Citation: Binran Zhao, Yiyi Zhao, Peng Liu, Yulong Men, Xinyu Meng, Yunxiang Pan. Progress and Understanding on Catalysts with Well-defined Interface for Boosting CO₂ Conversion[J]. Chinese Journal of Structural Chemistry, ;2022, 41(4): 220401. doi: 10.14102/j.cnki.0254-5861.2022-0024 shu

Progress and Understanding on Catalysts with Well-defined Interface for Boosting CO₂ Conversion

Binran Zhao ¹ ,
Yiyi Zhao ¹ ,
Peng Liu ² ,
Yulong Men ² ,
Xinyu Meng ² ,
Yunxiang Pan ^2,,

1.
School of Chemical Engineering, Northwest University, Xi'an 710069, China
2.
Department of Chemical Engineering, School of Chemistry and Chemical Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

Corresponding author: Yunxiang Pan, yxpan81@sjtu.edu.cn
Received Date: 5 February 2022
Accepted Date: 22 February 2022

Figures(12)

Catalytic conversion of CO₂ into valuable chemicals like CH₃OH is the most promising way to alleviate CO₂ emission for solving the serious climate change issue. Multi-component catalysts with well-defined interface show outstanding performance in CO₂ conversion due to the synergistic effects and multifunctional properties caused by the well-defined interface. A discharge technique, named as cold plasma, has been recognized as an excellent strategy for tuning catalyst interface properties. The temperature of cold plasma is lower than 200 ⁰C, and can be further lowered to room temperature by simply changing the operation conditions of cold plasma. The lower temperature of cold plasma can well maintain the catalyst structures, especially the porous structures. When conducting cold plasma, in addition to nontoxic working gases like Ar and air, no harmful substances are used. Cold-plasma-prepared catalysts have unique interface properties, and thereby exhibit superior performance in CO₂ conversion over the catalysts prepared by traditional methods. The present review summarizes the progress about the cold-plasma-prepared catalysts for CO₂ conversion, discusses the origin for the outstanding catalytic performance, and proposes the challenges and opportunities for further studies. This will stimulate more deep insights into the cold-plasma-prepared catalysts with well-defined interface properties for achieving more efficient CO₂ conversion.
- carbon dioxide,
- heterogeneous catalysis,
- interface effect,
- noble metal,
- transition metal,
- cold plasma
1. [1]
  Melchionna, M.; Fornasiero, P.; Prato, M.; Bonchio, M. Electrocatalytic CO₂ reduction: role of the cross-talk at nano-carbon interfaces. Energy Environ. Sci. 2021, 14, 5816–5833. doi: 10.1039/D1EE00228G
2. [2]
  Kattel, S.; Liu, P.; Chen, J. G. Tuning selectivity of CO₂ hydrogenation reactions at the metal/oxide interface. J. Am. Chem. Soc. 2017, 139, 9739–9754. doi: 10.1021/jacs.7b05362
3. [3]
  Ma, W.; He, X.; Wang, W.; Xie, S.; Zhang, Q.; Wang, Y. Electrocatalytic reduction of CO₂ and CO to multi-carbon compounds over Cu-based catalysts. Chem. Soc. Rev. 2021, 50, 12897–12914. doi: 10.1039/D1CS00535A
4. [4]
  Chen, J.; Wang, L. Effects of the catalyst dynamic changes and influence of the reaction environment on the performance of electrochemical CO₂ reduction. Adv. Mater. 2021, 2103900.
