Citation: Xun FENG, Ya-Pei SHANG, Li-Ya WANG, Man-Zhou HONG, Hai-Peng FANG, Xin ZHAO, Zhong-Jun LI. A New Manganese Coordination Polymer Based on Azobenzene Tetracarboxylate and Auxiliary Pyridine Ligand: Synthesis, Crystal Structure and Magnetic Property[J]. Chinese Journal of Structural Chemistry, ;2021, 40(2): 217-224. doi: 10.14102/j.cnki.0254-5861.2011-2809 shu

A New Manganese Coordination Polymer Based on Azobenzene Tetracarboxylate and Auxiliary Pyridine Ligand: Synthesis, Crystal Structure and Magnetic Property

a.
College of Chemistry and Chemical Engineering and Henan Key Laboratory of Function Oriented Porous Materials, Luoyang Normal University, Luoyang 471934, China
b.
College of Chemistry and Pharmacy Engineering, Nanyang Normal University, Nanyang 473601, China
c.
College of Chemistry, Zhengzhou University, Zhengzhou 450001, China

Corresponding author: Xun FENG, fengx@lynu.edu.cn; wlya@lynu.edu.cn
Received Date: 16 March 2020
Accepted Date: 2 July 2020

Fund Project: the National Foundation for Science of China U1804131the National Foundation for Science of China 21671114Foundation for Science & Technology Innovation Talents in Henan province 16410010012

Figures(6)

