Citation: YE Yan-Zhu, WU Xin-Jian, ZHANG Xian-Jin, WANG A-Lian. Synthesis, Crystal Structure and Photoluminescent Property of a Novel Dy3+ Coordination Compound Containing Rare (H2O)22 Clusters[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1980-1986. doi: 10.14102/j.cnki.0254-5861.2011-1418 shu

Synthesis, Crystal Structure and Photoluminescent Property of a Novel Dy3+ Coordination Compound Containing Rare (H2O)22 Clusters





  • Corresponding author: YE Yan-Zhu, yanzhuye@126.com
  • Received Date: 15 July 2016

    Fund Project: the Foundation of Fujian Educational Committee JA14348

Figures(5)

  • A novel Dy3+ coordination compound, (H2pipz)(H3O)[Dy(pydc)3]·11H2O (1, pipz=piperazine and H2pydc=pyridine-2,6-dicarboxylic acid), has been hydrothermally synthesized and characterized by X-ray single-crystal diffraction, elemental analysis. It is interesting that the packing structure of compound 1 contains 22-core water clusters. Compound 1 is extended into a threedimensional supramolecular structure via O…H…O hydrogen bonding interactions. Furthermore, the luminescent property of compound 1 was also investigated.
  • 加载中
    1. [1]

      Gu J. Z, Wu J, Lv D. Y, Tang Y, Zhu K, Wu J. Lanthanide coordination polymers based on 5-(2?-carboxylphenyl) nicotinate: syntheses, structure diversity, dehydration/hydration, luminescence and magnetic properties[J]. Dalton Trans., 2013,42:4822-4830. doi: 10.1039/c2dt32674d

    2. [2]

      Zhang F. M, Yan P. F, Zou X. Y, Zhang J. W, Hou G. F, Li G. M. Novel 3D alkali-lanthanide heterometal-organic frameworks with pyrazine-2,3,5,6-tetracarboxylic acid: synthesis, structure, and magnetism[J]. Cryst. Growth Des., 2014,14:2014-2021. doi: 10.1021/cg5001254

    3. [3]

      Wei X. H, Yang L. Y, Liao S. Y, Zhang M, Tian J. L, Du P. Y, Gu W, Liu X. A series of rare earth complexes with novel non-interpenetrating 3D networks: synthesis, structures, magnetic and optical properties[J]. Dalton Trans., 2014,43:5793-5800. doi: 10.1039/c3dt53112k

    4. [4]

      Feng X, Ling X. L, Liu L, Song H. L, Wang L. Y, Ng S. W, Su B. Y. A series of 3D lanthanide frameworks constructed from aromatic multi-carboxylate ligand: structural diversity, luminescence and magnetic properties[J]. Dalton Trans., 2013,42:10292-10303. doi: 10.1039/c3dt50810b

    5. [5]

      Vilela S. M. F, Firmino A. D. G, Mendes R. F, Fernandes J. A, Ananias D, Valente A. A, Ott H, Carlos L. D, Rocha J, Tome J. P. C, Paz F. A. A. Lanthanide-polyphosphonate coordination polymers combining catalytic and photoluminescence properties[J]. Chem. Commun., 2013,49:6400-6402. doi: 10.1039/c3cc42632g

    6. [6]

      Feng, W.; Zhang, Y.; Lü, X.; Hui, Y.; Shi, G.; Zou, D.; Song, J.; Fan, D.; Wong, W. K.; Richard, A. J. Near-infrared (NIR) luminescent homoleptic lanthanide salen complexes Ln4(Salen)4 (Ln = Nd, Yb or Er). CrystEngComm. 2012, 14, 3456-3463.

    7. [7]

      Xu J, Su W. P, Hong M. C. A series of lanthanide secondary building units based metal-organic frameworks constructed by organic pyridine-2,6-dicarboxylate and inorganic sulfate[J]. Cryst. Growth Des., 2011,11:337-346. doi: 10.1021/cg101343k

    8. [8]

      Ye Y. Z, Wu X. J, Wang A. L. Synthesis, structure and property of a novel coordination polymer[J]. J. Struct. Chem., 2014,33:1860-1864.