5. [5]
  Liu, G.; Wong, W. S. Y.; Kraft, M.; Ager, J. W.; Vollmer, D.; Xu, R. Wetting-regulated gas-involving (photo) electrocatalysis: biomimetics in energy conversion. Chem. Soc. Rev. 2021, 50, 10674–10699. doi: 10.1039/D1CS00258A
6. [6]
  Meng, X. Y.; Peng, C.; Jia, J.; Liu, P.; Men, Y. L.; Pan, Y. X. Recent progress and understanding on In₂O₃-based composite catalysts for boosting CO₂ hydrogenation. J. CO₂ Util. 2022, 55, 101844. doi: 10.1016/j.jcou.2021.101844
7. [7]
  Xie, B.; Lovell, E.; Tan, T. H.; Jantarang, S.; Yu, M.; Scott, J.; Amal, R. Emerging material engineering strategies for amplifying photothermal heterogeneous CO₂ catalysis. J. Energy Chem. 2021, 59, 108–125. doi: 10.1016/j.jechem.2020.11.005
8. [8]
  Lu, H.; Tournet, J.; Dastafkan, K.; Liu, Y.; Ng, Y. H.; Karuturi, S. K.; Zhao, C.; Yin, Z. Noble-metal-free multicomponent nanointegration for sustainbale energy conversion. Chem. Rev. 2021, 121, 10271–10366. doi: 10.1021/acs.chemrev.0c01328
9. [9]
  Nam, D. H.; Luna, P. D.; Rosas-Hernández, A.; Thevenon, A.; Li, F.; Agapie, T.; Peters, J. C.; Shekhah, O.; Eddaoudi, M.; Sargent, E. H. Molecular enhancement of heterogeneous CO₂ reduction. Nat. Mater. 2020, 19, 266–276. doi: 10.1038/s41563-020-0610-2
10. [10]
  Mehla, S.; Kandjani, A. E.; Babarao, R.; Lee, A. F.; Periasamy, S.; Wilson, K.; Ramakrishna, S.; Bhargava, S. K. Porous crystalline framworks for thermocatalytic CO₂ reduction: an emerging paradigm. Energy Environ. Sci. 2021, 14, 320–352. doi: 10.1039/D0EE01882A
11. [11]
  Pan, Y. X.; Wang, Z. J.; Cheng, D. G.; Wang Z. Hydrogenation of CO₂ in the absence of noble metals. Greenhouse Gas. Sci. Technol. 2021, 11, 1169–1170.
12. [12]
  De, S.; Dokania, A.; Ramirez, A.; Gascon, J. Advances in the design of heterogeneous catalysts and thermocatalytic processes for CO₂ utilization. ACS Catal. 2020, 10, 14147–14185. doi: 10.1021/acscatal.0c04273
13. [13]
  Wang, Z. J.; Song, H.; Liu, H.; Ye, J. Coupling of solar energy and thermal energy for carbon dioxide reduction: status and prospects. Angew. Chem. Int. Ed. 2020, 59, 8016–8035. doi: 10.1002/anie.201907443
14. [14]
  Ghoussoub, M.; Xia, M.; Duchesne P. N.; Segal, D.; Ozin, G. Principles of photothermal gas-phase heterogeneous CO₂ catalysis. Energy Environ. Sci. 2019, 12, 1122–1142. doi: 10.1039/C8EE02790K
15. [15]
  Sun, R.; Liao, Y.; Bai, S. T.; Zheng, M.; Zhou, C.; Zhang, T.; Sels, B. F. Heterogeneous catalysts for CO₂ hydrogenation to formic acid/formate: from nanoscale to single atom. Energy Environ. Sci. 2021, 14, 1247–1285. doi: 10.1039/D0EE03575K
16. [16]
  Taghvaei, H.; Heravi, M.; Rahimpour, M. R. Synthesis of supported nanocatalysts via novel non-thermal plasma methods and its application in catalytic processes. Plasma Process. Polym. 2017, 14, 1600204. doi: 10.1002/ppap.201600204
17. [17]
  Jia, L. Y.; Farouha, A.; Pinard, L.; Hedan, S.; Comparot, J. D.; Dufour, A.; Ben Tayeb, K.; Batiot-Dupeyrat, C. New routes for complete regeneration of coked zeolite. Appl. Catal. B: Environ. 2017, 219, 82–91. doi: 10.1016/j.apcatb.2017.07.040
18. [18]
  Liu, S.; Winter, L. R.; Chen, J. G. Review of plasma-assisted catalysis for selective generation of oxygenates from CO₂ and CH₄. ACS Catal. 2020, 10, 2855–2871. doi: 10.1021/acscatal.9b04811
19. [19]
  Li, S.; Dang, X.; Yu, X.; Abbas, G.; Zhang, Q.; Cao, L. The application of dielectric barrier discharge non-thermal plasma in VOCs abatement: a review. Chem. Eng. J. 2020, 388, 124275. doi: 10.1016/j.cej.2020.124275
20. [20]
  Liu, L.; Zhang, Z.; Das, S.; Kawi, S. Reforming of tar from biomass gasification in a hybrid catalysis-plasma system: a review. Appl. Catal. B: Environ. 2019, 250, 250–272. doi: 10.1016/j.apcatb.2019.03.039
21. [21]
  Zhang, S.; Oehrlein, G. S. From thermal catalysis to plasma catalysis: a review of surface processes and their characterizations. J. Phys. D: Appl. Phys. 2021, 213001.
