Citation: Bing-Ben CHEN, Wen-Zhuo ZHAO, Zi-Bin CHEN, Yi-Hang WEN, Jian-Wen CHENG. Luminescent Tetra-nuclear Lanthanide-titanium-organic Compound Obtained by the Mixed-ligand[J]. Chinese Journal of Structural Chemistry, ;2021, 40(12): 1668-1672. doi: 10.14102/j.cnki.0254-5861.2011-3220 shu

Luminescent Tetra-nuclear Lanthanide-titanium-organic Compound Obtained by the Mixed-ligand

  • Corresponding author: Jian-Wen CHENG, jwcheng@zjnu.cn
  • Received Date: 15 April 2021
    Accepted Date: 14 May 2021

    Fund Project: the NNSF of China 21975224

Figures(3)

  • A new heterometallic lanthanide-titanium-organic compound: [Eu2Ti2(dip)6(dig)2(H3O)2]·solvent (1, dip = diphenylglycolic acid, dig = diglycolic acid) has been synthesized under solvothermal conditions. Compound 1 contains a tetra-nuclear {Eu2Ti2} unit with the mixed ligands of dip and dig. Compound 1 displays intense red luminescence. Furthermore, the IR, PXRD, UV-vis and TGA spectra were also studied.
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      (a) Sheldrick, G. M. SHELXS97, Program for Crystal Structure Solution. University of Göttingen, Göttingen, Germany 1997; (b) Sheldrick, G. M. SHELXL97, Program for Crystal Structure Refinement. University of Göttingen, Göttingen, Germany 1997. (24) Crystal data for 1: monoclinic, P21/c, a = 20.0807(3), b = 19.0807(3), c = 26.9589(5) Å, β = 93.6970(10)o, V = 10307.9(3) Å3, Z = 4, μ = 1.422 mm−1, S = 1.096. The final least-squares refinements converged at R1 (wR2) = 0.0586 (0.1905) and for 18965 reflections with I > 2σ(I).

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      Crystal data for 1: monoclinic, P21/c, a = 20.0807(3), b = 19.0807(3), c = 26.9589(5) Å, β = 93.6970(10)o, V = 10307.9(3) Å3, Z = 4, μ = 1.422 mm−1, S = 1.096. The final least-squares refinements converged at R1 (wR2) = 0.0586 (0.1905) and for 18965 reflections with I > 2σ(I).

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