Recent Advances in C2 Gases Separation and Purification by Metal-Organic Frameworks
- Corresponding author: Cheng-Peng Li, hxxylcp@tjnu.edu.cn
Citation: Zhengyi Di, Xinjing Zheng, Yu Qi, Heng Yuan, Cheng-Peng Li. Recent Advances in C2 Gases Separation and Purification by Metal-Organic Frameworks[J]. Chinese Journal of Structural Chemistry, ;2022, 41(11): 221103. doi: 10.14102/j.cnki.0254-5861.2022-0132
Sholl, D. S.; Lively, R. P. Seven chemical separations to change the world. Nature 2016, 532, 435-437.
doi: 10.1038/532435a
Pei, J.; Shao, K.; Zhang, L.; Wen, H. M.; Li, B.; Qian, G. Current status of microporous metal-organic frameworks for hydrocarbon separations. Top. Curr. Chem. 2019, 377, 2-34.
doi: 10.1007/s41061-018-0226-z
Lin, J. Y. S. Molecular sieves for gas separation. Science 2016, 353, 121-122.
doi: 10.1126/science.aag2267
Kuznicki, S. M.; Bell, V. A.; Nair, S.; Hillhouse, H. W.; Jacubinas, R. M.; Braunbarth, C. M.; Toby, B. H.; Tsapatsis, M. A titanosilicate molecular sieve with adjustable pores for size-selective adsorption of molecules. Nature 2001, 412, 720-724.
doi: 10.1038/35089052
Vaidhyanathan, R.; Iremonger, S. S.; Shimizu, G. K. H.; Boyd, P. G.; Alavi, S.; Woo, T. K. Direct observation and quantification of CO2 binding within an amine-functionalized nanoporous solid. Science 2010, 330, 650-653.
doi: 10.1126/science.1194237
Ryu, U.; Jee, S.; Rao, P. C.; Shin, J.; Ko, C.; Yoon, M.; Park, K. S.; Choi, K. M. Recent advances in process engineering and upcoming applications of metal-organic frameworks. Coord. Chem. Rev. 2021, 426, 213544.
doi: 10.1016/j.ccr.2020.213544
Zhang, X.; Chen, Z.; Liu, X.; Hanna, S. L.; Wang, X.; Taheri-Ledari, R.; Maleki, A.; Li, P.; Farha, O. K. A historical overview of the activation and porosity of metal-organic frameworks. Chem. Soc. Rev. 2020, 49, 7406-7427.
doi: 10.1039/D0CS00997K
Lan, T.; Li, L.; Chen, Y.; Wang, X.; Yang, J.; Li, J. Opportunities and critical factors of porous metal-organic frameworks for industrial light olefins separation. Mater. Chem. Front. 2020, 4, 1954-1984.
doi: 10.1039/D0QM00186D
Lin, R. -B.; Xiang, S.; Xing, H.; Zhou, W.; Chen, B. Exploration of porous metal-organic frameworks for gas separation and purification. Coord. Chem. Rev. 2019, 378, 87-103.
doi: 10.1016/j.ccr.2017.09.027
Di, Z.; Mao, Y.; Yuan, H.; Zhou, Y.; Jin, J.; Li, C. -P. Covalent organic frameworks (COFs) for sequestration of 99TcO4-. Chem. Res. Chin. Univ. 2022, DOI: 10.1007/s40242-022-1447-9.
doi: 10.1007/s40242-022-1447-9
Ji, Z.; Di, Z.; Li, H.; Zou, S.; Wu, M.; Hong, M. A flexible Zr-MOF with dual stimulus responses to temperature and guest molecules. Inorg. Chem. Commun. 2021, 128, 108597.
doi: 10.1016/j.inoche.2021.108597
Bereciartua, P. J.; Cantín, Á.; Corma, A.; Jordá, J. L.; Palomino, M.; Rey, F.; Valencia, S.; W. C. J. E.; Kortunov, P.; Ravikovitch, P. I.; Burton, A.; Yoon, C.; Wang, Y.; Paur, C.; Guzman, J.; Bishop, A. R.; Casty, G. L. Control of zeolite framework flexibility and pore topology for separation of ethane and ethylene. Science 2017, 358, 1068-1071.
doi: 10.1126/science.aao0092
Cai, Z. W.; Sun, J.; Pan, Y. T.; Jiang, T. T.; Li, Q.; Cui, P. P.; Zhang, J. Synthesis of a rare doubly-interpenetrating zinc(II) coordination polymer for applications in photocatalysis. Chin. J. Struct. Chem. 2020, 39, 718-726.
Cui, W. G.; Hu, T. L.; Bu, X. H. Metal-organic framework materials for the separation and purification of light hydrocarbons. Adv. Mater. 2019, 32, 1806445.
