Citation: Hao Zhang, Ru Sun, Da-Cheng Li, Jian-Min Dou. A Review on Crystalline Porous MOFs Materials in Photocatalytic Transformations of Organic Compounds in Recent Three Years[J]. Chinese Journal of Structural Chemistry, ;2022, 41(11): 221107. doi: 10.14102/j.cnki.0254-5861.2022-0140 shu

A Review on Crystalline Porous MOFs Materials in Photocatalytic Transformations of Organic Compounds in Recent Three Years

  • Author Bio: Hao Zhang received his bachelor's degree from Yantai University in 2019. In the same year, he was admitted to the Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology of Liaocheng University for his master's degree. His current research focuses on molecular complexes and MOFs materials in photocatalytic decomposition of water to produce hydrogen and catalytic conversion of small organic molecules
    Ru Sun graduated from Taishan University with a bachelor's degree. She is currently studying in the Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology of Liaocheng University under the guidance of Prof. Da-Cheng Li. Her main research interests are the synthesis and properties of functionalized POMs
    Da-Cheng Li. Her main research interests are the synthesis and properties of functionalized POMs. Da-Cheng Li graduated from Liaocheng University and obtained the bachelor's degree in 1985. From 1989 to 1991, he studied in the graduate program of analytical chemistry at Shaanxi Normal University. He now works at the Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology of Liaocheng University. In recent years, he has been engaged in the research of borane chemistry, crown ether chemistry, coordination chemistry, drug polycrystal and eutectic
    Jian-Min Dou received his bachelor's degree from Liaocheng University in 1986 and earned his Ph.D. degree at Fudan University in 1998. He has been teaching in Liaocheng University for more than 30 years. His previous research focused on the structure and magnetic properties of metal crown ethers. The current direction is related to energy catalysis including photocatalytic water decomposition, CO2 reduction and degradation of organic pollutants
  • Corresponding author: Jian-Min Dou,
  • Hao Zhang and Ru Sun contributed equally to this work.
  • Received Date: 27 May 2022
    Accepted Date: 12 June 2022
    Available Online: 20 June 2022


  • Metal-organic frameworks (MOFs) have always been the focus of chemists due to their diverse structures, adjustable pore size and high stability since they came into being. In recent years, as one of the most significant applications of MOFs porous materials, photocatalytic organic compounds transformation has made full-grown progress both in the preparation of the catalysts themselves and in the scope of specific applications. Herein, we summarize the research progress of MOFs catalysts for photocatalytic transformations of organic compounds in recent three years. Some outstanding works on the preparation and synthesis strategies of photocatalysts are introduced firstly, including internal optimization and modification of MOFs, POM@MOF composite and core-shell MOF@COF hybrids. The second part is about the application of diverse types of organic reactions, including dual-function organic reactions, catalytic oxidation reactions, comprehensive utilization of CO2 and degradation of organic pollutants. Besides, the development opportunities and some problems to be solved in this field are proposed.
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