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Citation: Jing Zou, Guodong Liao, Jizhou Jiang, Zhiguo Xiong, Saishuai Bai, Haitao Wang, Pingxiu Wu, Peng Zhang, Xin Li. In-situ Construction of Sulfur-doped g-C3N4/defective g-C3N4 Isotype Step-scheme Heterojunction for Boosting Photocatalytic H2 Evolution[J]. Chinese Journal of Structural Chemistry, ;2022, 41(1): 220102. doi: 10.14102/j.cnki.0254-5861.2021-0039 shu

In-situ Construction of Sulfur-doped g-C3N4/defective g-C3N4 Isotype Step-scheme Heterojunction for Boosting Photocatalytic H2 Evolution

  • 1.

    School of Environmental Ecology and Biological Engineering, School of Chemistry and Environmental Engineering, Key Laboratory of Green Chemical Engineering Process of Ministry of Education, Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education, Wuhan Institute of Technology, Wuhan 430205, China

  • 2.

    Key Laboratory of Rare Mineral, Ministry of Natural Resources, Geological Experimental Testing Center of Hubei Province, Wuhan 430034, China

  • 3.

    Semiconductor Electronic Special Gas of Hubei Engineering Research Center, Jingzhou, Hubei 434000, China

  • 4.

    State Center for International Cooperation on Designer Low-Carbon & Environmental Materials (CDLCEM), School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China

  • 5.

    Institute of Biomass Engineering, Key Laboratory of Energy Plants Resource and Utilization, Ministry of Agriculture and Rural Affairs, South China Agricultural University, Guangzhou 510642, China

Figures(6)

  • The rational construction of a high-efficiency step-scheme heterojunctions is an effective strategy to accelerate the photocatalytic H2. Unfortunately, the variant energy-level matching between two different semiconductor confers limited the photocatalytic performance. Herein, a newfangled graphitic-carbon nitride (g-C3N4) based isotype step-scheme heterojunction, which consists of sulfur-doped and defective active sites in one microstructural unit, is successfully developed by in-situ polymerizing N, N-dimethyl-formamide (DMF) and urea, accompanied by sulfur (S) powder. Therein, the polymerization between the amino groups of DMF and the amide group of urea endows the formation of rich defects. The propulsive integration of S-dopants contributes to the excellent fluffiness and dispersibility of lamellar g-C3N4. Moreover, the developed heterojunction exhibits a significantly enlarged surface area, thus leading to the more exposed catalytically active sites. Most importantly, the simultaneous introduction of S-doping and defects in the units of g-C3N4 also results in a significant improvement in the separation, transfer and recombination efficiency of photo-excited electron-hole pairs. Therefore, the resulting isotype step-scheme heterojunction possesses a superior photocatalytic H2 evolution activity in comparison with pristine g-C3N4. The newly afforded metal-free isotype step-scheme heterojunction in this work will supply a new insight into coupling strategies of heteroatoms doping and defect engineering for various photocatalytic systems.
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    1. [1]

      Liao, G. F.; Gong, Y.; Zhang, L.; Gao, H. Y.; Yang, G. J.; Fang, B. Z. Semiconductor polymeric graphitic carbon nitride photocatalysts: the "holy grail" for the photocatalytic hydrogen evolution reaction under visible light. Energ. Environ. Sci. 2019, 12, 2080–2147.  doi: 10.1039/C9EE00717B

    2. [2]

      Liang, Z. Z.; Shen, R. C.; Ng, Y. H.; Zhang, P.; Xiang, Q. J.; Li, X. A review on 2D MoS2 cocatalysts in photocatalytic H2 production. J. Mater. Sci. Technol. 2020, 56, 89–121.  doi: 10.1016/j.jmst.2020.04.032

    3. [3]

      Nasir, J. A.; Munir, A.; Ahmad, N.; ul Haq, T.; Khan, Z.; Rehman, Z. Photocatalytic Z-scheme overall water splitting: recent advances in theory and experiments. Adv. Mater. 2021, 2105195.