22. [22]
  George, A.; Shen, B.; Craven, M.; Wang, Y.; Kang, D.; Wu, C.; Tu, X. A review of non-thermal plasma technology: a novel solution for CO₂ conversion and utilization. Renew. Sust. Energy Rev. 2021, 135, 109702. doi: 10.1016/j.rser.2020.109702
23. [23]
  Van Gessel, B.; Brandenburg, R.; Bruggeman, P. Electron properties and air mixing in radio frequency driven argon plasma jets at atmospheric pressure. Appl. Phys. Lett. 2013, 103, 064103. doi: 10.1063/1.4817936
24. [24]
  Wang, Z.; Zhang, Y.; Neyts, E. C.; Cao, X.; Zhang, X.; Jang, B. W. L.; Liu, C. J. Catalyst preparation with plasmas: how does it work? ACS Catal. 2018, 8, 2093–2110. doi: 10.1021/acscatal.7b03723
25. [25]
  Xu, J.; Zhang, Q.; Guo, F.; Xia, Y.; Tian, H. Coke resistance of Ni-based catalysts enhanced by cold plasma treatment for CH₄-CO₂ reforming: review. Inter. J. Hydrogen Energy 2021, 46, 23174–23189. doi: 10.1016/j.ijhydene.2021.03.245
26. [26]
  Di, L.; Zhang, J.; Zhang, X. A review on the recent progress, challenges, and perspectives of atmospheric-pressure cold plasma for preparation of supported metal catalysts. Plasma Process Polym. 2018, 15, e1700234. doi: 10.1002/ppap.201700234
27. [27]
  Kim, S. H.; Moon, S. Y.; Park, J. Y. Non-colloidal nanocatalysts fabricated using arc plasma deposition and their applications in heterogeneous catalysis and photocatalysis. Top. Catal. 2017, 60, 812–822. doi: 10.1007/s11244-017-0746-8
28. [28]
  Chen, G.; Snyders, R.; Britun, N. CO₂ conversion using catalyst-free and catalyst-assisted plasma-processes: recent progress and understanding. J. CO₂ Util. 2021, 49, 101557. doi: 10.1016/j.jcou.2021.101557
29. [29]
  Snoeckx, R.; Bogaerts, A. Plasma technology-a novel solution for CO₂ conversion? Chem. Soc. Rev. 2017, 46, 5805–5863. doi: 10.1039/C6CS00066E
30. [30]
  Chen, G.; Godfroid, T.; Britun, N.; Georgieva, V.; Delplancke-Ogletree, M. P.; Snyders, R. Plasma-catalytic conversion of CO₂ and CO₂/H₂O in a surface-wave sustained microwave discharge. Appl. Catal. B: Environ. 2017, 214, 114–125. doi: 10.1016/j.apcatb.2017.05.032
31. [31]
  Bian, L.; Zhang, L.; Xia, R.; Li, Z. Enhanced low-temperature CO₂ methanation activity on plasma-prepared Ni-based catalyst. J Nat. Gas Sci. Eng. 2015, 27, 1189–1194. doi: 10.1016/j.jngse.2015.09.066
32. [32]
  Guo, F.; Xu, J. Q.; Chu, W. CO₂ reforming of methane over Mn promoted Ni/Al₂O₃ catalyst treated by N₂ glow discharge plasma. Catal. Today 2015, 256, 124–129. doi: 10.1016/j.cattod.2015.02.036
33. [33]
  Liu, J.; Ma, Q.; Huang, Z.; Liu, G.; Zhang, H. Recent progress in graphene-based noble-metal nanocomposites for electrocatalytic applications. Adv. Mater. 2019, 31, 1800696. doi: 10.1002/adma.201800696
34. [34]
  Zhong, J.; Yang, X.; Wu, Z.; Liang, B.; Huang, Y.; Zhang, T. State of the art and perspectives in heterogeneous catalysis of CO₂ hydrogenation to methanol. Chem. Soc. Rev. 2020, 49, 1385–1413. doi: 10.1039/C9CS00614A
35. [35]
  Zada, A.; Muhammad, P.; Ahmad, W.; Hussain, Z.; Ali, S.; Khan, M.; Khan, Q.; Maqbool, M. Surface plasmonic-assisted photocatalysis and optoelectronic devices with noble metal nanocrystals: design, synthesis and applications. Adv. Funct. Mater. 2020, 30, 1906744. doi: 10.1002/adfm.201906744
