Citation: WANG Kai, HUANG Xu-Ke, ZHU Li, CHEN Zi-Lu, LIANG Fu-Pei. A Chain Cadmium(II) Coordination Polymer with Diacylhydrazide: Synthesis, Crystal Structure and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1912-1919. doi: 10.14102/j.cnki.0254-5861.2011-1230 shu

A Chain Cadmium(II) Coordination Polymer with Diacylhydrazide: Synthesis, Crystal Structure and Luminescent Property

WANG Kai ^a ,
HUANG Xu-Ke ^b ,
ZHU Li ^b ,
CHEN Zi-Lu ^b ,
LIANG Fu-Pei ^a,b,*,,

a.
Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China
b.
State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy, Guangxi Normal University, Guilin 541004, China

Corresponding author: LIANG Fu-Pei, fliangoffice@yahoo.com
Received Date: 5 April 2016

Fund Project: the Guangxi Natural Science Foundation 2015GXNSFDA139007, 2014GXNSFBA118055 and 2013GXNSFGA019008the National Natural Science Foundation of China 51572050, 21271050 and 21261004

Figures(9)

A novel Cd(II) coordination polymer with diacylhydrazide ligand N,N'-bis(3-methoxysalicyl)-2,6-pyridinedicarbohydrazide (H₆msphz),[Cd₂(H₂msphz)(Py)₄]_n (1, Py=pyridine) has been synthesized through solvothermal reaction and structurally characterized by single-crystal X-ray diffraction, IR, TGA and PXRD investigations. It crystallizes in triclinic system, space group P1, with a=11.0230(11), b=11.7264(15), c=17.3395(14)Å, α=70.520(9), β=84.806(7), γ=81.965(9)°, V=2089.9(4)Å³, D_c=1.638 g cm^-3, μ=1.083 mm^-1, F(000)=1032, Z=2 and S=1.040. In complex 1, the H₂msphz^4- ligand uses not only its coordinated pocket to catch one Cd(II) ion, but also its two terminal groups to chelate other two Cd(II) ions, leading to the formation of a chain structure. The adjacent chains are further assembled together by two kinds of π-π interactions between the Py rings, resulting in the finial double layered supramolecular structure. In addition, complex 1 is found to show photoluminescence in the solid state at room temperature, which can be ascribed to the intraligand π→π^* transitions.
- coordination polymer,
- diacylhydrazide,
- crystal structure,
- luminescence
1. [1]
  Zhang J. P, Zhang Y. B, Lin J. B, Chen X. M. Metal azolate frameworks: from crystal engineering to functional materials[J]. Chem. Rev., 2012,112:1001-1033. doi: 10.1021/cr200139g
2. [2]
  Kudo A, Miseki Y. Heterogeneous photocatalyst materials for water splitting[J]. Chem. Soc. Rev., 2009,38:253-278. doi: 10.1039/B800489G
3. [3]
  Zhao J. P, Han S. D, Zhao R, Yang Q, Chang Z, Bu X. H. Tuning the structure and magnetism of heterometallic sodium(1+)-cobalt(2+) formate coordination polymers by varying the metal ratio and solvents[J]. Inorg. Chem., 2013,52:2862-2869. doi: 10.1021/ic301936k
4. [4]
  Rocha J, Carlos L. D, Paz F. A. A, Ananias D. Luminescent multifunctional lanthanides-based metal-organic frameworks[J]. Chem. Soc. Rev., 2011,40:926-940. doi: 10.1039/C0CS00130A
5. [5]
  Carlos L. D, Ferreira R. A. S, Bermudez V. D. Z, Julian-Lopez B, Escribano P. Progress on lanthanide-based organic-inorganic hybrid phosphors[J]. Chem. Soc. Rev., 2011,40:536-549. doi: 10.1039/C0CS00069H
6. [6]
  Cook T. R, Zheng Y. R, Stang P. J. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials[J]. Chem. Rev., 2013,113:734-777. doi: 10.1021/cr3002824