    4. [4]

      He, K. L.; Xie, J.; Liu, Z. Q.; Li, N.; Chen, X. B.; Hu, J.; Li, X. Multifunctional Ni3C cocatalyst/g-C3N4 nanoheterojunctions for robust photocatalytic H2 evolution under visible light. J. Mater. Chem. A 2018, 6, 13110–13122.  doi: 10.1039/C8TA03048K

    5. [5]

      Wang, Z.; Li, C.; Domen, K. Recent developments in heterogeneous photocatalysts for solar-driven overall water splitting. Chem. Soc. Rev. 2019, 48, 2109–2125.  doi: 10.1039/C8CS00542G

    6. [6]

      Ganguly, P.; Harb, M.; Cao, Z.; Cavallo, L.; Breen, A.; Dervin, S.; Dionysiou, D. D.; Pillai, S. C. 2D nanomaterials for photocatalytic hydrogen production. ACS Energy Lett. 2019, 4, 1687–1709.  doi: 10.1021/acsenergylett.9b00940

    7. [7]

      Ai, L.; Shi, R.; Yang, J.; Zhang, K.; Zhang, T. R.; Lu, S. Y. Efficient combination of g-C3N4 and CDs for enhanced photocatalytic performance: a review of synthesis, strategies, and applications. Small 2021, 2007523.

    8. [8]

      Fujishima, A.; Honda, K. Electrochemical photolysis of water at a semiconductor electrode. Nature 1972, 238, 37.  doi: 10.1038/238037a0

    9. [9]

      Xing, W. N.; Tu, W. G.; Ou, M.; Wu, S. Y.; Yin, S. M.; Wang, H. J.; Chen, G.; Xu, R. Anchoring active Pt2+/Pt0 hybrid nanodots on g-C3N4 nitrogen vacancies for photocatalytic H2 evolution. ChemSusChem 2019, 12, 2029–2034.  doi: 10.1002/cssc.201801431

    10. [10]

      Liu, J.; Liu, Y.; Liu, N. Y.; Han, Y. Z.; Zhang, X.; Huang, H.; Lifshitz, Y.; Lee, S. T.; Zhong, J.; Kang, Z. H. Metal-free efficient photocatalyst for stable visible water splitting via a two-electron pathway. Science 2015, 347, 970–974.  doi: 10.1126/science.aaa3145

    11. [11]

      Jiang, H.; Xing, Z.; Zhao, T.; Yang, Z.; Wang, K.; Li, Z.; Yang, S.; Xie, L.; Zhou, W. Plasmon Ag nanoparticle/Bi2S3 ultrathin nanobelt/oxygen-doped flower-like MoS2 nanosphere ternary heterojunctions for promoting charge separation and enhancing solar-driven photothermal and photocatalytic performances. Appl. Catal., B: Environ. 2020, 274, 118947.  doi: 10.1016/j.apcatb.2020.118947

    12. [12]

      Hisatomi, T.; Kubota, J.; Domen, K. Recent advances in semiconductors for photocatalytic and photoelectrochemical water splitting. Chem. Soc. Rev. 2014, 43, 7520–7535.  doi: 10.1039/C3CS60378D

    13. [13]

      Jiang, J.; Ou-yang, L.; Zhu, L.; Zheng, A.; Zou, J.; Yi, X.; Tang, H. Dependence of electronic structure of g-C3N4 on the layer number of its nanosheets: a study by Raman spectroscopy coupled with first-principles calculations. Carbon 2014, 80, 213–221.  doi: 10.1016/j.carbon.2014.08.059

    14. [14]

      Xia, P.; Cheng, B.; Jiang, J.; Tang, H. Localized π-conjugated structure and EPR investigation of g-C3N4 photocatalyst. Appl. Surf. Sci. 2019, 487, 335–342.  doi: 10.1016/j.apsusc.2019.05.064

    15. [15]

      Jiang, J.; Li, N.; Zou, J.; Zhou, X.; Eda, G.; Zhang, Q.; Zhang, H.; Li, L. J.; Zhai, T.; Wee, A. T. S. Synergistic additive-mediated CVD growth and chemical modification of 2D materials. Chem. Soc. Rev. 2019, 48, 4639–4654.  doi: 10.1039/C9CS00348G

    16. [16]

      Xu, C. Q.; Zhang, W. D.; Deguchi, K.; Ohki, S.; Shimizu, T.; Ma, R.; Sasaki, T. Construction of a push-pull system in g-C3N4 for efficient photocatalytic hydrogen evolution under visible light. J. Mater. Chem. A 2020, 8, 13299–13310.  doi: 10.1039/C9TA13513H

    17. [17]

      Xia, P.; Cao, S.; Zhu, B.; Liu, M.; Shi, M.; Yu, J.; Zhang, Y. Designing a 0D/2D S-scheme heterojunction over polymeric carbon nitride for visible-light photocatalytic inactivation of bacteria. Angew. Chem. Int. Ed. 2020, 59, 5218–5225.  doi: 10.1002/anie.201916012