36. [36]
  Akhundi, A.; Habibi-Yangjeh, A.; Abitorabi M.; Pouran, S. R. Review on photocatalytic conversion of carbon dioxide to value-added compounds and renewable fuels by graphitic carbon nitride-based photocatalysts. Catal. Rev. 2019, 61, 595–628. doi: 10.1080/01614940.2019.1654224
37. [37]
  Price, C. A. H.; Reina, T. R.; Liu, J. Engineering heterogenous catalysts for chemical CO₂ utilization: lessons from thermal catalysis and advantages of yolk@shell structured nanoreactors. J. Energy Chem. 2021, 57, 304–324. doi: 10.1016/j.jechem.2020.08.061
38. [38]
  Zhang, H.; Cheng, W.; Luan, D.; Lou, X. W. Atomically dispersed reactive centers for electrocatalytic CO₂ reduction and water splitting. Angew. Chem. Int. Ed. 2021, 60, 13177–13196. doi: 10.1002/anie.202014112
39. [39]
  Zou, J. J.; Zhang, Y. P.; Liu, C. J. Reduction of supported noble-metals ions using glow discharge plasma. Langmuir 2006, 22, 11388–11394. doi: 10.1021/la061795b
40. [40]
  Yan, J.; Pan, Y.; Cheetham, A. G.; Lin, Y. A.; Wang, W.; Cui, H.; Liu, C. J. One-step fabrication of self-assembled peptide thin films with highly dispersed noble metal nanoparticles. Langmuir 2013, 29, 16051–16057. doi: 10.1021/la4036908
41. [41]
  Zhao, Y.; Pan, Y. X.; Xie, Y.; Liu, C. J. Carbon dioxide reforming of methane over glow discharge plasma-reduced Ir/Al₂O₃ catalyst. Catal. Commun. 2008, 9, 1558–1562. doi: 10.1016/j.catcom.2007.12.024
42. [42]
  Rui, N.; Wang, Z.; Sun, K.; Ye, J.; Ge, Q.; Liu, C. J. CO₂ hydrogenation to methanol over Pd/In₂O₃: effects of Pd and oxygen vacancy. Appl. Catal. B: Environ. 2017, 218, 488–497. doi: 10.1016/j.apcatb.2017.06.069
43. [43]
  Men, Y. L.; Liu, Y.; Wang, Q.; Luo, Z. H.; Shao, S.; Li, Y. B.; Pan, Y. X. Highly dispersed Pt-based catalysts for selective CO₂ hydrogenation to methanol at atmospheric pressure. Chem. Eng. Sci. 2019, 200, 167–175. doi: 10.1016/j.ces.2019.02.004
44. [44]
  Li, J.; Zhou, Y.; Tang, W.; Zheng, J.; Gao, X.; Wang, N.; Chen, X.; Wei, M.; Xiao, X.; Chu, W. Cold-plasma technique enabled supported Pt single atoms with tunable coordination for hydrogen evolution reaction. Appl. Catal. B: Environ. 2021, 285, 119861. doi: 10.1016/j.apcatb.2020.119861
45. [45]
  Shi, L.; Zhou, Y.; Tan, X.; Qi, S.; Smith, K. J.; Yi, C.; Yang, B.; Liu, S. Dielectric barrier discharge plasma grafting carboxylate groups on Pt/Al₂O₃ catalysts for highly efficient hydrogen release from perhydrodibenzyltoluene. Catal. Sci. Technol. 2022, DOI: 10.1039/d1cy01652k. doi: 10.1039/d1cy01652k
46. [46]
  Men, Y. L.; Liu, P.; Peng, X.; Pan, Y. X. Efficient photocatalytic triggered by thin carbon layers coating on photocatalysis: recent progress and future perspective. Sci. China Chem. 2020, 63, 1416–1427. doi: 10.1007/s11426-020-9767-9
47. [47]
  Chen, S.; Chen, A. Electrochemical reduction of carbon dioxide on Au nanoparticles: an in situ FTIR study. J. Phys. Chem. C 2019, 123, 23898–23906. doi: 10.1021/acs.jpcc.9b04080
48. [48]
