Citation: WANG Kai, HUANG Xu-Ke, ZHU Li, CHEN Zi-Lu, LIANG Fu-Pei. A Chain Cadmium(II) Coordination Polymer with Diacylhydrazide: Synthesis, Crystal Structure and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1912-1919. doi: 10.14102/j.cnki.0254-5861.2011-1230 shu

A Chain Cadmium(II) Coordination Polymer with Diacylhydrazide: Synthesis, Crystal Structure and Luminescent Property

WANG Kai ^a ,
HUANG Xu-Ke ^b ,
ZHU Li ^b ,
CHEN Zi-Lu ^b ,
LIANG Fu-Pei ^a,b,*,,

a.
Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China
b.
State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy, Guangxi Normal University, Guilin 541004, China

Corresponding author: LIANG Fu-Pei, fliangoffice@yahoo.com
Received Date: 05 April 2016

Fund Project: the Guangxi Natural Science Foundation 2015GXNSFDA139007, 2014GXNSFBA118055 and 2013GXNSFGA019008the National Natural Science Foundation of China 51572050, 21271050 and 21261004

Figures(9)

A novel Cd(II) coordination polymer with diacylhydrazide ligand N,N'-bis(3-methoxysalicyl)-2,6-pyridinedicarbohydrazide (H₆msphz),[Cd₂(H₂msphz)(Py)₄]_n (1, Py=pyridine) has been synthesized through solvothermal reaction and structurally characterized by single-crystal X-ray diffraction, IR, TGA and PXRD investigations. It crystallizes in triclinic system, space group P1, with a=11.0230(11), b=11.7264(15), c=17.3395(14)Å, α=70.520(9), β=84.806(7), γ=81.965(9)°, V=2089.9(4)Å³, D_c=1.638 g cm^-3, μ=1.083 mm^-1, F(000)=1032, Z=2 and S=1.040. In complex 1, the H₂msphz^4- ligand uses not only its coordinated pocket to catch one Cd(II) ion, but also its two terminal groups to chelate other two Cd(II) ions, leading to the formation of a chain structure. The adjacent chains are further assembled together by two kinds of π-π interactions between the Py rings, resulting in the finial double layered supramolecular structure. In addition, complex 1 is found to show photoluminescence in the solid state at room temperature, which can be ascribed to the intraligand π→π^* transitions.
- coordination polymer,
- diacylhydrazide,
- crystal structure,
- luminescence
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