    18. [18]

      Wang, Y.; Liu, L.; Ma, T.; Zhang, Y.; Huang, H. 2D graphitic carbon nitride for energy conversion and storage. Adv. Funct. Mater. 2021, 31, 2102540.  doi: 10.1002/adfm.202102540

    19. [19]

      Tu, W.; Xu, Y.; Wang, J.; Zhang, B.; Zou, T.; Yin, S.; Wu, S.; Li, C.; Huang, Y.; Zhou, Y.; Robertson, J.; Kraft, M.; Xu, R. Investigating the role of tunable nitrogen vacancies in graphitic carbon nitride nanosheets for efficient visible-light-driven H2 evolution and CO2 reduction. ACS Sustain. Chem. Eng. 2017, 5, 7260–7268.  doi: 10.1021/acssuschemeng.7b01477

    20. [20]

      Che, W.; Cheng, W.; Yao, T.; Tang, F.; Liu, W.; Su, H.; Huang, Y.; Liu, Q.; Liu, J.; Hu, F.; Pan, Z.; Sun, Z.; Wei, S. Fast photoelectron transfer in (Cring)-C3N4 plane heterostructural nanosheets for overall water splitting. J. Am. Chem. Soc. 2017, 139, 3021–3026.  doi: 10.1021/jacs.6b11878

    21. [21]

      Luo, J.; Wang, M.; Chen, L.; Shi, J. Efficient benzaldehyde photosynthesis coupling photocatalytic hydrogen evolution. J. Energy Chem. 2022, 66, 52–60.  doi: 10.1016/j.jechem.2021.07.017

    22. [22]

      Liang, J.; Yang, X.; Wang, Y.; He, P.; Fu, H.; Zhao, Y.; Zou, Q.; An, X. A review on g-C3N4 incorporated with organics for enhanced photocatalytic water splitting. J. Mater. Chem. A 2021, 9, 12898–12922.  doi: 10.1039/D1TA00890K

    23. [23]

      Yang, W.; Ma, G.; Fu, Y.; Peng, K.; Yang, H.; Zhan, X.; Yang, W.; Wang, L.; Hou, H. Rationally designed Ti3C2 MXene@TiO2/CuInS2 Schottky/S-scheme integrated heterojunction for enhanced photocatalytic hydrogen evolution. Chem. Eng. J. 2022, 429, 132381.  doi: 10.1016/j.cej.2021.132381

    24. [24]

      Yan, J.; Wang, T.; Qiu, S.; Song, Z.; Zhu, W.; Liu, X.; Lian, J.; Sun, C.; Li, H. Insights into the efficient charge separation over Nb2O5/2D-C3N4 heterostructure for exceptional visible-light driven H2 evolution. J. Energy Chem. 2022, 65, 548–555.  doi: 10.1016/j.jechem.2021.06.030

    25. [25]

      Xi, Y.; Chen, W.; Dong, W.; Fan, Z.; Wang, K.; Shen, Y.; Tu, G.; Zhong, S.; Bai, S. Engineering an interfacial facet of S-scheme heterojunction for improved photocatalytic hydrogen evolution by modulating the internal electric field. ACS Appl. Mater. Interfaces 2021, 13, 39491–39500.  doi: 10.1021/acsami.1c11233

    26. [26]

      Gogoi, D.; Shah, A. K.; Rambabu, P.; Qureshi, M.; Golder, A. K.; Peela, N. R. Step-scheme heterojunction between CdS nanowires and facet-selective assembly of MnOx-BiVO4 for an efficient visible-light-driven overall water splitting. ACS Appl. Mater. Interfaces 2021, 13, 45475–45487.  doi: 10.1021/acsami.1c11740

    27. [27]

      Zou, J.; Deng, W.; Jiang, J.; Arramel; He, X.; Li, N.; Fang, J.; Hsu, J. P. Built-in electric field-assisted step-scheme heterojunction of carbon nitride-copper oxide for highly selective electrochemical detection of p-nonylphenol. Electrochim. Acta 2020, 354, 136658.  doi: 10.1016/j.electacta.2020.136658

    28. [28]

      Li, Y. F.; Zhou, M. H.; Cheng, B.; Shao, Y. Recent advances in g-C3N4-based heterojunction photocatalysts. J. Mater. Sci. Technol. 2020, 56, 1–17.  doi: 10.1016/j.jmst.2020.04.028