  Zhang, T.; Shang, H.; Zhang, B.; Yan, D.; Xiang, X. Ag/ultrathin-layered double hydroxide nanosheets induced by a self-redox strategy for highly selective CO₂ reduction. ACS Appl. Mater. Interfaces 2021, 13, 16536–16544. doi: 10.1021/acsami.1c02737
49. [49]
  Garba, M. D.; Usman, M.; Khan, S.; Shehzad, F.; Galadima, A.; Ehsan, M. F.; Ghanem, A. S.; Humayun, M. CO₂ towards fuels: a review of catalytic conversion of carbon dioxide to hydrocarbons. J. Environ. Chem. Eng. 2021, 9, 104756. doi: 10.1016/j.jece.2020.104756
50. [50]
  Franco, F.; Rettenmaier, C.; Jeon, H. S.; Cuenya, B. R. Transition metal-based catalysts for the electrochemical CO₂ reduction: from atoms and molecules to nanostructured materials. Chem. Soc. Rev. 2020, 49, 6884–6946. doi: 10.1039/D0CS00835D
51. [51]
  Ao, C.; Feng, B.; Qian, S.; Wang, L.; Zhao, W.; Zhai, Y.; Zhang, L. Theoretical study of transition metals supported on g-C₃N₄ as electrochemical catalysts for CO₂ reduction to CH₃OH and CH₄. J. CO₂ Util. 2020, 36, 116–123. doi: 10.1016/j.jcou.2019.11.007
52. [52]
  Wang, D.; Xie, Z.; Porosoff, M. D.; Chen, J. G. Recent advances in carbon dioxide hydrogenation to produce olefins and aromatics. Chem 2021, 7, 2277–2311. doi: 10.1016/j.chempr.2021.02.024
53. [53]
  Dou, S.; Wang, X.; Wang, S. Rational design of transition metal-based materials for highly efficient electrocatalysis. Small Methods 2019, 3, 1800211. doi: 10.1002/smtd.201800211
54. [54]
  Podrojková, N.; Sans, V.; Oriňak, A.; Oriňaková, R. Recent developments in the modeling of heterogeneous catalysts for CO₂ conversion to chemicals. ChemCatChem 2020, 12, 1802–1825. doi: 10.1002/cctc.201901879
55. [55]
  Liu, C. J.; Ye, J.; Jiang, J.; Pan, Y. Progresses in the preparation of coke resistant Ni-based catalyst for steam and CO₂ reforming of methane. ChemCatChem 2011, 3, 529–541. doi: 10.1002/cctc.201000358
56. [56]
  Fu, Z.; Wang, J.; Zhang, N.; Hao, K.; Yang, Z. Effects of substrate defects on the carbon cluster formation in graphene growth on Ni(111) surface. Phys. Lett. A 2014, 378, 3055–3059. doi: 10.1016/j.physleta.2014.08.024
57. [57]
  Liu, P.; Peng, X.; Men, Y. L.; Pan, Y. X. Recent progresses on improving CO₂ adsorption and proton production for enhancing efficiency of photocatalytic CO₂ reduction by H₂O. Green Chem. Eng. 2020, 1, 33-39. doi: 10.1016/j.gce.2020.09.003
58. [58]
  Zhu, X.; Huo, P.; Zhang, Y. P.; Cheng, D. G.; Liu, C. J. Structure and reactivity of plasma treated Ni/Al₂O₃ catalyst for CO₂ reforming of methane. Appl. Catal. B: Environ. 2008, 81, 132–140. doi: 10.1016/j.apcatb.2007.11.042
59. [59]
  Marinho, A. L. A.; Toniolo, F. S.; Noronha, F. B.; Epron, F.; Duprez, D.; Bion, N. Highly active and stable Ni dispersed on mesoporous CeO₂-Al₂O₃ catalysts for production of syngas by dry reforming of methane. Appl. Catal. B: Environ. 2021, 281, 119459. doi: 10.1016/j.apcatb.2020.119459
60. [60]
  Zou, J. J.; Liu, C. J.; Zhang, Y. P. Control of the metal-support interface of NiO-loaded photocatalysts via cold plasma treatment. Langmuir 2006, 22, 2334–2339. doi: 10.1021/la052135u
61. [61]
