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Citation: YE Yan-Zhu, WU Xin-Jian, ZHANG Xian-Jin, WANG A-Lian. Synthesis, Crystal Structure and Photoluminescent Property of a Novel Dy3+ Coordination Compound Containing Rare (H2O)22 Clusters[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1980-1986. doi: 10.14102/j.cnki.0254-5861.2011-1418 shu

Synthesis, Crystal Structure and Photoluminescent Property of a Novel Dy3+ Coordination Compound Containing Rare (H2O)22 Clusters

  • Department of Science Research and Training, Fujian Institute of Education, Fuzhou 350001, China

  • Corresponding author: YE Yan-Zhu, yanzhuye@126.com
  • Received Date: 15 July 2016
    Accepted Date: 27 October 2016

    Fund Project: the Foundation of Fujian Educational Committee JA14348

Figures(5)

  • A novel Dy3+ coordination compound, (H2pipz)(H3O)[Dy(pydc)3]·11H2O (1, pipz=piperazine and H2pydc=pyridine-2,6-dicarboxylic acid), has been hydrothermally synthesized and characterized by X-ray single-crystal diffraction, elemental analysis. It is interesting that the packing structure of compound 1 contains 22-core water clusters. Compound 1 is extended into a threedimensional supramolecular structure via O…H…O hydrogen bonding interactions. Furthermore, the luminescent property of compound 1 was also investigated.
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