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Citation: Teng Yan, Xiaojie Zhang, Hua Liu, Zhiliang Jin. CeO2 Particles Anchored to Ni2P Nanoplate for Efficient Photocatalytic Hydrogen Evolution[J]. Chinese Journal of Structural Chemistry, ;2022, 41(1): 220104. doi: 10.14102/j.cnki.0254-5861.2021-0057 shu

CeO2 Particles Anchored to Ni2P Nanoplate for Efficient Photocatalytic Hydrogen Evolution

  • 1.

    School of Chemistry and Chemical Engineering, Ningxia Key Laboratory of Solar Chemical Conversion Technology, Key Laboratory for Chemical Engineering and Technology, State Ethnic Affairs Commission, North Minzu University, Yinchuan 750021, China

  • 2.

    Department of Metallurgical and Chemical Engineering, Jiyuan Vocational and Technical College, Jiyuan 459000, China

  • Corresponding author: Zhiliang Jin, zl-jin@nun.edu.cn
  • Received Date: 16 December 2021
    Accepted Date: 6 January 2022

Figures(5)

  • Photocatalytic hydrogen evolution can convert intermittent and dispersive solar energy into hydrogen with high energy density, which is expected to fundamentally solve the problems of environmental pollution and energy shortages. In this experiment, the performance of the catalyst is modified by introducing cocatalyst and morphology control. Ni(OH)2 nanoflowers are used as substrates to derive nanoplate stack Ni2P by high-temperature phosphating method, and a great many of CeO2 nanoparticles are anchored in the Ni2P. This unique 3D/0D combination effectively inhibits the agglomeration of CeO2 nanoparticles and shortens the electron transfer path. Secondly, the introduction of metal-like performance of Ni2P broadens the light absorption range of the catalyst and reduces the overpotential of the catalyst, which is a key factor in enhancing the catalytic activity. The design ideas of this experiment have reference significance for the design of efficient and environmentally friendly photocatalysts.
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