  Pan, Y. X.; Liu, C. J.; Shi, P. Preparation and characterization of coke resistant Ni/SiO₂ catalyst for carbon dioxide reforming of methane. J. Power Sources 2008, 176, 46–53. doi: 10.1016/j.jpowsour.2007.10.039
62. [62]
  Yan, X.; Hu, T.; Liu, P.; Li, S.; Zhao, B.; Zhang, Q.; Jiao, W.; Chen, S.; Wang, P.; Lu, J.; Fan, L.; Deng, X.; Pan, Y. X. Highly efficient and stable Ni/CeO₂-SiO₂ catalyst for dry reforming of methane: effect of interfacial structure of Ni/CeO₂ on SiO₂. Appl. Catal. B: Environ. 2019, 246, 221–231. doi: 10.1016/j.apcatb.2019.01.070
63. [63]
  Jia, X.; Zhang, X.; Rui, N.; Hu, X.; Liu, C. J. Structural effect of Ni/ZrO₂ catalyst on CO₂ methanation with enhanced activity. Appl. Catal. B: Environ. 2019, 244, 159–169. doi: 10.1016/j.apcatb.2018.11.024
64. [64]
  Rui, N.; Zhang, X.; Zhang, F.; Liu, Z.; Cao, X.; Xie, Z.; Zou, R.; Senanayake, S. D.; Yang, Y.; Rodriguez, J. A.; Liu, C. J. Highly active Ni/CeO₂ catalyst for CO₂ methanation: preparation and characterization. Appl. Catal. B: Environ. 2021, 282, 119581. doi: 10.1016/j.apcatb.2020.119581
65. [65]
  Zheng, X.; Wang, H.; Wen, J.; Peng, H. In₂S₃-NiS co-decorated MoO₃@MoS₂ composites for enhancing the solar-light induced CO₂ photoreduction activity. Int. J. Hydrogen Energy 2021, 46, 36848–36858. doi: 10.1016/j.ijhydene.2021.08.161
66. [66]
  Xu, J.; Xia, P.; Zhang, Q.; Guo, F.; Xia, Y.; Tian, H. Coke resistance of Ni-based catalysts enhanced by cold plasma treatment for CH₄-CO₂ reforming: review. Int. J. Hydrogen Energy 2021, 46, 23174–23189. doi: 10.1016/j.ijhydene.2021.03.245
67. [67]
  Sivachandiran, L.; Costa, P. D.; Khacef, A. CO₂ reforming in CH₄ over Ni/γ-Al₂O₃ nano catalysts: effect of cold plasma surface discharge. Appl. Surf. Sci. 2020, 501, 144175. doi: 10.1016/j.apsusc.2019.144175
68. [68]
  Zhao, B.; Liu, P.; Li, S.; Shi, H.; Jia, X.; Wang, Q.; Yang, F.; Song, Z.; Guo, C.; Hu, J.; Chen, Z.; Yan, X.; Ma, X. Bimetallic Ni-Co nanoparticles on SiO₂ as robust catalyst for CO methanation: effect of homogeneity of Ni-Co alloy. Appl. Catal. B: Environ. 2020, 278, 119307. doi: 10.1016/j.apcatb.2020.119307
69. [69]
  Ahmad, F.; Lovell, E. C.; Masood, H.; Cullen, P. J.; Ostrikov, K. K.; Scott, J. A.; Amal, R. Low-temperature CO₂ methanation: synergistic effects in plasma-Ni hybrid catalytic system. ACS Sustainable Chem. Eng. 2020, 8, 1888–1898. doi: 10.1021/acssuschemeng.9b06180
70. [70]
  Wang, B.; Xiong, Y.; Han, Y.; Hong, J.; Zhang, Y.; Li, J.; Jing, F.; Chu, W. Preparation of stable and highly active Ni/CeO₂ catalysts by glow discharge plasma technique for glycerol steam reforming. Appl. Catal. B: Environ. 2019, 249, 257–265. doi: 10.1016/j.apcatb.2019.02.074
71. [71]
  Tang, W.; Li, J.; Zheng, J.; Chu, W.; Wang, N. Atomically dispersed metal sites stabilized on a nitrogen doped carbon carrier via N₂ glow-discharge plasma. Chem. Commun. 2020, 56, 9198–9201. doi: 10.1039/D0CC02949A
72. [72]
  Ronda-Lloret, M.; Wang, Y.; Oulego, P.; Rothenberg, G.; Tu, X. CO₂ hydrogenation at atmospheric pressure and low temperature using plasma-enhanced catalysis over supported cobalt oxide catalysts. ACS Sustainable Chem. Eng. 2020, 8, 17397–17407. doi: 10.1021/acssuschemeng.0c05565