Zhao, X.; Wang, Y.; Li, D. -S.; Bu, X.; Feng, P. Metal-organic frameworks for separation. Adv. Mater. 2018, 30, 1705189.
doi: 10.1002/adma.201705189
Griffin, S. L.; Champness, N. R. A periodic table of metal-organic frameworks. Coord. Chem. Rev. 2020, 414, 213295.
doi: 10.1016/j.ccr.2020.213295
Lin, R. -B.; Xiang, S.; Li, B.; Cui, Y.; Qian, G.; Zhou, W.; Chen, B. Our journey of developing multifunctional metal-organic frameworks. Coord. Chem. Rev. 2019, 384, 21-36.
doi: 10.1016/j.ccr.2019.01.009
Kuppler, R. J.; Timmons, D. J.; Fang, Q. R.; Li, J. R.; Makal, T. A.; Young, M. D.; Yuan, D. Q.; Zhao, D.; Zhuang, W. J.; Zhou, H. C. Potential applications of metal-organic frameworks. Coord. Chem. Rev. 2009, 253, 3042-3066.
doi: 10.1016/j.ccr.2009.05.019
Zhang, S.; Taylor, M. K.; Jiang, L.; Ren, H.; Zhu, G. Light hydrocarbon separations using porous organic framework materials. Chem. Eur. J. 2020, 26, 3205-3221.
doi: 10.1002/chem.201904455
Su, K.; Wang, W.; Du, S.; Ji, C.; Yuan, D. Efficient ethylene purification by a robust ethane-trapping porous organic cage. Nat. Commun. 2021, 12, 3703.
doi: 10.1038/s41467-021-24042-7
Zhang, X.; Li, L.; Wang, J. X.; Wen, H. M.; Krishna, R.; Wu, H.; Zhou, W.; Chen, Z. N.; Li, B.; Qian, G.; Chen, B. Selective ethane/ethylene separation in a robust microporous hydrogen-bonded organic framework. J. Am. Chem. Soc. 2020, 142, 633-640.
doi: 10.1021/jacs.9b12428
Wang, W.; Su, K.; El-Sayed, E. M.; Yang, M.; Yuan, D. Solvatomorphism influence of porous organic cage on C2H2/CO2 separation. ACS Appl. Mater. Interfaces 2021, 13, 24042-24050.
doi: 10.1021/acsami.1c04573
Pang, J.; Liu, C.; Huang, Y.; Wu, M.; Jiang, F.; Yuan, D.; Hu, F.; Su, K.; Liu, G.; Hong, M. Visualizing the dynamics of temperature- and solvent-responsive soft crystals. Angew. Chem. Int. Ed. 2016, 55, 7478-7482.
doi: 10.1002/anie.201603030
Pang, J.; Jiang, F.; Wu, M.; Liu, C.; Su, K.; Lu, W.; Yuan, D.; Hong, M. A porous metal-organic framework with ultrahigh acetylene uptake capacity under ambient conditions. Nat. Commun. 2015, 6, 7575.
doi: 10.1038/ncomms8575
Pang, J.; Di, Z.; Qin, J. -S.; Yuan, S.; Lollar, C. T.; Li, J.; Zhang, P.; Wu, M.; Yuan, D.; Hong, M.; Zhou, H. -C. Precisely embedding active sites into a mesoporous Zr-framework through linker installation for high-efficiency photocatalysis. J. Am. Chem. Soc. 2020, 142, 15020-15026.
doi: 10.1021/jacs.0c05758
Xue, H.; Li, T.; Yin, Q.; Huang, G.; Liu, T. F. A sulfonate-based metal-organic framework for the transformation of CO2 and epoxides into cyclic carbonates. Chin. J. Struct. Chem. 2020, 39, 2027-2032.
Yu, X.; Du, S.; Yang, Y.; Di, Z.; Wu, M. Two pyrene-based metalorganic frameworks for chemiluminescence. Inorg. Chem. 2021, 60, 1320-1324.
doi: 10.1021/acs.inorgchem.0c03627
Wang, X. T.; Wei, W.; Zhang, K.; Du, S. W. Detection of diethyl ether by a europium MOF through fluorescence enhancement. Chin. J. Struct. Chem. 2021, 40, 369-375.
Bai, S.; Liu, X.; Zhu, K.; Wu, S.; Zhou, H. Metal-organic framework-based separator for lithium-sulfur batteries. Nat. Energy 2016, 1, 16094.
doi: 10.1038/nenergy.2016.94
Guo, S. S.; Huang, L.; Ye, Y. X.; Liu, L. Z.; Yao, Z. Z.; Xiang, S. C.; Zhang, J. D.; Zhang, Z. J. Carbazole based anionic MOF for proton conductivity. Chin. J. Struct. Chem. 2021, 40, 55-60.
Xue, Y.; Zhu, Z.; Zhang, X.; Chen, J.; Yang, X.; Gao, X.; Zhang, S.; Luo, F.; Wang, J.; Zhao, W.; Huang, C.; Pei, X.; Wan, Q. Accelerated bone regeneration by MOF modified multifunctional membranes through enhancement of osteogenic and angiogenic performance. Adv. Healthc. Mater. 2021, 10, 2001369.
doi: 10.1002/adhm.202001369
Wang, Y.; Li, Q.; Deng, M.; Chen, K.; Wang, J. Self-assembled metal-organic frameworks nanocrystals synthesis and application for plumbagin drug delivery in acute lung injury therapy. Chin. Chem. Lett. 2022, 33, 324-327.
doi: 10.1016/j.cclet.2021.06.080
Tang, J. H.; Sun, H. Y.; Ma, W.; Feng, M. L.; Huang, X. Y. Recent progress in developing crystalline ion exchange materials for the removal of radioactive ions. Chin. J. Struct. Chem. 2020, 39, 2157-2171.