    29. [29]

      Wageh, S.; Al-Ghamdi, A. A.; Jafer, R.; Li, X.; Zhang, P. A new heterojunction in photocatalysis: S-scheme heterojunction. Chin. J. Catal. 2021, 42, 667–669.  doi: 10.1016/S1872-2067(20)63705-6

    30. [30]

      Xu, Q.; Zhang, L.; Cheng, B.; Fan, J.; Yu, J. S-scheme heterojunction photocatalyst. Chem 2020, 6, 1543–1559.  doi: 10.1016/j.chempr.2020.06.010

    31. [31]

      Wang, Y.; Hao, X.; Zhang, L.; Jin, Z.; Zhao, T. Amorphous Co3S4 nanoparticle-modified tubular g-C3N4 forms step-scheme heterojunctions for photocatalytic hydrogen production. Catal. Sci. Technol. 2021, 11, 943–955.  doi: 10.1039/D0CY02009E

    32. [32]

      Li, X.; Zhang, J.; Huo, Y.; Dai, K.; Li, S.; Chen, S. Two-dimensional sulfur- and chlorine-codoped g-C3N4/CdSe-amine heterostructures nano-composite with effective interfacial charge transfer and mechanism insight. Appl. Catal. B: Environ. 2021, 280, 119452.  doi: 10.1016/j.apcatb.2020.119452

    33. [33]

      Chen, Y.; Su, F.; Xie, H.; Wang, R.; Ding, C.; Huang, J.; Xu, Y.; Ye, L. One-step construction of S-scheme heterojunctions of N-doped MoS2 and S-doped g-C3N4 for enhanced photocatalytic hydrogen evolution. Chem. Eng. J. 2021, 404, 126498.  doi: 10.1016/j.cej.2020.126498

    34. [34]

      Huang, Y.; Mei, F. F.; Zhang, J. F.; Dai, K.; Dawson, G. Construction of 1D/2D W18O49/porous g-C3N4 S-scheme heterojunction with enhanced photocatalytic H2 evolution. Acta Phys. -Chim. Sin. 2022, 38, 2108028.

    35. [35]

      Fu, J.; Xu, Q.; Low, J.; Jiang, C.; Yu, J. Ultrathin 2D/2D WO3/g-C3N4 step-scheme H2-production photocatalyst. Appl. Catal., B: Environ. 2019, 243, 556–565.  doi: 10.1016/j.apcatb.2018.11.011

    36. [36]

      Li, B.; Zhang, B.; Zhang, Y.; Zhang, M.; Huang, W.; Yu, C.; Sun, J.; Feng, J.; Dong, S.; Sun, J. Porous g-C3N4/TiO2 S-scheme heterojunction photocatalyst for visible-light driven H2 production and simultaneous wastewater purification. Int. J. Hydrogen Energy 2021, 46, 32413–32424.  doi: 10.1016/j.ijhydene.2021.07.090

    37. [37]

      Qin, D.; Xia, Y.; Li, Q.; Yang, C.; Qin, Y.; Lv, K. One-pot calcination synthesis of Cd0.5Zn0.5S/g-C3N4 photocatalyst with a step-scheme heterojunction structure. J. Mater. Sci. Technol. 2020, 56, 206–215.  doi: 10.1016/j.jmst.2020.03.034

    38. [38]

      Song, T.; Xie, C.; Matras-Postolek, K.; Yang, P. 2D Layered g-C3N4/WO3/WS2 S-scheme heterojunctions with enhanced photochemical performance. J. Phys. Chem. C 2021, 125, 19382–19393.  doi: 10.1021/acs.jpcc.1c06753

    39. [39]

      Huang, Y.; Liu, J.; Zhao, C.; Jia, X.; Ma, M.; Qian, Y.; Yang, C.; Liu, K.; Tan, F.; Wang, Z.; Li, X.; Qu, S.; Wang, Z. Facile synthesis of defect-modified thin-layered and porous g-C3N4 with synergetic improvement for photocatalytic H2 production. ACS Appl. Mater. Interfaces 2020, 12, 52603–52614.  doi: 10.1021/acsami.0c14262

    40. [40]

      Cui, M.; Cui, K.; Liu, X.; Chen, X.; Chen, Y.; Guo, Z. Roles of alkali metal dopants and surface defects on polymeric carbon nitride in photocatalytic peroxymonosulfate activation towards water decontamination. J. Hazard. Mater. 2022, 424, 127292.  doi: 10.1016/j.jhazmat.2021.127292