    9. [9]

      Yang L. R, Song S, Shao C. Y, Zhang W, Zhang H. M, Bu Z. W, Ren T. G. Synthesis, structure and luminescent properties of 3D lanthanide (La(III), Ce(III)) coordination polymers possessing 1D nanosized cavities based on pyridine-2,6-dicarboxylic acid[J]. Synth. Met., 2011,161:1500-1508. doi: 10.1016/j.synthmet.2011.04.016

    10. [10]

      (a) Li, M.; Feng, R.; Huang, Q. Z.; Feng, Y. Q.; Shi, H. Z. Synthesis, crystal structure and luminescent property of a novel lanthanide coordination polymer containing (H2O)20 clusters. Inorg. Chem. Commun. 2014, 50, 8-12. (b) Aghabozorg, H.; Motieiyan, E.; Salimi, A. R.; Mirzaei, M.; Manteghi, F.; Shokrollahi, A.; Derki, S.; Ghadermazi, M.; Sheshmani, S.; Eshtiagh-Hosseini, H. Piperazinediium, Zr(IV) and Ce(IV) pyridine-2,6-dicarboxylates: syntheses, characterizations, crystal structures, ab initio HF, DFT calculations and solution studies. Polyhedron 2010, 29, 1453-1464. (c) Dalai, S.; Rana, A.; Chowdhuri, D. S.; Bera, M.; Zangrando, E. Cubane-like water clusters in a 3D supramolecular network of zinc with pyridine-2,6-dicarboxylic acid and 5-aminotetrazole. Inorg. Chim. Acta 2010, 363, 1052-1055. (d) Deng, D. S.; Liu, P.; Fu, W. J.; Li, L.; Yang, F. X.; Ji, B. M. Metal-organic open frameworks with one-dimension channels assembled with pyridine 2,6-dicarboxylic acid and N-containing auxiliary ligands: syntheses, crystal structures, and physical characterization. Inorg. Chim. Acta 2010, 363, 891-898.

    11. [11]

      Zhu T. Y, Ikarashi K, Ishigaki T, Uematsu K, Toda K, Okawa H, Sato M. Structure and luminescence of sodium and lanthanide(III) coordination polymers with pyridine-2,6-dicarboxylic acid[J]. Inorg. Chim. Acta, 2009,362:3407-3414. doi: 10.1016/j.ica.2009.01.036

    12. [12]

      Deng D. S, Liu P, Fu W. J, Li L, Yang F. X, Ji B. M. Metal-organic open frameworks with one-dimension channels assembled with pyridine 2,6-dicarboxylic acid and N-containing auxiliary ligands: syntheses, crystal structures, and physical characterization[J]. Inorg. Chim. Acta, 2010,363:891-898. doi: 10.1016/j.ica.2009.12.044

    13. [13]

      Dalai S, Rana A, Chowdhuri D. S, Bera M, Zangrando E. Cubane-like water clusters in a 3D supramolecular network of zinc with pyridine-2,6-dicarboxylic acid and 5-aminotetrazole[J]. Inorg. Chim. Acta, 2010,363:1052-1055. doi: 10.1016/j.ica.2009.12.018

    14. [14]

      Zeng X. Z, Zhang A. Y, He C, Li Y. W. Synthesis, structure and thermal properties of two cerium(Ⅳ) complexes with 2,6-pyridinedicarboxylic acid[J]. Chin. J. Inorg. Chem., 2013,29:1557-1562.

    15. [15]

      Sheldrick, G. M. SHELXS-97, Program for Crystal Structure Solution. University of G?ttingen, G?ttingen (Germany) 1997.

    16. [16]

      Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structures. University of G?ttingen, G?ttingen (Germany) 1997.

    17. [17]

      Biswas S, Jena H. S, Goswami S, Sanda S, Konar S. Synthesis and characterization of two lanthanide (Gd3+and Dy3+)-based three-dimensional metal organic frameworks with squashed metallomacrocycle type building blocks and their magnetic, sorption, and fluorescence properties study[J]. Cryst. Growth Des., 2014,14:1287-1295. doi: 10.1021/cg401804e

    18. [18]

      Ghosh S. K. Structure of a discrete hexadecameric water cluster in a metal-organic framework structure[J]. Inorg. Chem., 2004,43:6687-6889.

    19. [19]

      Mao P. D, Yan L. L, Wu W. N, Liu M. Q, Zhou L. H, Fu S. L. Lanthanide (La, Tb, Dy) complexes with quinolinyloxy acetamide ligand: crystal structures and fluorescence properties[J]. Chin. J. Inorg. Chem., 2016,32:1095-1100.

