Citation: Yang LIU, Xue-Li CAO, Wei WANG, Guo-Ling LI, Shun LI, You-Gui HUANG. A Linear Ce^Ⅲ Complex Based on in-situ Generated N-hydroxy-1, 8-naphthalenedicarboximide[J]. Chinese Journal of Structural Chemistry, ;2021, 40(11): 1475-1481. doi: 10.14102/j.cnki.0254-5861.2011-3190 shu

A Linear Ce^Ⅲ Complex Based on in-situ Generated N-hydroxy-1, 8-naphthalenedicarboximide

Yang LIU ^{a, b, c} ,
Xue-Li CAO ^{a, b, c} ,
Wei WANG ^{b, c} ,
Guo-Ling LI ^{b, c} ,
Shun LI ^{b, c} ,
You-Gui HUANG ^{b, c,,}

a.
College of Chemistry, Fuzhou University, Fuzhou 350108, China
b.
CAS Key Laboratory of Design and Assembly of Functional Nanostructures, and Fujian Provincial Key Laboratory of Nanomaterials, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China
c.
Xiamen Institute of Rare Earth Materials, Haixi Institutes, Chinese Academy of Sciences, Xiamen 361021, China

Corresponding author: You-Gui HUANG, yghuang@fjirsm.ac.cn
Received Date: 23 March 2021
Accepted Date: 1 June 2021

Fund Project: NSF of China 21871262NSF of China 21805257NSF of China 21901242NSF of Fujian Province 2019J01130NSF of Fujian Province 2020J05080NSF of Xiamen 3502Z20206080

Figures(5)

A Ce^Ⅲ linear complex of N-hydroxy-1, 8-naphthalenedicarboximide (HL) has been synthesized with acenaphthoquinone dioxime (acndH₂) under solvothermal conditions, in which L is generated by a series of in-situ reactions starting from acndH₂. X-ray crystallography reveals the coordination chains of Ce^Ⅲ ions are assembled into a 3D supramolecular framework via π…π interactions. The title complex has been characterized by IR and UV-Vis spectra and thermogravimetric analysis (TGA). Furthermore, the fluorescent properties study demonstrated a ligand-based emission of the Ce^Ⅲ complex with ~6 nm blue-shift compared with the emisision of the HL ligand.
- N-hydroxy-1,
- 8-naphthalenedicarboximide,
- acenaphthoquinone dioxime,
- rare earth,
- fluorescence complex,
- X-ray crystallography
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沈阳化工大学材料科学与工程学院沈阳 110142

A Linear CeⅢ Complex Based on in-situ Generated N-hydroxy-1, 8-naphthalenedicarboximide

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通讯作者: 陈斌, bchen63@163.com

A Linear Ce^Ⅲ Complex Based on in-situ Generated N-hydroxy-1, 8-naphthalenedicarboximide