Hu, F. L.; Di, Z. Y.; Wu, M. Y.; Hong, M. C.; Li, J. A robust multifunctional Eu-6-cluster based framework for gas separation and recognition of small molecules and heavy metal ions. Cryst. Growth Des. 2019, 19, 6381-6387.
doi: 10.1021/acs.cgd.9b00866
Su, K.; Du, S.; Wang, W.; Yuan, D. Control of random self-assembly of pyrogallol[4]arene-based nanocapsule or framework. Chin. Chem. Lett. 2020, 31, 2023-2026.
doi: 10.1016/j.cclet.2019.11.047
Di, Z.; Pang, J.; Hu, F.; Wu, M.; Hong, M. An ultra-stable microporous supramolecular framework with highly selective adsorption and separation of water over ethanol. Nano. Res. 2021, 14, 2584-2588.
doi: 10.1007/s12274-020-3258-y
Qin, Y.; Wan, Y.; Guo, J.; Zhao, M. Two-dimensional metal-organic framework nanosheet composites: preparations and applications. Chin. Chem. Lett. 2022, 33, 693-702.
doi: 10.1016/j.cclet.2021.07.013
Xu, Q. -Y.; Tan, Z.; Liao, X. -W.; Wang, C. Recent advances in nanoscale metal-organic frameworks biosensors for detection of biomarkers. Chin. Chem. Lett. 2022, 33, 22-32.
doi: 10.1016/j.cclet.2021.06.015
Hu, F. L.; Di, Z. Y.; Lin, P.; Huang, P.; Wu, M. Y.; Jiang, F. L.; Hong, M. C. An anionic uranium-based metal-organic framework with ultralarge nanocages for selective dye adsorption. Cryst. Growth Des. 2018, 18, 576-580.
doi: 10.1021/acs.cgd.7b01525
Hu, F.; Di, Z.; Wu, M.; Li, J. Building a robust 3D Ca-MOF by a new square Ca4O SBU for purification of natural gas. Dalton Trans. 2020, 49, 8836-8840.
doi: 10.1039/D0DT00943A
Desai, A. V.; Sharma, S.; Let, S.; Ghosh, S. K. N-donor linker based metal-organic frameworks (MOFs): advancement and prospects as functional materials. Coord. Chem. Rev. 2019, 395, 146-192.
doi: 10.1016/j.ccr.2019.05.020
Hu, F. L.; Huang, P.; Di, Z. Y.; Wu, M. Y.; Jiang, F. L.; Hong, M. C. A robust cage-based framework for the highly selective purification of natural gas. Chem. Commun. 2019, 55, 10257-10260.
doi: 10.1039/C9CC03354H
Little, M. A.; Cooper, A. I. The chemistry of porous organic molecular materials. Adv. Funct. Mater. 2020, 30, 1909842.
doi: 10.1002/adfm.201909842
Zhu, B.; Cao, J. -W.; Mukherjee, S.; Pham, T.; Zhang, T.; Wang, T.; Jiang, X.; Forrest, K. A.; Zaworotko, M. J.; Chen, K. -J. Pore engineering for one-step ethylene purification from a three-component hydrocarbon mixture. J. Am. Chem. Soc. 2021, 143, 1485-1492.
doi: 10.1021/jacs.0c11247
Yang, Y.; Li, L.; Lin, R. B.; Ye, Y.; Yao, Z.; Yang, L.; Xiang, F.; Chen, S.; Zhang, Z.; Xiang, S.; Chen, B. Ethylene/ethane separation in a stable hydrogen-bonded organic framework through a gating mechanism. Nat. Chem. 2021, 13, 933.
doi: 10.1038/s41557-021-00740-z
Lyndon, R.; You, W.; Ma, Y.; Bacsa, J.; Gong, Y.; Stangland, E. E.; Walton, K. S.; Sholl, D. S.; Lively, R. P. Tuning the structures of metalorganic frameworks via a mixed-linker strategy for ethylene/ethane kinetic separation. Chem. Mater. 2020, 32, 3715-3722.
doi: 10.1021/acs.chemmater.9b04177
Zhou, P.; Yue, L.; Wang, X.; Fan, L.; Chen, D. L.; He, Y. Improving ethane/ethylene separation performance of isoreticular metal-organic frameworks via substituent engineering. ACS Appl. Mater. Interfaces 2021, 13, 54059-54068.
doi: 10.1021/acsami.1c17818
Wu, J. R.; Yang, Y. W. Synthetic macrocycle-based nonporous adaptive crystals for molecular separation. Angew. Chem. Int. Ed. 2020, 132, 2271-2275.
doi: 10.1002/ange.201911965
Wang, Q. M.; Shen, D.; B?uulow, M.; Lau, M. L.; Deng, S.; Fitch, F.; Lemcoff, N. O.; Semanscin, J. Metallo-organic molecular sieve for gas separation and purification. Micro. Meso. Mater. 2002, 55, 217-230.
