 0.998. The recoveries at three standard levels (1.0, 25.0 and 50.0 mg/kg) were 75.7%-122.0%, the relative standard deviation was 0.6%-7.3%, and the detection limits (LODs) were 0.1-0.3 mg/kg. This method is convenient, accurate, green and efficient, and can be used for the rapid detection of 11 kinds of bisphenols in plastic food contact materials.

Key words:

Bisphenols
/ Ultra-performance convergence chromatography
/ Ultrasonic extraction
/ Plastic food contact materials

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沈阳化工大学材料科学与工程学院沈阳 110142

超高效合相色谱法同时检测塑料食品接触材料中11种双酚类化合物

English

Determination of 11 Kinds of Bisphenols in Plastic Food Contact Materials by Ultra-Performance Convergence Chromatography

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通讯作者: 陈斌, bchen63@163.com

中国化学会秘书处

超高效合相色谱法同时检测塑料食品接触材料中11种双酚类化合物

English

Determination of 11 Kinds of Bisphenols in Plastic Food Contact Materials by Ultra-Performance Convergence Chromatography

CCS Chemistry：嵌段共聚物自组装成 “三明治”二维有机材料，实现纳米级压力传感功能

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CCS Chemistry：工作高效不疲劳，只须让催化剂动起来

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CCS Chemistry：金黄色葡萄球菌醛基脱氢酶是如何识别特异性底物的？

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