A new manganese coordination polymer (CP) has been synthesized under hydrothermal conditions. It's formula is {Mn₂(Oaobtc)(bpe)(H₂O)₄]}_n, where H₄Oobtc represents oxide azobenzene 2, 2΄, 3, 3΄-tetracarboxyl acid, and bpe is 1,2-bis(4-pyridine) ethylene. It was characterized by elemental analysis, infrared spectrum and X-ray single-crystal diffraction. The coordination polymer crystallizes in the monoclinic system, space group P2₁/c. The central ion was coordinated with H₄Oobtc ligands using bridging model, and carboxylic group connects two adjacent Mn(Ⅱ) ions into dimer units. The oxygen from carboxylates connect these dimer units into a one-dimensional (1D) chain, and N atoms from the bpe further expanded them into three-dimensional (3D) supramolecular edifice, eventually. Variable-temperature magnetic measurements of CP 1 indicate the presence of weak antiferromagnetic exchange between two nearest Mn(Ⅱ) ions with J = –0.367 cm⁻¹.
- acetate bridging,
- manganese(Ⅱ),
- X-ray crystal structure,
- oxidation azoxybenzene-2, 2΄, 3, 3΄-tetracarboxyl acid,
- antiferromagnetic interaction
1. [1]
  Tang, L.; Shi, D. Q.; Wang, Y. L.; Yin, S. Y.; Wang, J. J.; Hou, X. Y. Structures and properties of two pillared-layer Mn(Ⅱ) MOFs with 5-ethyl-pyridine-2,3-dicarboxylate. Chin. J. Struct. Chem. 2019, 38, 1600−1608.
2. [2]
  Yu, Y. Z.; Chang, S. Y.; Han, X.; Chen, G. X.; Xuan, Y. W.; Wu, X. L.; Wang, F. Hydrothermal synthesis, crystal structure and luminescence property of a 2D manganese(Ⅱ) coordination polymer. Chin. J. Struct. Chem. 2019, 38, 147−154.
3. [3]
  Du, Z. Y.; Prosvirin, A. V.; Mao, J. G. Novel manganese(Ⅱ) sulfonate-phosphonates with dinuclear, tetranuclear, and hexanuclear clusters. Inorg. Chem. 2007, 46, 9884−9894. doi: 10.1021/ic701213g
4. [4]
  Zhang, M. B.; Zhang, N.; Hu, R. X. Single and double chainlike manganese coordination polymers of linear ligands: synthesis, structure and magnetism. Chin. J. Struct. Chem. 2019, 38, 301−307.
5. [5]
  Liu, Q.; Yu, L. L.; Wang, Y. Y.; Ji, Z.; Horvat, J.; Cheng, M. L.; Jia, X. Y.; Wang, G. X. Manganese-based layered coordination polymer: synthesis, structural characterization, magnetic property, and electrochemical performance in lithium-ion batteries. Inorg. Chem. 2013, 52, 6, 2817−2822. doi: 10.1021/ic301579g
6. [6]
  Feng, X.; Xu, C.; Wang, Z. Q.; Tang, S. F.; Fu, W. J.; Ji, B. M.; Wang, L. Y. Aerobic oxidation of alcohols and the synthesis of benzoxazoles 2-catalyzed by a cuprocupric coordination colymer (Cu+-CP) assisted by TEMPO. Inorg. Chem. 2015, 54, 2088−2090. doi: 10.1021/ic502884z
7. [7]
  Feng, X.; Tian, A. Q.; Li, T. F.; Wang, L. Y.; Lei, P. P. Hydrothermal synthesis, crystal structure and characterization of a 1D neodymium(Ⅲ) coordination polymer containing the pyridine 2,6-dicarboxylate and oxalate ligands. Russ. J. Coord. Chem. 2011, 37, 823−828.
8. [8]
  Dong, M.; Babalhavaeji, A.; Collins, C. V.; Jarrah, K.; Sadovski, O.; Dai, Q.; Woolley, G. A. Near-infrared photoswitching of azobenzenes under physiological conditions. J. Am. Chem. Soc. 2017, 139, 13483−13486. doi: 10.1021/jacs.7b06471
9. [9]
  Arıcı, M.; Yeşilel, O. Z.; Taş, M. Coordination polymers assembled from 3, 3΄, 5, 5΄-azobenzenetetracarboxylic acid and different bis(imidazole) ligands with varying flexibility. Cryst. Growth Des. 2015, 15, 3024−3031. doi: 10.1021/acs.cgd.5b00432
10. [10]
  Feng, X.; Chen, H. P.; Li, R. F.; Yang, M. T.; Guo, S. L.; Wang, L. Y.; Liang, Q. R.; Li, Z. J. Cationic bipy induced the three dimensional supramolecules based on azoxybenzene tetracarboxylate: structures and NIR luminescence property. Polyhedron 2019, 157, 420−427. doi: 10.1016/j.poly.2018.10.055
11. [11]
  Kitagawa, S.; Kitaura, R.; Noro, S. Functional porous coordination polymers. Angew. Chem. Int. Ed. 2004, 43, 2334−2375. doi: 10.1002/anie.200300610
12. [12]
  Feng, X.; Liu, J.; Li, J.; Ma, L. F.; Wang, L. Y; Ng, S. W.; Qin, G. Z. J. Series of coordination-polymers based on 4-(5-sulfo-quinolin-8-yloxy) phthalate and bipyridinyl coligands: structure diversity and properties. Solid State Chem. 2015, 80, 230−236.
13. [13]
  Gomez, V.; Corbella, M.; Aullon. G. Two temperature-independent spinomers of the dinuclear Mn(Ⅲ) compound [{Mn(H₂O)(phen)}₂(μ-2-ClC₆H₄COO) ₂(μ-O)](ClO₄)₂. Inorg. Chem. 2010, 49, 1471−1480. doi: 10.1021/ic901719t
14. [14]
  Feng, X.; Ling, X. L.; Liu, L.; Wang, Y. A series of 3D lanthanide frameworks constructed from aromatic multi-carboxylate ligand: structural diversity, luminescence and magnetic properties. Dalton Trans. 2013, 42, 10292−10303. doi: 10.1039/c3dt50810b
15. [15]
  Costes, J. P.; Dahan, F.; Donnadieu, B.; Rodriguez Douton, M. J.; Bousseksou, A.; Tuchagues, J. P. Synthesis, structures, and magnetic properties of novel mononuclear, tetranuclear, and 1D chain MnⅢ complexes involving three related asymmetrical trianionic ligands. Inorg. Chem. 2004, 43, 2736−2744. doi: 10.1021/ic0348796