doi: 10.1016/S1387-1811(02)00405-5
Bao, Z.; Alnemrat, S.; Yu, L.; Vasiliev, I.; Ren, Q.; Lu, X.; Deng, S. Adsorption of ethane, ethylene, propane, and propylene on a magnesium-based metal-organic framework. Langmuir 2011, 27, 13554-13562.
doi: 10.1021/la2030473
Bloch, E. D.; Queen, W. L.; Krishna, R.; Zadrozny, J. M.; Brown, C. M.; Long, J. R. Hydrocarbon separations in a metal-organic framework with open iron(II) coordination sites. Science 2012, 335, 1606-1610.
doi: 10.1126/science.1217544
Lin, R. B.; Li, L.; Zhou, H. L.; Wu, H.; He, C.; Li, S.; Krishna, R.; Li, J.; Zhou, W.; Chen, B. Molecular sieving of ethylene from ethane using a rigid metal-organic framework. Nat. Mater. 2018, 17, 1128-1133.
doi: 10.1038/s41563-018-0206-2
Zhang, L.; Li, L.; Hu, E.; Yang, L.; Shao, K.; Yao, L.; Jiang, K.; Cui, Y.; Yang, Y.; Li, B.; Chen, B.; Qian, G. Boosting ethylene/ethane separation within copper(I)-chelated metal-organic frameworks through tailor-made aperture and specific π-complexation. Adv. Sci. 2019, 7, 1901918.
Lei, X. W.; Yang, H.; Wang, Y.; Wang, Y.; Chen, X.; Xiao, Y.; Bu, X.; Feng, P. Tunable metal-organic frameworks based on 8-connected metal trimers for high ethane uptake. Small 2020, 17, 2003167.
Qi, D.; Zhaoqiang, Z.; Cong, Y.; Peixin, Z.; Jun, W.; Xili, C.; Chao-Hong, H.; Shuguang, D.; Huabin, X. Exploiting equilibrium-kinetic synergetic effect for separation of ethylene and ethane in a microporous metal-organic framework. Sci. Adv. 2020, 6, 4322.
doi: 10.1126/sciadv.aaz4322
Gucuyener, C.; den, B. J. V.; Jorge, G.; Freek, K. Ethane/ethene separation turned on its head: selective ethane adsorption on the metal-organic framework ZIF-7 through a gate-opening mechanism. J. Am. Chem. Soc. 2010, 132, 17704-17706.
doi: 10.1021/ja1089765
Pires, J.; Pinto, M. L.; Saini, V. K. Ethane selective IRMOF-8 and its significance in ethane-ethylene separation by adsorption. ACS Appl. Mater. Interfaces 2014, 6, 12093-12099.
doi: 10.1021/am502686g
Pillai, R. S.; Pinto, M. L.; Pires, J.; Jorge, M.; Gomes, J. R. Understanding gas adsorption selectivity in IRMOF-8 using molecular simulation. ACS Appl. Mater. Interfaces 2015, 7, 624-637.
doi: 10.1021/am506793b
Lin, R. B.; Wu, H.; Li, L.; Tang, X. L.; Li, Z.; Gao, J.; Cui, H.; Zhou, W.; Chen, B. Boosting ethane/ethylene separation within isoreticular ultramicroporous metal-organic frameworks. J. Am. Chem. Soc. 2018, 140, 12940-12946.
doi: 10.1021/jacs.8b07563
Liao, P. Q.; Zhang, W. X.; Zhang, J. P.; Chen, X. M. Efficient purification of ethene by an ethane-trapping metal-organic framework. Nat. Commun. 2015, 6, 8697.
doi: 10.1038/ncomms9697
Li, L.; Lin, R. B.; Krishna, R.; Li, H.; Xiang, S.; Wu, H.; Li, J.; Zhou, W.; Chen, B. Ethane/ethylene separation in a metal-organic framework with iron-peroxo sites. Science 2018, 362, 443-446.
doi: 10.1126/science.aat0586
Li, B.; Cui, X.; O'Nolan, D.; Wen, H. -M.; Jiang, M.; Krishna, R.; Wu, H.; Lin, R. -B.; Chen, Y. -S.; Yuan, D.; Xing, H.; Zhou, W.; Ren, Q.; Qian, G.; Zaworotko, M. J.; Chen, B. An ideal molecular sieve for acetylene removal from ethylene with record selectivity and productivity. Adv. Mater. 2017, 29, 1704210.
doi: 10.1002/adma.201704210
Shen, J.; He, X.; Ke, T.; Krishna, R.; van Baten, J. M.; Chen, R.; Bao, Z.; Xing, H.; Dincǎ, M.; Zhang, Z.; Yang, Q.; Ren, Q. Simultaneous interlayer and intralayer space control in two-dimensional metal-organic frameworks for acetylene/ethylene separation. Nat. Commun. 2020, 11, 6259-6259.
doi: 10.1038/s41467-020-20101-7
Pei, J.; Shao, K.; Wang, J. X.; Wen, H. M.; Yang, Y.; Cui, Y.; Krishna, R.; Li, B.; Qian, G. A chemically stable Hofmann-type metal-organic framework with sandwich-like binding sites for benchmark acetylene capture. Adv. Mater. 2020, 32, 1908275.