7. [7]
  O'Keeffe M, Yaghi O. M. Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets[J]. Chem. Rev., 2012,112:675-702. doi: 10.1021/cr200205j
8. [8]
  Zhang W. X, Liao P. Q, Lin R. B, Wei Y. S, Zeng M. H, Chen X. M. Metal cluster-based functional porous coordination polymers[J]. Coordin. Chem. Rev., 2015,263.
9. [9]
  Xiang S. C, Hu S. M, Sheng T. L, Chen J. S, Wu X. T. Structural diversity of infinite 3d-4f heterometallic cluster compounds driven by various lanthanide radii[J]. Chem. Eur. J., 2009,15:12496-12502. doi: 10.1002/chem.200900520
10. [10]
  Wang K, Chen Z. L, Zou H. H, Zhang Z, Sun W. Y, Liang F. P. Two types of Cu-Ln heterometallic coordination polymers with 2-hydroxyisophthalate: syntheses, structures, and magnetic properties[J]. Cryst. Growth Des., 2015,15:2883-2890. doi: 10.1021/acs.cgd.5b00327
11. [11]
  Prakash M. J, Lah M. S. Metal-organic macrocycles, metal-organic polyhedra and metal-organic frameworks[J]. Chem. Commun., 2009,3326.
12. [12]
  Kurmoo M. Magnetic metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1353-1379. doi: 10.1039/b804757j
13. [13]
  Qin, S. N.; Chen, Z. L.; Liu, D. C.; Huang, W. Y.; Liang, F. P. A 1D copper(II) chain featuring novel hexanuclear secondary building blocks: synthesis, crystal structure and magnetic property. Inorg. Chem. Commun. 2011, 14, 784-787.
14. [14]
  Qin S. N, Chen Z. L, Liu D. C, Huang W. Y, Liang F. P. Synthesis, crystal structure, and luminescent properties of metal complexes bearing 2,6-pyridine-diacylhydrazide ligands: supramolecular assemblies via intermolecular interactions[J]. Trans. Met. Chem., 2011,36:369-378. doi: 10.1007/s11243-011-9479-x
15. [15]
  G uo, Y. N, X u, G. F, Gamez P, Zhao L, Lin S. Y, Deng R, Tang J. K, Zhang H. J. Two-step relaxation in a linear tetranuclear dysprosium(III) aggregate showing single-molecule magnet behavior[J]. J. Am. Chem. Soc., 2010,132:8538-8539. doi: 10.1021/ja103018m
16. [16]
  Sheldrick, G. M. SHELXS-97, Program for Crystal Structure Solution. University of G?ttingen 1997.
17. [17]
  Sheldrick, G. M. SHELXL 97, Program for the Refinement of Crystal Structure. University of G?ttingen 1997.
18. [18]
  Dolomanov, O. V.; Bourthis, L. J.; Gildea, R. L.; Howard, J. A. K.; Puschmann, H. J. OLEX2: a complete structure solution, refinement and analysis program. Appl. Crystallogr. 2009, 42, 339-341.
19. [19]
  Wang K, Zou H. H, Chen Z. L, Zhang Z, Sun W. Y, Liang F. P. A series of 3D metal organic frameworks based on[J]. Dalton Trans., 2014,43:12989-12995. doi: 10.1039/C4DT01593B
20. [20]
  Zh ao, S. N, Su S. Q, Song X. Z, Zhu M, Hao Z. M, Meng X, Song S. Y, Zhang H. J. A series of metal-organic frameworks constructed from a V-shaped tripodal carboxylate ligand: syntheses, structures, photoluminescent, and magnetic properties[J]. Cryst. Growth Des., 2013,13:2756-2765. doi: 10.1021/cg3018387
21. [21]
  Singh R, Bharadwaj P. K. Coordination polymers built with a linear bis-imidazole and different dicarboxylates: unusual entanglement and emission properties[J]. Cryst. Growth Des., 2013,13:3722-3733. doi: 10.1021/cg400756z
22. [22]
  Liu C. S, Wang J. J, Chang Z, Yan L. F, Bu X. H. Cadmium(II) coordination polymers based on a bulky anthracene-based dicarboxylate ligand: crystal structures and luminescent properties[J]. CrystEngComm., 2010,12:1833-1841. doi: 10.1039/b923516g
