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Citation: Tian-Qin Zeng, Lang Chen, Bing-Hao Wang, Sheng Tian, Zhang-Jun Bai, Xiong Wang, Jun-Kang Guo, Shuang-Feng Yin. One-Pot Synthesis of Bismuth Basic Nitrate-Bi2MoO6 Photocatalyst for Selective Oxidation of Toluene[J]. Chinese Journal of Structural Chemistry, ;2022, 41(12): 2212025-2212032. doi: 10.14102/j.cnki.0254-5861.2022-0149 shu

One-Pot Synthesis of Bismuth Basic Nitrate-Bi2MoO6 Photocatalyst for Selective Oxidation of Toluene

  • 1.

    Advanced Catalytic Engineering Research Center of the Ministry of Education, College of Chemistry and Chemical Engineering, State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University, Changsha 410082, China

  • 2.

    College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, China

Figures(9)

  • The key issues to improve the performance of photocatalysts for selective oxidation of toluene are promoting the migration and separation of charge carrier, and enhancing the generation of active oxygen species. It is known that the construction of compact heterojunction is an efficient protocol to inhibit photogenerated electron-hole recombination. In this work, a 2D-2D [Bi6O6(OH)3](NO3)3·1.5H2O-Bi2MoO6 (denoted as BBN-BMO) composite heterojunction has been prepared by one-step hydrothermal method for the first time. The tetragonal phase BBN in the composite plays the role of transferring electrons from the visible light activated orthorhombic phase BMO and promoting the generation of active •O2-, the holes left in BMO are used to activate toluene and produce benzyl radical, thus greatly improving the photocatalytic performance for selective oxidation of toluene. The toluene conversion rate of BBN-BMO is 3466 μmol·g-1·h-1, which is three times that of pure BMO. The selectivity to benzaldehyde is 94.2%. In addition, reasonable mechanism has been speculated based on a series of control experiments.
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