doi: 10.1002/adma.201908275
Jiang, K.; Zhang, L.; Xia, T.; Yang, Y.; Li, B.; Cui, Y.; Qian, G. A water-stable fcu-MOF material with exposed amino groups for the multifunctional separation of small molecules. Sci. China Mater. 2019, 62, 1315-1322.
doi: 10.1007/s40843-019-9427-5
Chai, Y.; Han, X.; Li, W.; Liu, S.; Yao, S.; Wang, C.; Shi, W.; da-Silva, I.; Manuel, P.; Cheng, Y.; Daemen, L. D.; Ramirez-Cuesta, A. J.; Tang, C. C.; Jiang, L.; Yang, S.; Guan, N.; Li, L. Control of zeolite pore interior for chemoselective alkyne/olefin separations. Science 2020, 368, 1002-1006.
doi: 10.1126/science.aay8447
Xiang, S. C.; Zhang, Z.; Zhao, C. G.; Hong, K.; Zhao, X.; Ding, D. R.; Xie, M. H.; Wu, C. D.; Das, M. C.; Gill, R.; Thomas, K. M.; Chen, B. Rationally tuned micropores within enantiopure metal-organic frameworks for highly selective separation of acetylene and ethylene. Nat. Commun. 2011, 2, 204.
doi: 10.1038/ncomms1206
Cui, X.; Chen, K.; Xing, H.; Yang, Q.; Krishna, R.; Bao, Z.; Wu, H.; Zhou, W.; Dong, X.; Han, Y.; Li, B.; Ren, Q.; Zaworotko, M. J.; Chen, B. Pore chemistry and size control in hybrid porous materials for acetylene capture from ethylene. Science 2016, 353, 141-144.
doi: 10.1126/science.aaf2458
Zou, S.; Di, Z.; Li, H.; Liu, Y.; Ji, Z.; Li, H.; Chen, C.; Wu, M.; Hong, M. A stable fluorinated hybrid microporous material for efficient separation of C2-C3 alkyne/alkene mixtures. Inorg. Chem. 2022, 61, 7530-7536.
doi: 10.1021/acs.inorgchem.2c00654
Li, L.; Lin, R. -B.; Krishna, R.; Wang, X.; Li, B.; Wu, H.; Li, J.; Zhou, W.; Chen, B. Efficient separation of ethylene from acetylene/ethylene mixtures by a flexible-robust metal-organic framework. J. Mater. Chem. A 2017, 5, 18984-18988.
doi: 10.1039/C7TA05598F
Wang, J.; Zhang, Y.; Zhang, P.; Hu, J.; Lin, R. B.; Deng, Q.; Zeng, Z.; Xing, H.; Deng, S.; Chen, B. Optimizing pore space for flexible-robust metal-organic framework to boost trace acetylene removal. J. Am. Chem. Soc. 2020, 142, 9744-9751.
doi: 10.1021/jacs.0c02594
Sensharma, D.; O'Hearn, D. J.; Koochaki, A.; Bezrukov, A. A.; Kumar, N.; Wilson, B. H.; Vandichel, M.; Zaworotko, M. J. The first sulfate-pillared hybrid ultramicroporous material, SOFOUR-1-Zn, and its acetylene capture properties. Angew. Chem. Int. Ed. 2021, 134, 202116145.
Zhang, Z.; Yang, Q.; Cui, X.; Yang, L.; Bao, Z.; Ren, Q.; Xing, H. Sorting of C4 olefins with interpenetrated hybrid ultramicroporous materials by combining molecular recognition and size-sieving. Angew. Chem. Int. Ed. 2017, 56, 16282-16287.
doi: 10.1002/anie.201708769
Liu, L.; Yao, Z.; Ye, Y.; Yang, Y.; Lin, Q.; Zhang, Z.; O'Keeffe, M.; Xiang, S. Integrating the pillared-layer strategy and pore-space partition method to construct multicomponent MOFs for C2H2/CO2 separation. J. Am. Chem. Soc. 2020, 142, 9258-9266.
doi: 10.1021/jacs.0c00612
Fan, W.; Yuan, S.; Wang, W.; Feng, L.; Liu, X.; Zhang, X.; Wang, X.; Kang, Z.; Dai, F.; Yuan, D.; Sun, D.; Zhou, H. C. Optimizing multivariate metal-organic frameworks for efficient C2H2/CO2 separation. J. Am. Chem. Soc. 2020, 142, 8728-8737.
doi: 10.1021/jacs.0c00805
Yang, H.; Trieu, T. X.; Zhao, X.; Wang, Y.; Wang, Y.; Feng, P.; Bu, X. Lock-and-key and shape-memory effects in an unconventional synthetic path to magnesium metal-organic frameworks. Angew. Chem. Int. Ed. 2019, 58, 11757-11762.
doi: 10.1002/anie.201905876
Ye, Y.; Ma, Z.; Lin, R. B.; Krishna, R.; Zhou, W.; Lin, Q.; Zhang, Z.; Xiang, S.; Chen, B. Pore space partition within a metal-organic framework for highly efficient C2H2/CO2 separation. J. Am. Chem. Soc. 2019, 141, 4130-4136.
doi: 10.1021/jacs.9b00232
Yao, Q. X.; Tian, M. M.; Wang, Y.; Meng, Y. J.; Wang, J.; Yao, Q. Y.; Zhou, X.; Yang, H.; Wang, H. W.; Li, Y. W.; Zhang, J. A robust, waterstable, and multifunctional praseodymium-organic framework showing permanent porosity, CO2 adsorption properties, and selective sensing of Fe3+ ion. Chin. J. Struct. Chem. 2020, 39, 1862-1870.
