Citation: TAN Xiong-Wen, LI Chang-Hong, CHEN Zhi-Hui, LI Heng-Feng, LI Wei. Hydrothermal Synthesis, Crystal Structure and Properties of a 1D Chain Copper(II) Polymer with 3-(2-Pyridiyl)-1H-1,2,4-triazole(Hpt)[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1967-1971. doi: 10.14102/j.cnki.0254-5861.2011-1407 shu

Hydrothermal Synthesis, Crystal Structure and Properties of a 1D Chain Copper(II) Polymer with 3-(2-Pyridiyl)-1H-1,2,4-triazole(Hpt)

  • Corresponding author: LI Heng-Feng, lihf@csu.edu.cn LI Wei, li_weihnxy@163.com
  • Received Date: 30 June 2016

    Fund Project: the Doctoral Scientific Research Foundation of Hengyang Normal University 16D06Key Project of Industrial Science and Technology Support of Hengyang City 2015KG23

Figures(4)

  • A new 1D copper(II) polymer[Cu(Hpt)(3,5-DMBA)]n has been hydrothermally synthesized with copper acetate, 3-(pyridin-2-yl)-1,2,4-triazole(Hpt) and 3,5-dimethylbenzoic acid (3,5-DMBA). It crystallizes in triclinic space group P1, with a=8.1974(6), b=8.3280(6), c=12.5021(9)Å, α=84.3320(10), β=71.8870(10), γ=65.4560(10)°, V=737.44(9)Å3, Dc=1.612 g/cm3, Z=2, F(000)=366, GOOF=1.035, R=0.0298 and wR=0.0855. The crystal structure is a one-dimensional (1-D) chain in which the Cu(II) is five-coordinated with square pyramidal geometry. The crystal structure shows that the whole molecule consists of two copper ions bridged by two μ2-η1:η0-3,5-dimethylbenzoic acid anions and two 3-(pyridin-2-yl)-1,2,4-triazole molecules. The coordination environment of Cu(II) ion is CuO2N3. The luminescence and thermal properties of the complex were investigated.
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