Citation: Yue Zhao, Yachong Liu, Boqiang Miao, Yu Ding, Pujun Jin, Yu Chen. One-dimensional Rhodium-nickel Alloy Assemblies with Nano-dendrite Subunits for Alkaline Methanol Oxidation[J]. Chinese Journal of Structural Chemistry, ;2022, 41(4): 220404. doi: 10.14102/j.cnki.0254-5861.2022-0019 shu

One-dimensional Rhodium-nickel Alloy Assemblies with Nano-dendrite Subunits for Alkaline Methanol Oxidation

Yue Zhao ¹ ,
Yachong Liu ¹ ,
Boqiang Miao ¹ ,
Yu Ding ¹ ,
Pujun Jin ^1,, ,
Yu Chen ^1,,

1.
Key Laboratory of Macromolecular Science of Shaanxi Province, Shaanxi Key Laboratory for Advanced Energy Devices, School of Materials Science and Engineering, Shaanxi Normal University, Xi'an 710062, China

Corresponding author: Pujun Jin, jinpj@snnu.edu.cn Yu Chen, ndchenyu@gmail.com
Received Date: 29 January 2022
Accepted Date: 15 February 2022

Figures(5)

The noble metal rhodium (Rh) nanostructures have wide applications in catalysis and electrocatalysis. In this work, a series of RhNi alloy nanostructures with different Rh/Ni atomic ratios can be synthesized by one-step wet chemical method. By adjusting Rh^III/N^iII feed ratio, high-quality one-dimensional Rh₁Ni₁ alloy nanodendrite assemblies (Rh₁Ni₁-NDs-As) can be synthesized selectively. Electrochemical measurements show that the introduction of Ni can enhance the electroactivity of Rh nanomaterials for methanol oxidation reaction (MOR) in alkaline media. For potential practical application, Rh₁Ni₁-NDs-As reveals improved electroactivity and durability for MOR compared to commercial Rh nanoparticle due to the particular morphology, Ni-doping, high electrochemical active area, and excellent anti-poison ability. Considering the facial synthesis and high electroactivity/durability, Rh₁Ni₁-NDs-As may be promising anode catalysts in direct methanol fuel cells.
- rhodium nanomaterials,
- fuel cells,
- methanol oxidation reaction,
- nanodendrites,
- alloy
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