Matsuda, R.; Kitaura, R.; Kitagawa, S.; Kubota, Y.; Belosludov, R. V.; Kobayashi, T. C.; Sakamoto, H.; Chiba, T.; Takata, M.; Kawazoe, Y.; Mita, Y. Highly controlled acetylene accommodation in a metal-organic microporous material. Nature 2005, 436, 238-241.
doi: 10.1038/nature03852
Luo, F.; Yan, C.; Dang, L.; Krishna, R.; Zhou, W.; Wu, H.; Dong, X.; Han, Y.; Hu, T. L.; O'Keeffe, M.; Wang, L.; Luo, M.; Lin, R. B.; Chen, B. UTSA-74: a MOF-74 isomer with two accessible binding sites per metal center for highly selective gas separation. J. Am. Chem. Soc. 2016, 138, 5678-5684.
doi: 10.1021/jacs.6b02030
Lin, R. B.; Li, L.; Wu, H.; Arman, H.; Li, B.; Lin, R. G.; Zhou, W.; Chen, B. Optimized separation of acetylene from carbon dioxide and ethylene in a microporous material. J. Am. Chem. Soc. 2017, 139, 8022-8028.
doi: 10.1021/jacs.7b03850
Li, H.; Liu, C.; Chen, C.; Di, Z.; Yuan, D.; Pang, J.; Wei, W.; Wu, M.; Hong, M. An unprecedented pillar-cage fluorinated hybrid porous framework with highly efficient acetylene storage and separation. Angew. Chem. Int. Ed. 2021, 60, 7547-7552.
doi: 10.1002/anie.202013988
Niu, Z.; Cui, X.; Pham, T.; Verma, G.; Lan, P. C.; Shan, C.; Xing, H.; Forrest, K. A.; Suepaul, S.; Space, B.; Nafady, A.; Al-Enizi, A. M.; Ma, S. A MOF-based ultra-strong acetylene nano-trap for highly efficient C2H2/CO2 separation. Angew. Chem. Int. Ed. 2021, 60, 5283-5288.
doi: 10.1002/anie.202016225
Di, Z.; Liu, C.; Pang, J.; Chen, C.; Hu, F.; Yuan, D.; Wu, M.; Hong, M. Cage-like porous materials with simultaneous high C2H2 storage and excellent C2H2/CO2 separation performance. Angew. Chem. Int. Ed. 2021, 60, 10828-10832.
doi: 10.1002/anie.202101907
Li, H.; Ji, Z.; Chen, C.; Di, Z.; Liu, Y.; Wu, M. A microporous metalorganic framework for efficient C2H2/CO2 and C2H6/CH4 separation. Cryst. Growth Des. 2021, 21, 2277-2282.
doi: 10.1021/acs.cgd.0c01701
Xu, T.; Jiang, Z.; Liu, P.; Chen, H.; Lan, X.; Chen, D.; Li, L.; He, Y. Immobilization of oxygen atoms in the pores of microporous metal-organic frameworks for C2H2 separation and purification. ACS Appl. Nano. Mater. 2020, 3, 2911-2919.
doi: 10.1021/acsanm.0c00162
Chen, K. -J.; Scott, H. S.; Madden, D. G.; Pham, T.; Kumar, A.; Bajpai, A.; Lusi, M.; Forrest, K. A.; Space, B.; Perry, J. J.; Zaworotko, M. J. Benchmark C2H2/CO2 and CO2/C2H2 separation by two closely related hybrid ultramicroporous materials. Chem 2016, 1, 753-765.
doi: 10.1016/j.chempr.2016.10.009
Shi, Y.; Xie, Y.; Cui, H.; Ye, Y.; Wu, H.; Zhou, W.; Arman, H.; Lin, R. B.; Chen, B. Highly selective adsorption of carbon dioxide over acetylene in an ultramicroporous metal-organic framework. Adv. Mater. 2021, 33, 2105880.
doi: 10.1002/adma.202105880
Gu, Y.; Zheng, J. J.; Otake, K. I.; Shivanna, M.; Sakaki, S.; Yoshino, H.; Ohba, M.; Kawaguchi, S.; Wang, Y.; Li, F.; Kitagawa, S. Host-guest interaction modulation in porous coordination polymers for inverse selective CO2/C2H2 separation. Angew. Chem. Int. Ed. 2021, 60, 11688-11694.
doi: 10.1002/anie.202016673
Zhang, Z.; Peh, S. B.; Krishna, R.; Kang, C.; Chai, K.; Wang, Y.; Shi, D.; Zhao, D. Optimal pore chemistry in an ultramicroporous metal-organic framework for benchmark inverse CO2/C2H2 separation. Angew. Chem. Int. Ed. 2021, 60, 17198-17204.
doi: 10.1002/anie.202106769
Jiang, Z.; Fan, L.; Zhou, P.; Xu, T.; Hu, S.; Chen, J.; Chen, D. -L.; He, Y. An aromatic-rich cage-based MOF with inorganic chloride ions decorating the pore surface displaying the preferential adsorption of C2H2 and C2H6 over C2H4. Inorg. Chem. Front. 2021, 8, 1243-1252.
