Citation: TAN Xiong-Wen, LI Chang-Hong, CHEN Zhi-Hui, LI Heng-Feng, LI Wei. Hydrothermal Synthesis, Crystal Structure and Properties of a 1D Chain Copper(II) Polymer with 3-(2-Pyridiyl)-1H-1,2,4-triazole(Hpt)[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1967-1971. doi: 10.14102/j.cnki.0254-5861.2011-1407 shu

Hydrothermal Synthesis, Crystal Structure and Properties of a 1D Chain Copper(II) Polymer with 3-(2-Pyridiyl)-1H-1,2,4-triazole(Hpt)

TAN Xiong-Wen ^a,b ,
LI Chang-Hong ^a,c ,
CHEN Zhi-Hui ^a ,
LI Heng-Feng ^a,*,, ,
LI Wei ^b,*,,

a.
School of Materials Science and Engineering, Central South University, Changsha 410083, China
b.
Department of Chemistry and Materials Science, Hengyang Normal University, Hengyang 421008, China
c.
Department of Chemical Engineering, Hunan Institute of Technology, Hengyang 421002, China

Corresponding author: LI Heng-Feng, lihf@csu.edu.cn LI Wei, li_weihnxy@163.com
Received Date: 30 June 2016
Accepted Date: 24 October 2016

Fund Project: the Doctoral Scientific Research Foundation of Hengyang Normal University 16D06Key Project of Industrial Science and Technology Support of Hengyang City 2015KG23

Figures(4)

A new 1D copper(II) polymer[Cu(Hpt)(3,5-DMBA)]_n has been hydrothermally synthesized with copper acetate, 3-(pyridin-2-yl)-1,2,4-triazole(Hpt) and 3,5-dimethylbenzoic acid (3,5-DMBA). It crystallizes in triclinic space group P1, with a=8.1974(6), b=8.3280(6), c=12.5021(9)Å, α=84.3320(10), β=71.8870(10), γ=65.4560(10)°, V=737.44(9)Å³, D_c=1.612 g/cm³, Z=2, F(000)=366, GOOF=1.035, R=0.0298 and wR=0.0855. The crystal structure is a one-dimensional (1-D) chain in which the Cu(II) is five-coordinated with square pyramidal geometry. The crystal structure shows that the whole molecule consists of two copper ions bridged by two μ₂-η¹:η⁰-3,5-dimethylbenzoic acid anions and two 3-(pyridin-2-yl)-1,2,4-triazole molecules. The coordination environment of Cu(II) ion is CuO₂N₃. The luminescence and thermal properties of the complex were investigated.
- copper(II) polymer,
- luminescence and thermal properties
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