Citation: Chen-Hao OU YANG, Zi-Juan WEI, Liang HE, Yu-Jun GUO, Ming-Bu LUO, Qi-Pu LIN. Syntheses and Structures of Two Zn-Pyrazole/carboxyl Coordination Frameworks[J]. Chinese Journal of Structural Chemistry, ;2021, 40(10): 1265-1270. doi: 10.14102/j.cnki.0254–5861.2011–3149 shu

Syntheses and Structures of Two Zn-Pyrazole/carboxyl Coordination Frameworks

Chen-Hao OU YANG ^{a, b} ,
Zi-Juan WEI ^{a, b} ,
Liang HE ^b ,
Yu-Jun GUO ^b ,
Ming-Bu LUO ^b ,
Qi-Pu LIN ^b,,

a.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Qi-Pu LIN, linqipu@fjirsm.ac.cn
Received Date: 22 February 2021
Accepted Date: 7 July 2021

Fund Project: the National Natural Science Foundation of China 21501028the National Natural Science Foundation of Fujian Province 2017J01039

Figures(6)

Two pyrazole-based zinc(II) metal-organic frameworks, [(Zn₄(PDC)₂(BDC)(H₂O)₂]_n (compound 1, PDC = 1H-pyrazole-3, 5-dicarboxylic acid, BDC = benzene-1, 4, -dicarboxylic acid) and [(Zn₃(PDC)₂(BPY)₃(H₂O)₂]_n (compound 2, BPY = 4, 4-bipyridine), were synthesized and characterized by X-ray diffraction, elemental analysis, thermogravimetric analysis, infrared and fluorescence spectroscopy. Compound 1 crystallizes in space group Pna2₁ with a = 14.325(3), b = 10.004(2), c = 16.454(3) Å, V = 2357.8(8) Å³, Z = 4, M_r = 821.83, D_c = 2.298 g·cm^-3, F(000) = 1608, GOOF = 1.163, the final R = 0.0218 and wR = 0.0686 for 5150 observed reflections with I > 2σ(I). Compound 2 crystallizes in monoclinic space group C2/c with a = 17.034(2), b = 11.6313(9), c = 11.7608(13) Å, V = 2034.9(4) Å³, Z = 2, M_r = 1006.91, D_c = 1.643 g·cm^-3, F(000) = 1020, GOOF = 1.084, the final R = 0.0320 and wR = 0.0768 for 2435 observed reflections with I > 2σ(I).
- pyrazole-carboxyl,
- X-ray crystallography,
- metal-organic frameworks,
- luminescence
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