Citation: Cheng-Dan SHI, Jia-Yue TIAN, Fei-Long JIANG, Qi-Hui CHEN, Mao-Chun HONG. A Novel Co(Ⅱ)-organic Framework with Multiple Active Sites for Selective Gas Adsorption[J]. Chinese Journal of Structural Chemistry, ;2021, 40(2): 169-174. doi: 10.14102/j.cnki.0254–5861.2011–2784 shu

A Novel Co(Ⅱ)-organic Framework with Multiple Active Sites for Selective Gas Adsorption

a.
College of Chemistry and Materials Science, Fujian Normal University, Fuzhou 350007, China
b.
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: Qi-Hui CHEN, chenqh@fjirsm.ac.cn Mao-Chun HONG, hmc@fjirsm.ac.cn
Received Date: 24 February 2020
Accepted Date: 30 March 2020

Fund Project: the National Natural Science Foundation of China 21871265

Figures(3)

A novel metal-organic framework [Co(BTTA)(H₂O)₂]_n (FJI-H24) has been prepared from H₂BTTA ligand and CoCl₂, and its structure was determined by single-crystal X-ray diffraction, thermogravimetric analysis, and Fourier transform infrared spectroscopy. It has relatively narrow pores and high density of open metal ions and free Lewis base sites. Gas adsorption tests demonstrate that FJI-H24 has moderate CO₂ (34.0 cm³·g^–1) and C₂H₂ (53.0 cm³·g^–1) adsorption capacity, but displays high selectivity of CO₂/N₂ (87) and C₂H₂/CH₄ (66) under ambient conditions (298 K, 1 atm), which may be attributed to its relatively narrow pores and polar environment. This work will provide a potential strategy for preparing practical porous metal-organic frameworks for gas adsorption and purification.
- metal-organic frameworks,
- gas adsorption,
- gas purification,
- open metal ions,
- Lewis base sites
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