Citation: Guoliang Liu, Xiao-Qin Liu, Lin-Bing Sun. Recent Advances in Metal-Organic Cages-Based Composite Membranes[J]. Chinese Journal of Structural Chemistry, ;2022, 41(11): 221110. doi: 10.14102/j.cnki.0254-5861.2022-0178 shu

Recent Advances in Metal-Organic Cages-Based Composite Membranes

  • Author Bio: Guoliang Liu received his PhD in physical chemistry from Fujian Institute of Research on the Structure of Matter, CAS, where he worked on application-oriented design and synthesis of zirconium metal-organic cages (Zr-MOCs) under the guidance of Prof. Daqiang Yuan. After a postdoctoral stint at National University of Singapore with Prof. Dan Zhao, he joined the faculty of Nanjing Tech University at 2020. His research interests focus on the construction of Zr-MOCs based crystalline porous supramolecular frameworks for sophisticated applications
    Xiao-Qin Liu obtained her PhD in 1999 from Nanjing Tech University under the supervision of Professor Jun Shi and Professor Hu-Qing Yao. She joined the faculty of Nanjing Tech University in 1982, and became a professor in 1999. Her current research interests focus on the design, synthesis, and applications of porous functional materials, with emphasis on adsorbents and catalysts
    Lin-Bing Sun obtained his PhD in 2008 from Nanjing University under the supervision of Professor Jian-Hua Zhu and Professor Yuan Chun. He joined the faculty of Nanjing Tech University in 2008, and became an associate professor in 2011. He was a postdoctoral research associate at Texas A & M University with Professor Hong-Cai Zhou in 2011-2012. His current research interests focus on the fabrication of porous materials and their applications in adsorption and heterogeneous catalysis
  • Corresponding author: Lin-Bing Sun,
  • Received Date: 1 August 2022
    Accepted Date: 18 August 2022
    Available Online: 23 August 2022


  • Conventional polymeric membranes face several limitations, such as the trade-off between permeability and selectivity, and physical aging or membrane fouling. In this case, fabrication of composite membranes, usually including mixed matrix membranes (MMMs) or thin film nanocomposite (TFN) membranes by introduction of porous materials as fillers has gained much attention. To achieve excellent membrane performance, it is of great importance to select proper porous materials to avoid agglomeration or precipitation during the composite membrane fabrication processes. Metal-organic cages (MOCs) have been explored as additives for the fabrication of defectfree composite membranes owing to their diversified topologies, well-defined pore structures, nanoscale size, and excellent solubility. This review mainly focuses on the recent advances in applications of MOCs for membrane separation, including synthetic artificial channels, reverse osmosis, nanofiltration, pervaporation and gas separation. Besides, two types of MOCs that have been extensively investigated for composite membrane fabrication are also highlighted. Furthermore, challenges and possible directions are also discussed in details, hoping to provide insightful guidance on the development of more MOC-based membranes with impressive separation performance.
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