1. [1]
  Kaimin WANG , Xiong GU , Na DENG , Hongmei YU , Yanqin YE , Yulu MA . Synthesis, structure, fluorescence properties, and Hirshfeld surface analysis of three Zn(Ⅱ)/Cu(Ⅱ) complexes based on 5-(dimethylamino) isophthalic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1397-1408. doi: 10.11862/CJIC.20240009
2. [2]
  Rui HUANG , Shengjie LIU , Qingyuan WU , Nanfeng ZHENG . Enhanced selectivity of catalytic hydrogenation of halogenated nitroaromatics by interfacial effects. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 201-212. doi: 10.11862/CJIC.20240356
3. [3]
  Jian Yang , Guang Yang , Zhijie Chen . Capturing carbon dioxide from air by using amine-functionalized metal-organic frameworks. Chinese Journal of Structural Chemistry, 2024, 43(5): 100267-100267. doi: 10.1016/j.cjsc.2024.100267
4. [4]
  Guoliang Gao , Guangzhen Zhao , Guang Zhu , Bowen Sun , Zixu Sun , Shunli Li , Ya-Qian Lan . Recent advancements in noble-metal electrocatalysts for alkaline hydrogen evolution reaction. Chinese Chemical Letters, 2025, 36(1): 109557-. doi: 10.1016/j.cclet.2024.109557
5. [5]
  Zihao Wang , Jing Xue , Zhicui Song , Jianxiong Xing , Aijun Zhou , Jianmin Ma , Jingze Li . Li-Zn alloy patch for defect-free polymer interface film enables excellent protection effect towards stable Li metal anode. Chinese Chemical Letters, 2024, 35(10): 109489-. doi: 10.1016/j.cclet.2024.109489
6. [6]
  Yuan Dong , Mutian Ma , Zhenyang Jiao , Sheng Han , Likun Xiong , Zhao Deng , Yang Peng . Effect of electrolyte cation-mediated mechanism on electrocatalytic carbon dioxide reduction. Chinese Chemical Letters, 2024, 35(7): 109049-. doi: 10.1016/j.cclet.2023.109049
7. [7]
  Yuhao Guo , Na Li , Tingjiang Yan . Tandem catalysis for photoreduction of CO2 into multi-carbon fuels on atomically thin dual-metal phosphochalcogenides. Chinese Journal of Structural Chemistry, 2024, 43(7): 100320-100320. doi: 10.1016/j.cjsc.2024.100320
8. [8]
  Ze Liu , Xiaochen Zhang , Jinlong Luo , Yingjian Yu . Application of metal-organic frameworks to the anode interface in metal batteries. Chinese Chemical Letters, 2024, 35(11): 109500-. doi: 10.1016/j.cclet.2024.109500
9. [9]
  Chunhui Zhang , Jie Wang , Jieyang Zhan , Runmin Yang , Guanggang Gao , Jiayuan Zhang , Linlin Fan , Mengqi Wang , Hong Liu . Highly sensitive hydrazine detection through a novel Raman scattering quenching mechanism enabled by a crystalline and noble metal–free polyoxometalate substrate. Chinese Chemical Letters, 2025, 36(3): 109719-. doi: 10.1016/j.cclet.2024.109719
10. [10]
  Tao Tang , Chen Li , Sipu Li , Zhong Qiu , Tianqi Yang , Beirong Ye , Shaojun Shi , Chunyang Wu , Feng Cao , Xinhui Xia , Minghua Chen , Xinqi Liang , Xinping He , Xin Liu , Yongqi Zhang . One-step constructing advanced N-doped carbon@metal nitride as ultra-stable electrocatalysts via urea plasma under room temperature. Chinese Chemical Letters, 2024, 35(11): 109887-. doi: 10.1016/j.cclet.2024.109887
11. [11]