    41. [41]

      Yu, G.; Zhao, H.; Xing, C.; Guo, L.; Li, X. Creation of carbon defects and in-plane holes with the assistance of NH4Br to enhance the photocatalytic activity of g-C3N4. Catal. Sci. Technol. 2021, 11, 5349–5359.  doi: 10.1039/D1CY00641J

    42. [42]

      Li, X.; Kang, B.; Dong, F.; Zhang, Z.; Luo, X.; Han, L.; Huang, J.; Feng, Z.; Chen, Z.; Xu, J.; Peng, B.; Wang, Z. Enhanced photocatalytic degradation and H2/H2O2 production performance of S-pCN/WO2.72 S-scheme heterojunction with appropriate surface oxygen vacancies. Nano Energy 2021, 81, 105671.  doi: 10.1016/j.nanoen.2020.105671

    43. [43]

      Chen, L.; Zhu, D.; Li, J.; Wang, X.; Zhu, J.; Francis, P. S.; Zheng, Y. Sulfur and potassium co-doped graphitic carbon nitride for highly enhanced photocatalytic hydrogen evolution. Appl. Catal., B: Environ. 2020, 273, 119050.  doi: 10.1016/j.apcatb.2020.119050

    44. [44]

      Liu, Z.; Zhang, X.; Jiang, Z.; Chen, H. S.; Yang, P. Phosphorus and sulphur co-doping of g-C3N4 nanotubes with tunable architectures for superior photocatalytic H2 evolution. Int. J. Hydrogen Energy 2019, 44, 20042–20055.  doi: 10.1016/j.ijhydene.2019.06.037

    45. [45]

      Lv, H.; Huang, Y.; Koodali, R. T.; Liu, G.; Zeng, Y.; Meng, Q.; Yuan, M. Synthesis of sulfur-doped 2D graphitic carbon nitride nanosheets for efficient photocatalytic degradation of phenol and hydrogen evolution. ACS Appl. Mater. Interfaces 2020, 12, 12656–12667.  doi: 10.1021/acsami.9b19057

    46. [46]

      Wang, H.; Bian, Y.; Hu, J.; Dai, L. Highly crystalline sulfur-doped carbon nitride as photocatalyst for efficient visible-light hydrogen generation. Appl. Catal., B: Environ. 2018, 238, 592–598.  doi: 10.1016/j.apcatb.2018.07.023

    47. [47]

      Wang, H.; Qiu, X.; Peng, Z.; Wang, W.; Wang, J.; Zhang, T.; Jiang, L.; Liu, H. Cobalt-gluconate-derived high-density cobalt sulfides nanocrystals encapsulated within nitrogen and sulfur dual-doped micro/mesoporous carbon spheres for efficient electrocatalysis of oxygen reduction. J. Colloid Interface Sci. 2020, 561, 829–837.  doi: 10.1016/j.jcis.2019.11.065

    48. [48]

      Liu, R.; Tan, K.; Gong, Y.; Chen, Y.; Li, Z.; Xie, S.; He, T.; Lu, Z.; Yang, H.; Jiang, D. Covalent organic frameworks: an ideal platform for designing ordered materials and advanced applications. Chem. Soc. Rev. 2021, 50, 120–242.  doi: 10.1039/D0CS00620C

    49. [49]

      Zou, J.; Wu, S.; Liu, Y.; Sun, Y.; Cao, Y.; Hsu, J. P.; Shen Wee, A. T.; Jiang, J. An ultra-sensitive electrochemical sensor based on 2D g-C3N4/CuO nanocomposites for dopamine detection. Carbon 2018, 130, 652–663.  doi: 10.1016/j.carbon.2018.01.008

    50. [50]

      He, X.; Bai, S.; Jiang, J.; Ong, W. J.; Peng, J.; Xiong, Z.; Liao, G.; Zou, J.; Li, N. Oxygen vacancy mediated step-scheme heterojunction of WO2.9/g-C3N4 for efficient electrochemical sensing of 4-nitrophenol. Chemical Engineering Journal Advances 2021, 8, 100175.  doi: 10.1016/j.ceja.2021.100175

    51. [51]

      Zhao, D.; Wang, Y.; Dong, C.; Huang, Y.; Chen, J.; Xue, F.; Shen, S.; Guo, L. Boron-doped nitrogen-deficient carbon nitride-based Z-scheme heterostructures for photocatalytic overall water splitting. Nat. Energy 2021, 6, 388–397.  doi: 10.1038/s41560-021-00795-9