    20. [20]

      Li H. H, Li H, Niu Z, Wang Y. P. Structural diversity of two novel Dy(III) metal-organic frameworks based on binuclear nodes with furan-2,5-dicarboxylic acid: crystal structures and luminescent properties[J]. Inorg. Chem. Commun., 2015,55:103-107. doi: 10.1016/j.inoche.2015.03.013

    21. [21]

      Yang R, He S. Y, Wu W. T, Wen Z. Y, Shi Q. Z, Wang D. Q. Crystal structure, fluorescence characterization of dysprosium(III) multicomponent complex with acylhydrazone and 1,10-phenanthroline[J]. Acta Chimica Sinica, 2004,62:2040-2044.

  • 加载中
    1. [1]

      LU Jiu-FuLIU JuJIANG MinGE Hong-Guanga . Synthesis, Structure and Luminescent Property of a 2D Cd(Ⅱ) Coordination Polymer Based on Mixed-ligands of 1,3-Bis(imidazol)propane and Pyridine-3,5-dicarboxylic Acid. Chinese Journal of Structural Chemistry, 2015, 34(2): 248-252. doi: 10.14102/j.cnki.0254-5861.2011-0449

    2. [2]

      CHEN Chang-JuanZHANG Ai-Jiang . Synthesis, Crystal Structure and Luminescent Properties of a Novel 1D Zigzag Chain Barium(Ⅱ) Coordination Polymer. Chinese Journal of Structural Chemistry, 2015, 34(2): 285-291. doi: 10.14102/j.cnki.0254-5861.2011-0486

    3. [3]

      LU Jiu-FuSHI JuanZHENG NanGUO Xiao-HuaGE Hong-Guang . Synthesis, Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework. Chinese Journal of Structural Chemistry, 2016, 35(2): 319-325. doi: 10.14102/j.cnki.0254-5861.2011-0814

    4. [4]

      LU Jiu-FuSHI JuanZHENG NanGUO Xiao-HuaGE Hong-Guang . Synthesis, Crystal Structure and Luminescent Property of a Ag(Ι) Coordination Polymer with a 3D Sandwich-like Framework. Chinese Journal of Structural Chemistry, 2016, 35(2): 319-325. doi: 10.14102/j.cnki.0254-5861.2011-0814

    5. [5]

      CHEN Yan-MeiGAO QianGAO Dan-DanWANG De-RongLI Ya-HongLIU WeiLI Wu . Synthesis, Structure, and Luminescent Property of a 3-D Strontium Complex [Sr3(pda)2(Hpda)2(H2O)2]n·2nH2O. Chinese Journal of Structural Chemistry, 2014, 33(5): 746-752.

    6. [6]

      DU Xi-GangMI GangLIU Ji-ChunZHANG Jun . A Luminescent Zn(Ⅱ) Supramolecular Coordination Polymer Constructed from 3,4-Thiophenedicarboxylic Acid and Flexible Benzimidazole-based Connector. Chinese Journal of Structural Chemistry, 2014, 33(11): 1597-1602. doi: 10.14102/j.cnki.0254-5861.2011-0315

    7. [7]

      KONG Zhi-GuoGUO Sheng-NanHE Gui-YuanLI Xin-HangJIAO Yu-QiWANG Xiu-Yan . Crystal Structure and Luminescence of a New Two-dimensional Sr(Ⅱ) Coordination Polymer Based on 3,5-Dinitro-salicylic Acid and 1,10-Phenanthroline. Chinese Journal of Structural Chemistry, 2015, 34(8): 1295-1299. doi: 10.14102/j.cnki.0254-5861.2011-0692

    8. [8]

      HAN QianGUO Sheng-NanWANG Xiu-Yan . A New 3D Pb(Ⅱ) Coordination Polymer [Pb(L)]n Based on a Long Flexible Octane-1,8-dicarboxylic Acid: Crystal Structure and Physical Properties. Chinese Journal of Structural Chemistry, 2015, 34(11): 1756-1760. doi: 10.14102/j.cnki.0254-5861.2011-0757

    9. [9]

      YE Yan-ZhuLIN ShenWU Xin-Jian . Synthesis, Structure and Luminescent Property of an Europium(Ⅲ) Coordination Polymer. Chinese Journal of Structural Chemistry, 2014, 33(11): 1649-1654. doi: 10.14102/j.cnki.0254-5861.2011-0372

    10. [10]