Fan, L.; Zhou, P.; Wang, X.; Yue, L.; Li, L.; He, Y. Rational construction and performance regulation of an In(III)-tetraisophthalate framework for one-step adsorption-phase purification of C2H4 from C2 hydrocarbons. Inorg. Chem. 2021, 60, 10819-10829.
doi: 10.1021/acs.inorgchem.1c01560
Gu, X. W.; Wang, J. X.; Wu, E.; Wu, H.; Zhou, W.; Qian, G.; Chen, B.; Li, B. Immobilization of Lewis basic sites into a stable ethane-selective MOF enabling one-step separation of ethylene from a ternary mixture. J. Am. Chem. Soc. 2022, 144, 2614-2623.
doi: 10.1021/jacs.1c10973
Wang, H. -T.; Chen, Q.; Zhang, X.; Zhao, Y. -L.; Xu, M. -M.; Lin, R. -B.; Huang, H.; Xie, L. -H.; Li, J. -R. Two isostructural metal-organic frameworks with unique nickel clusters for C2H2/C2H6/C2H4 mixture separation. J. Mater. Chem. A 2022, DOI: 10.1039/D2TA01466A.
doi: 10.1039/D2TA01466A
Chen, K. J.; Madden, D. G.; Mukherjee, S.; Pham, T.; Forrest, K. A.; Kumar, A.; Space, B.; Kong, J.; Zhang, Q. Y.; Zaworotko, M. J. Synergistic sorbent separation for one-step ethylene purification from a fourcomponent mixture. Science 2019, 366, 241-246.
doi: 10.1126/science.aax8666
Cao, J. W.; Mukherjee, S.; Pham, T.; Wang, Y.; Wang, T.; Zhang, T.; Jiang, X.; Tang, H. J.; Forrest, K. A.; Space, B.; Zaworotko, M. J.; Chen, K. J. One-step ethylene production from a four-component gas mixture by a single physisorbent. Nat. Commun. 2021, 12, 6507.
doi: 10.1038/s41467-021-26473-8
Xu, Z.; Xiong, X.; Xiong, J.; Krishna, R.; Li, L.; Fan, Y.; Luo, F.; Chen, B. A robust Th-azole framework for highly efficient purification of C2H4 from a C2H4/C2H2/C2H6 mixture. Nat. Commun. 2020, 11, 3163.
doi: 10.1038/s41467-020-16960-9
Wang, G. -D.; Li, Y. -Z.; Shi, W. -J.; Hou, L.; Wang, Y. -Y.; Zhu, Z. One-step C2H4 purification from ternary C2H6/C2H4/C2H2 mixtures by a robust metal-organic framework with customized pore environment. Angew. Chem. Int. Ed. 2022, DOI: 10.1002/anie.202205427.
doi: 10.1002/anie.202205427
Fei Jin , Bolin Yang , Xuanpu Wang , Teng Li , Noritatsu Tsubaki , Zhiliang Jin . Facilitating efficient photocatalytic hydrogen evolution via enhanced carrier migration at MOF-on-MOF S-scheme heterojunction interfaces through a graphdiyne (CnH2n-2) electron transport layer. Chinese Journal of Structural Chemistry, 2023, 42(12): 100198-100198. doi: 10.1016/j.cjsc.2023.100198
Yaxin Sun , Huiyu Li , Shiquan Guo , Congju Li . Metal-based cathode catalysts for electrocatalytic ORR in microbial fuel cells: A review. Chinese Chemical Letters, 2024, 35(5): 109418-. doi: 10.1016/j.cclet.2023.109418
Fei Yin , Erli Yang , Xue Ge , Qian Sun , Fan Mo , Guoqiu Wu , Yanfei Shen . Coupling WO3−x dots-encapsulated metal-organic frameworks and template-free branched polymerization for dual signal-amplified electrochemiluminescence biosensing. Chinese Chemical Letters, 2024, 35(4): 108753-. doi: 10.1016/j.cclet.2023.108753
Erzhuo Cheng , Yunyi Li , Wei Yuan , Wei Gong , Yanjun Cai , Yuan Gu , Yong Jiang , Yu Chen , Jingxi Zhang , Guangquan Mo , Bin Yang . Galvanostatic method assembled ZIFs nanostructure as novel nanozyme for the glucose oxidation and biosensing. Chinese Chemical Letters, 2024, 35(9): 109386-. doi: 10.1016/j.cclet.2023.109386
Shenghui Tu , Anru Liu , Hongxiang Zhang , Lu Sun , Minghui Luo , Shan Huang , Ting Huang , Honggen Peng . Oxygen vacancy regulating transition mode of MIL-125 to facilitate singlet oxygen generation for photocatalytic degradation of antibiotics. Chinese Chemical Letters, 2024, 35(12): 109761-. doi: 10.1016/j.cclet.2024.109761
Jiajun Wang , Guolin Yi , Shengling Guo , Jianing Wang , Shujuan Li , Ke Xu , Weiyi Wang , Shulai Lei . Computational design of bimetallic TM2@g-C9N4 electrocatalysts for enhanced CO reduction toward C2 products. Chinese Chemical Letters, 2024, 35(7): 109050-. doi: 10.1016/j.cclet.2023.109050
