Citation: Yue Qiu, Jin-Jin Li, Ling Zhao, Zhenhao Xi, Weikang Yuan. Porous Metal-Organic Framework-Polymer Composites Using High Internal Phase Emulsion Templates: A Review[J]. Chinese Journal of Structural Chemistry, ;2022, 41(12): 221206. doi: 10.14102/j.cnki.0254-5861.2022-0179 shu

Porous Metal-Organic Framework-Polymer Composites Using High Internal Phase Emulsion Templates: A Review

  • Author Bio: Yue Qiu received her bachelor's degree from East China University of Science and Technology (ECUST) in 2021. She is currently studying for her master's degree at school of chemical engineering, ECUST. Her research work focuses on the interface stability mechanism of HIPE and the fabrication of porous polymeric materials
    Jin-Jin Li is an associate professor at School of chemical engineering, East China University of Science and Technology. Her research focuses on the synthesis of functional polymers by controlled radical polymerizations for a wide range of applications, and porous polymers or polymer composites by using HIPE templates
    Ling Zhao is a professor at both of Shanghai Key Laboratory of Multiphase Materials Chemical Engineering and State Key Laboratory of Chemical Engineering, East China University of Science and Technology. Her research focuses on multiphase reaction and transfer: (Ⅰ) industrial reaction process development and (Ⅱ) supercritical fluid assisted polymerization and polymer processing
    Zhenhao Xi is a professor at both of Shanghai Key Laboratory of Multiphase Materials Chemical Engineering and State Key Laboratory of Chemical Engineering, East China University of Science and Technology. He mainly focuses on the researches of polymer reaction engineering and the high-added value polymeric materials
    Weikang Yuan is an academician of the Chinese Academy of Engineering and a distinguished professor at State Key Laboratory of Chemical Engineering, East China University of Science and Technology. He has been engaged in chemical engineering and industrial reactor development, with chemical reaction engineering as the main direction
  • Corresponding author: Jin-Jin Li, Zhenhao Xi,
  • Received Date: 1 August 2022
    Accepted Date: 26 August 2022
    Available Online: 31 August 2022


  • As promising engineering materials for green and sustainable processes, porous metalorganic framework (MOF)-polymer composites show great potential in applications, including adsorption, separation, catalysis, and bioengineering. Owing to the mild and scalable operation, porous polymeric materials derived from high internal phase emulsion templates (polyHIPE) have received great interests in recent decades. In this contribution, research progress of the preparation of porous MOF@polyHIPE composites and their applications are reviewed, highlighting how can MOF particles be shaped by HIPE templates, in particular the polymerizable ones. Four different emulsion templates stabilized by MOFs and the applications of corresponding MOF@polyHIPE are included. Hopefully, both the state-of-art and future directions present herein can give rise to the development of high-performance porous MOF@polyHIPEs.
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