      WU Zhen-Dong . Synthesis, Structure and Photoluminescence of a New Pb(II) Coordination Polymer [Pb(1, 4-chdc)(L)]n·nH2OBased on a Flexible 1,4-Cyclohexanedicarboxylic Acid. Chinese Journal of Structural Chemistry, 2016, 35(5): 753-757. doi: 10.14102/j.cnki.0254-5861.2011-0958

    11. [11]

      YANG HuaHU Dao-Dao . Synthesis, Structure, and Luminescent Property of a 3-D Zinc Complex {[Zn8(4-APha)8(CH3COO)8](CH3CH2OH)2}n. Chinese Journal of Structural Chemistry, 2014, 33(7): 1019-1024.

    12. [12]

      YE Yan-ZhuWU Xin-JianWANG A-Lian . Synthesis, Structure and Property of a Novel Coordination Polymer [Tb(C7H3NO4)(C6H4NO2)(H2O)]. Chinese Journal of Structural Chemistry, 2014, 33(12): 1860-1864. doi: 10.14102/j.cnki.0254-5861.2011-0534

    13. [13]

      ZHAI Ji-QuanZHANG YuCHENG Jian-KaiYANG Jin-XiaZHANG XinbQIN Ye-YanYAO Yuan-Gen . Synthesis, Structure and Luminescent Property of a New Zinc(II) Complex. Chinese Journal of Structural Chemistry, 2016, 34(10): 1513-1518. doi: 10.14102/j.cnki.0254-5861.2011-0710

    14. [14]

      ZHU Xiao-FeiWANG NingXIE Xiao-YanHOU Rui-BinZHOU De-FengLI Ya-FengHU JunLI Xin-YuanLIU HeNIE Wang . A New 3D Metal-organic Framework with Tetranuclear Cadmium(Ⅱ) Clusters:Synthesis, Structure, and Luminescent Property. Chinese Journal of Structural Chemistry, 2014, 33(2): 277-283.

    15. [15]

      ZHANG TianLI Rong-FangTIAN Ai-QinFENG XunTIAN Pan-Hao . Synthesis, Crystal Structure and Luminescent Property of Ladder-shaped Zinc Coordination Polymer with Mixed Polyfunctional Ligands. Chinese Journal of Structural Chemistry, 2016, 35(7): 1122-1128. doi: 10.14102/j.cnki.0254-5861.2011-1019

    16. [16]

      LIN Yu-QingGAO MinZHANG HuiPENG XueGU WenLIU XinLIAO Sheng-Yun . Syntheses, Structures and Luminescent Properties of 3D Ni(Ⅱ)-Ln(Ⅲ) Heterometallic Coordination Polymers Constructed from the Triazol-Based Ligand. Chinese Journal of Inorganic Chemistry, 2018, 34(9): 1600-1609. doi: 10.11862/CJIC.2018.194

    17. [17]

      . Pb(Ⅱ) Coordination Complexes Based on 5-Methyl-1H-pyrazole-3-carboxylic Acid: Syntheses, Structures and Luminescent Properties. Chinese Journal of Inorganic Chemistry, 2019, 35(4): 687-694. doi: 10.11862/CJIC.2019.084

    18. [18]

      JIANG Zheng-JingYIN Jing-ZhouLI Rong-QingZHANG Zai-ChaoLU Lu-De . Syntheses, Structures and Luminescent Properties of Two Zinc(Ⅱ) Coordination Polymers Constructed by Acetate and Pyridyl-Containing Ligands. Chinese Journal of Inorganic Chemistry, 2018, 34(4): 719-727. doi: 10.11862/CJIC.2018.086

    19. [19]

      YANG HeJIANG YangXU BoLI Cun-Cheng . Synthesis, Crystal Structure and Luminescent Property of a New Indium(III) Coordination Polymer. Chinese Journal of Structural Chemistry, 2016, 35(11): 1723-1727. doi: 10.14102/j.cnki.0254-5861.2011-1153

    20. [20]

      XU BoLI LingLI JieLI Cun-Cheng . Crystal Structure and Luminescent Property of a Coordination Complex Constructed with Pyrazine and 1,4-Phenylenediacetic Acid. Chinese Journal of Structural Chemistry, 2014, 33(12): 1826-1830. doi: 10.14102/j.cnki.0254-5861.2011-0378

Metrics
  • PDF Downloads(0)
  • Abstract views(3168)
  • HTML views(51)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return