Jing LIANG , Qian WANG , Junfeng BAI . Synthesis and structures of cdq-topological quaternary and (4, 4, 8)-c topological quinary Zn-MOFs with both oxalic acid and triazole ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2186-2192. doi: 10.11862/CJIC.20240177
Bairu Meng , Zongji Zhuo , Han Yu , Sining Tao , Zixuan Chen , Erik De Clercq , Christophe Pannecouque , Dongwei Kang , Peng Zhan , Xinyong Liu . Design, synthesis, and biological evaluation of benzo[4,5]thieno[2,3-d]pyrimidine derivatives as novel HIV-1 NNRTIs. Chinese Chemical Letters, 2024, 35(6): 108827-. doi: 10.1016/j.cclet.2023.108827
Ying Zhao , Yin-Hang Chai , Tian Chen , Jie Zheng , Ting-Ting Li , Francisco Aznarez , Li-Long Dang , Lu-Fang Ma . Size-controlled synthesis and near-infrared photothermal response of Cp* Rh-based metalla[2]catenanes and rectangular metallamacrocycles. Chinese Chemical Letters, 2024, 35(6): 109298-. doi: 10.1016/j.cclet.2023.109298
Lingling Su , Qunyan Wu , Congzhi Wang , Jianhui Lan , Weiqun Shi . Theoretical design of polyazole based ligands for the separation of Am(Ⅲ)/Eu(Ⅲ). Chinese Chemical Letters, 2024, 35(8): 109402-. doi: 10.1016/j.cclet.2023.109402
Hui Li , Yanxing Qi , Jia Chen , Juanjuan Wang , Min Yang , Hongdeng Qiu . Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO2 and selectivity over N2 and CH4. Chinese Chemical Letters, 2024, 35(11): 109659-. doi: 10.1016/j.cclet.2024.109659
Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl2 and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
Xingyan Liu , Chaogang Jia , Guangmei Jiang , Chenghua Zhang , Mingzuo Chen , Xiaofei Zhao , Xiaocheng Zhang , Min Fu , Siqi Li , Jie Wu , Yiming Jia , Youzhou He . Single-atom Pd anchored in the porphyrin-center of ultrathin 2D-MOFs as the active center to enhance photocatalytic hydrogen-evolution and NO-removal. Chinese Chemical Letters, 2024, 35(9): 109455-. doi: 10.1016/j.cclet.2023.109455
Yunjia Jiang , Lingyao Wang , Yuanbin Zhang . Anion pillared MOFs for challenging hydrocarbon separations. Chinese Journal of Structural Chemistry, 2024, 43(11): 100374-100374. doi: 10.1016/j.cjsc.2024.100374
Jie Ma , Jianxiang Wang , Jianhua Yuan , Xiao Liu , Yun Yang , Fei Yu . The regulating strategy of hierarchical structure and acidity in zeolites and application of gas adsorption: A review. Chinese Chemical Letters, 2024, 35(11): 109693-. doi: 10.1016/j.cclet.2024.109693
Wenyi Mei , Lijuan Xie , Xiaodong Zhang , Cunjian Shi , Fengzhi Wang , Qiqi Fu , Zhenjiang Zhao , Honglin Li , Yufang Xu , Zhuo Chen . Design, synthesis and biological evaluation of fluorescent derivatives of ursolic acid in living cells. Chinese Chemical Letters, 2024, 35(5): 108825-. doi: 10.1016/j.cclet.2023.108825
Yongheng Ren , Yang Chen , Hongwei Chen , Lu Zhang , Jiangfeng Yang , Qi Shi , Lin-Bing Sun , Jinping Li , Libo Li . Electrostatically driven kinetic Inverse CO2/C2H2 separation in LTA-type zeolites. Chinese Journal of Structural Chemistry, 2024, 43(10): 100394-100394. doi: 10.1016/j.cjsc.2024.100394
Hongjin Shi , Guoyin Yin , Xi Lu , Yangyang Li . Stereoselective synthesis of 2-deoxy-α-C-glycosides from glycals. Chinese Chemical Letters, 2024, 35(12): 109674-. doi: 10.1016/j.cclet.2024.109674
Jiaxuan Wang , Tonghe Liu , Bingxiang Wang , Ziwei Li , Yuzhong Niu , Hou Chen , Ying Zhang . Synthesis of polyhydroxyl-capped PAMAM dendrimer/silica composites for the adsorption of aqueous Hg(II) and Ag(I). Chinese Chemical Letters, 2024, 35(12): 109900-. doi: 10.1016/j.cclet.2024.109900
Chaochao Wei , Ru Wang , Zhongkai Wu , Qiyue Luo , Ziling Jiang , Liang Ming , Jie Yang , Liping Wang , Chuang Yu . Revealing the size effect of FeS2 on solid-state battery performances at different operating temperatures. Chinese Chemical Letters, 2024, 35(6): 108717-. doi: 10.1016/j.cclet.2023.108717