    52. [52]

      Sun, Y.; Jiang, J.; Liu, Y.; Wu, S.; Zou, J. A facile one-pot preparation of Co3O4/g-C3N4 heterojunctions with excellent electrocatalytic activity for the detection of environmental phenolic hormones. Appl. Surf. Sci. 2018, 430, 362–370.  doi: 10.1016/j.apsusc.2017.06.157

    53. [53]

      Zou, J.; Mao, D.; Wee, A. T. S.; Jiang, J. Micro/nano-structured ultrathin g-C3N4/Ag nanoparticle hybrids as efficient electrochemical biosensors for l-tyrosine. Appl. Surf. Sci. 2019, 467, 608–618.

    54. [54]

      Zou, J.; Mao, D.; Li, N.; Jiang, J. Reliable and selective lead-ion sensor of sulfur-doped graphitic carbon nitride nanoflakes. Appl. Surf. Sci. 2020, 506, 144672.  doi: 10.1016/j.apsusc.2019.144672

    55. [55]

      Song, H.; Liu, X.; Wang, U.; Chen, L.; Zhang, J.; Zhao, C.; He, F.; Dong, P.; Li, B.; Wang, S.; Wang, S.; Sun, H. Synergy of intermolecular donor-acceptor and ultrathin structures in crystalline carbon nitride for efficient photocatalytic hydrogen evolution. J. Colloid Interface Sci. 2022, 607, 1603–1612.  doi: 10.1016/j.jcis.2021.09.088

    56. [56]

      Li, X. B.; Liu, J. Y.; Huang, J. T.; He, C. Z.; Feng, Z. J.; Chen, Z.; Wan, L. Y.; Deng, F. All organic S-scheme heterojunction PDI-Ala/S-C3N4 photo-catalyst with enhanced photocatalytic performance. Acta Phys. -Chim. Sin. 2021, 37, 2010030.

    57. [57]

      Chen, Y.; Su, F.; Xie, H.; Wang, R.; Ding, C.; Huang, J.; Xu, Y.; Ye, L. One-step construction of S-scheme heterojunctions of N-doped MoS2 and S-doped g-C3N4 for enhanced photocatalytic hydrogen evolution. Chem. Eng. J. 2021, 404, 126498.  doi: 10.1016/j.cej.2020.126498

    58. [58]

      He, F.; Meng, A.; Cheng, B.; Ho, W.; Yu, J. Enhanced photocatalytic H2-production activity of WO3/TiO2 step-scheme heterojunction by graphene modification. Chin. J. Catal. 2020, 41, 9–20.  doi: 10.1016/S1872-2067(19)63382-6

    59. [59]

      Ren, D.; Zhang, W.; Ding, Y.; Shen, R.; Jiang, Z.; Lu, X.; Li, X. In situ fabrication of robust cocatalyst-free CdS/g-C3N4 2D-2D step-scheme heterojunctions for highly active H2 evolution. Solar RRL 2020, 4, 1900423.  doi: 10.1002/solr.201900423

    60. [60]

      Cheng, C.; He, B.; Fan, J.; Cheng, B.; Cao, S.; Yu, J. An inorganic/organic S-scheme heterojunction H2-production photocatalyst and its charge transfer mechanism. Adv. Mater. 2021, 33, 2100317.  doi: 10.1002/adma.202100317

    61. [61]

      Xu, Q.; Zhang, L.; Cheng, B.; Fan, J.; Yu, J. S-scheme heterojunction photocatalyst. Chem 2020, 6, 1543–1559.  doi: 10.1016/j.chempr.2020.06.010

    62. [62]

      Xia, P.; Cao, S.; Zhu, B.; Liu, M.; Shi, M.; Yu, J.; Zhang, Y. Designing a 0D/2D S-scheme heterojunction over polymeric carbon nitride for visible-light photocatalytic inactivation of bacteria. Angew. Chem. Int. Ed. 2020, 59, 5218–5225.  doi: 10.1002/anie.201916012

    63. [63]

      Xu, F.; Meng, K.; Cheng, B.; Wang, S.; Xu, J.; Yu, J. Unique S-scheme heterojunctions in self-assembled TiO2/CsPbBr3 hybrids for CO2 photoreduction. Nat. Commun. 2020, 11, 4613.  doi: 10.1038/s41467-020-18350-7

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