Citation: Hai-Yan JU, Ming YANG, Gang ZHANG, De-Zheng LIU, Yong-Sheng YANG, Yan-Bo ZHANG. Construction of Chiral One-dimensional Chains via Mononuclear Chiral Precursors and Circular Dichroism Properties[J]. Chinese Journal of Structural Chemistry, ;2021, 40(6): 767-774. doi: 10.14102/j.cnki.0254–5861.2011–3008 shu

Construction of Chiral One-dimensional Chains via Mononuclear Chiral Precursors and Circular Dichroism Properties

Hai-Yan JU ^{a, b} ,
Ming YANG ^{a, b} ,
Gang ZHANG ^{a, b} ,
De-Zheng LIU ^c,, ,
Yong-Sheng YANG ^{a, b,,} ,
Yan-Bo ZHANG ^{a, b,,}

a.
School of Chemistry and Engineering, Wuhan Textile University, Wuhan 430073, China
b.
Hubei Key Laboratory of Biomass Fibers and Eco-dyeing & Finishing, Wuhan Textile University, Wuhan 430073, China
c.
Hubei Key Laboratory of Power System Design and Test for Electrical Vehicle, Hubei University of Arts and Science, Xiangyang 441053, China

Corresponding author: De-Zheng LIU, liudezheng@hbuas.edu.cn Yong-Sheng YANG, ysyang@wtu.edu.cn Yan-Bo ZHANG, yanboz@163.com
Received Date: 26 October 2020
Accepted Date: 15 December 2020

Fund Project: Wuhan Textile University 017/195014Wuhan Textile University 017/192223Wuhan Textile University 017/205051Hubei Superior and Distinctive Discipline Group of "Mechatronics and Automobiles" XKQ2019009Natural Science Foundation of Hubei Province 2016CFB334

Figures(5)

One-dimensional (1D) chiral chain complexes [CuLSCu(Pydc)] (2S) and [CuLRCu(Pydc)] (2R) (LS = (E)-3-(((1S, 2S)-2-(((E)-3-oxo-3-(4-pyridin-4-yl)phenyl)propylidene)amono)-1, 2-diphenyl)imino)-1-(4-(pyridi-4-yl)phenyl)butan-1-one) and LR = (E)-3-(((1R, 2R)-2-(((E)-3-oxo-3-(4-pyridin-4-yl)phenyl)propylidene)amono)-1, 2-diphenyl)imino)-1-(4-(pyridi-4-yl)phenyl)butan-1-one and Pydc = 2, 6-pyridinedicarboxylic acid) have been synthesized vis mononuclear chiral enantiomer precursors CuLS (1S) and CuLR (1R). Their different chiral configurations of 1S, 1R, 2S and 2R were determined by single-crystal X-ray diffraction analyses and further characterized by elemental analyses, infrared spectra (IR), powder X-ray diffraction (PXRD), thermal gravimetric analyses (TGA) and circular dichroism spectra (CD).
- mononuclear chiral precursors,
- 1D chiral chain,
- circular dichroism spectra
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