  Xingxing Jiang , Yuxin Zhao , Yan Kong , Jianju Sun , Shangzhao Feng , Xin Lu , Qi Hu , Hengpan Yang , Chuanxin He . Support effect and confinement effect of porous carbon loaded tin dioxide nanoparticles in high-performance CO₂ electroreduction towards formate. Chinese Chemical Letters, 2025, 36(1): 109555-. doi: 10.1016/j.cclet.2024.109555
12. [12]
  Wenjiang LI , Pingli GUAN , Rui YU , Yuansheng CHENG , Xianwen WEI . C₆₀-MoP-C nanoflowers van der Waals heterojunctions and its electrocatalytic hydrogen evolution performance. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 771-781. doi: 10.11862/CJIC.20230289
13. [13]
  Yuchen Wang , Zhenhao Xu , Kai Yan . Rational design of metal-metal hydroxide interface for efficient electrocatalytic oxidation of biomass-derived platform molecules. Chinese Journal of Structural Chemistry, 2025, 44(1): 100418-100418. doi: 10.1016/j.cjsc.2024.100418
14. [14]
  Yatian Deng , Dao Wang , Jinglan Cheng , Yunkun Zhao , Zongbao Li , Chunyan Zang , Jian Li , Lichao Jia . A new popular transition metal-based catalyst: SmMn₂O₅ mullite-type oxide. Chinese Chemical Letters, 2024, 35(8): 109141-. doi: 10.1016/j.cclet.2023.109141
15. [15]
  Boqiang Wang , Yongzhuo Xu , Jiajia Wang , Muyang Yang , Guo-Jun Deng , Wen Shao . Transition-metal free trifluoromethylimination of alkenes enabled by direct activation of N-unprotected ketimines. Chinese Chemical Letters, 2024, 35(9): 109502-. doi: 10.1016/j.cclet.2024.109502
16. [16]
  Peipei CUI , Xin LI , Yilin CHEN , Zhilin CHENG , Feiyan GAO , Xu GUO , Wenning YAN , Yuchen DENG . Transition metal coordination polymers with flexible dicarboxylate ligand: Synthesis, characterization, and photoluminescence property. Chinese Journal of Inorganic Chemistry, 2024, 40(11): 2221-2231. doi: 10.11862/CJIC.20240234
17. [17]
  Daheng Wen , Weiwei Fang , Yongmei Liu , Tao Tu . Valorization of carbon dioxide with alcohols. Chinese Chemical Letters, 2024, 35(7): 109394-. doi: 10.1016/j.cclet.2023.109394
18. [18]
  Xueyang Zhao , Bangwei Deng , Hongtao Xie , Yizhao Li , Qingqing Ye , Fan Dong . Recent process in developing advanced heterogeneous diatomic-site metal catalysts for electrochemical CO₂ reduction. Chinese Chemical Letters, 2024, 35(7): 109139-. doi: 10.1016/j.cclet.2023.109139
19. [19]
  Shuanglin TIAN , Tinghong GAO , Yutao LIU , Qian CHEN , Quan XIE , Qingquan XIAO , Yongchao LIANG . First-principles study of adsorption of Cl₂ and CO gas molecules by transition metal-doped g-GaN. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1189-1200. doi: 10.11862/CJIC.20230482
20. [20]
  Pengfei Zhang , Qingxue Ma , Zhiwei Jiang , Xiaohua Xu , Zhong Jin . Transition-metal-catalyzed remote meta-C—H alkylation and alkynylation of aryl sulfonic acids enabled by an indolyl template. Chinese Chemical Letters, 2024, 35(8): 109361-. doi: 10.1016/j.cclet.2023.109361

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(465)
HTML views(28)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Progress and Understanding on Catalysts with Well-defined Interface for Boosting CO2 Conversion

Metrics

通讯作者: 陈斌, bchen63@163.com

Progress and Understanding on Catalysts with Well-defined Interface for Boosting CO₂ Conversion