16. [16]
  Tsai, H. L.; Yang, C. I.; Wernsdorfer, W.; Huang, S. H.; Jhan, S. Y.; Liu, M. H.; Lee, G. H. Mn4 single-molecule-magnet-based polymers of a one-dimensional helical chain and a three-dimensional network: syntheses, crystal structures, and magnetic properties. Inorg. Chem. 2012, 51, 13171−13180. doi: 10.1021/ic3014333
17. [17]
  Sheldrick, G. M. SHELXL-2014/7, Program for the Solution of Crystal Structure. University of Göttingen, Germany 2014.
18. [18]
  Sheldrick, G. M. SHELXL-2014/7, Program for the Refinement of Crystal Structure. University of Göttingen, Germany 2014.
19. [19]
  Feng, X.; Wang, J. G.; Liu, B.; Wang, L. Y.; Zhao, J. S.; Weng, N. S. From 2D double decker architecture to 3D Pcu framework with 1D tube: syntheses, structures, luminescent and magnetic studies. Cryst. Growth Des. 2012, 12, 927−938. doi: 10.1021/cg2013717
20. [20]
  Saxena, A.; Kumar, A.; Mozumdar, S. Ni-nanoparticles: an efficient green catalyst for chemo-selective. J. Mol. Catal. A. Chem. 2007, 269, 35−40. doi: 10.1016/j.molcata.2006.12.042
21. [21]
  Bai, R. F.; Feng, X.; Sun, Y. L.; Chen, H.; Qin, G. Z.; Liu, X. F. A silver-organic frameworks based on flexible-aromatic dicarboxylate and bipyridinyl skeletons coligand: crystal structure and luminescence property. J. Inorg. Organomet. Polym. 2016, 26, 512−518. doi: 10.1007/s10904-016-0358-y
22. [22]
  Tao, J.; Yin, X.; Wei, Z. B.; Huang, R. B.; Zheng, L. S. Hydrothermal syntheses, crystal structures and photoluminescent properties of three metal-cluster based coordination polymers containing mixed organic ligands. Eur. J. Inorg. Chem. 2004, 1, 125−133.
23. [23]
  Vologzhanina, A. V.; Zorina-Tikhonova, E. N.; Chistyakov, A. S.; Sidorov, A. A.; Russ, A. A. Intermolecular Interactions in crystals of the photosensitive coordination compounds of zinc(Ⅱ). J. Coord. Chem. 2018, 44, 733−737. doi: 10.1134/S1070328418100111
24. [24]
  Wang, Y. F.; He, C. J. Syntheses, crystal structures and characterization of two coordination polymers based on mixed ligands. Chin. J. Struct. Chem. 2018, 37, 481−489.
25. [25]
  Miao, X. H.; Zhu, L. G. Supramolecular assembly under the control of the chelating ligand for the MnII/bridging ligands/3-sulfobenzoate system and catalytic properties for the disproportionation of hydrogen peroxide. New J. Chem. 2010, 34, 2403−2414. doi: 10.1039/b9nj00428a
26. [26]
  Feng, X.; Chen, J. L.; Bai, R. F.; Wei, J. T.; Chen, X. X. Two unique cobalt-organic frameworks based on substituted imidazole-dicarboxylate and dipyridyl-type ancillary ligands: crystal structures and magnetic properties. Inorg. Chem. Commun. 2016, 66, 41−46. doi: 10.1016/j.inoche.2016.01.002
27. [27]
  Stoicescu, L.; Jeanson, A. C.; Tesouro-Vallina, D. A.; Boudalis, A. K.; Costes, J. P.; Tuchagues. J. P. Structure and properties of dinuclear manganese(Ⅲ) complexes with pentaanionic pentadentate ligands including alkoxo, amido, and phenoxo donors. Inorg. Chem. 2007, 46, 6902−6910. doi: 10.1021/ic062398r
28. [28]
  Miguel, C. L.; Eugenio, C.; Maurici, L. J. 2D and 3D bimetallic oxalate-based ferromagnets prepared by insertion of Mn Ⅲ-salen type complexes. Dalton Trans. 2013, 42, 5100−5110. doi: 10.1039/c3dt32996h
29. [29]
  Hiller, W.; Strahle, J.; Dtaz, A.; Hanack, M.; Hatfield, W. E.; Haar, L. W.; Gutlich, P. Synthesis, structure, and magnetic properties of catena-(.mu.-oxo) (hemiporphyrazinato) iron(Ⅳ), the first polymeric. mu.-oxo-bridged complex of iron. J. Am. Chem. Soc. 1984, 106, 329−335. doi: 10.1021/ja00314a013
30. [30]
  Han, M. L.; Li, S. H.; Ma, L. F.; Wang, L. Y. Syntheses, structures and properties of two manganese(Ⅱ) metal-organic frameworks based on bromoisophthalate and bipyridyl-type co-ligands. Inorg. Chem. 2012, 20, 340−345.
31. [31]
  Ma, L. F.; Han, M. L.; Qin, J. H.; Wang, L. Y.; Du, M. MnII coordination polymers based on bi-, tri-, and tetranuclear and polymeric chain building units: crystal structures and magnetic properties. Inorg. Chem. 2012, 51, 9431−9442. doi: 10.1021/ic3012537
32. [32]
  Ding, S.; Ji, Y. F.; Kang, M. Y.; Du, C. F.; Liu, Z. L.; Liu, C. M. In situ synthesis of manganese(Ⅲ) complexes under control: crystal structure and magnetic properties. Inorg. Chem. Commun. 2012, 21, 96−99. doi: 10.1016/j.inoche.2012.04.022
33. [33]
  Fuller, A. L.; Watkins, R. W.; Dunbar, K. R.; Prosvirin, A. V.; Arif, A. M.; Berreau, L. M. Manganese(Ⅱ) chemistry of a new N3 O-donor chelate ligand: synthesis, X-ray structures, and magnetic properties of solvent-and oxalate-bound complexes. Dalton Trans. 2005, 1891−1896.
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