23. [23]
  Zheng S. L, Yang J. H, Yu X. L, Chen X. M, Wong W. T. Syntheses, structures, photoluminescence, and theoretical studies of d(10) metal complexes of 2,2'-dihydroxy-[J]. Inorg. Chem., 2004,43:830-838. doi: 10.1021/ic034847i
1. [1]
  KONG Zhi-Guo , WANG Wei , ZHANG Bing . Synthesis, Crystal Structure and Luminescence of a New Two-dimensional Pb(II) Coordination Polymer. Chinese Journal of Structural Chemistry, 2016, 34(10): 1503-1507. doi: 10.14102/j.cnki.0254-5861.2011-0715
2. [2]
  GONG Ya-Qiong , MI Tao-Qing , JIANG Fei-Long . Synthesis, Crystal Structure and Photoluminescence of a Zn(Ⅱ) Coordination Polymer Derived from 1,1'-Biphenyl-2,2',6,6'-tetracarboxylic Acid. Chinese Journal of Structural Chemistry, 2015, 34(7): 1087-1091. doi: 10.14102/j.cnki.0254-5861.2011-0587
3. [3]
  GUO Feng . A Novel 6-Connected Self-interpenetrated Zn(II) Coordination Polymer Based on 1,4-Bis(2-methylimidazole-3-ium-1-yl)biphenyl and Dicarboxylate Ligand: Synthesis, Crystal Structure and Luminescent Property. Chinese Journal of Structural Chemistry, 2016, 34(10): 1579-1584. doi: 10.14102/j.cnki.0254-5861.2011-0697
4. [4]
  KONG Zhi-Guo , GUO Sheng-Nan , YU Miao , FENG Si-Yang , HU Bo . A New Luminescent Cd(II) Coordination Polymer Constructed by Mixed 1,4-Naphthalenedicarboxylate and N-donor Chelating Ligand. Chinese Journal of Structural Chemistry, 2016, 35(4): 591-596. doi: 10.14102/j.cnki.0254-5861.2011-0908
5. [5]
  XU Bo , LI Zhi-Wang , JIANG Yang , LI Cun-Cheng . A Luminescent Cd(II) Coordination Polymer Constructed from Isophthalic Acid and 1,3-Bis-(4-pyridyl)propane. Chinese Journal of Structural Chemistry, 2015, 34(6): 925-930. doi: 10.14102/j.cnki.0254-5861.2011-0638
6. [6]
  GUO Sheng-Nan , ZHAO Xin-Yu , SUN Rong-Ze , ZHANG Yue , MIAO Jia-Qi , KONG Zhi-Guo . A New 1D Cd(Ⅱ) Coordination Polymer Constructed by 2,2'-H₂biimidazole: [Cd(H₂biim)₂(SO₄)]_n·3nH₂O. Chinese Journal of Structural Chemistry, 2014, 33(12): 1796-1800. doi: 10.14102/j.cnki.0254-5861.2011-0361
7. [7]
  WANG Xiu-Yan , LIU Fu-Yi , ZHANG Yan-Na , XU Zhan-Lin . Synthesis, Crystal Structure and Photoluminescence of a New Zn(Ⅱ) Dimer Constructed by 1,10-Phenanthroline Derivative and Flexible Dicarboxylate. Chinese Journal of Structural Chemistry, 2014, 33(1): 33-36.
8. [8]
  XUE Li-Ping , SHAN Li-Li , FENG Wen-Jing . Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology. Chinese Journal of Structural Chemistry, 2016, 35(2): 293-297. doi: 10.14102/j.cnki.0254-5861.2011-0845
9. [9]
  XUE Li-Ping , SHAN Li-Li , FENG Wen-Jing . Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology. Chinese Journal of Structural Chemistry, 2016, 35(2): 293-297. doi: 10.14102/j.cnki.0254-5861.2011-0845
10. [10]
  XIE Yi-Ming ZHAO Yong-Ting . Three Lanthanide Coordination Polymers Based on Novel Rigid Tetracarboxylate Ligand: Syntheses, Crystal Structures, and Luminescence Properties. Chinese Journal of Structural Chemistry, 2015, 34(11): 1723-1728. doi: 10.14102/j.cnki.0254-5861.2011-0743
11. [11]
  KONG Zhi-Guo , GUO Sheng-Nan , HE Gui-Yuan , LI Xin-Hang , JIAO Yu-Qi , WANG Xiu-Yan . Crystal Structure and Luminescence of a New Two-dimensional Sr(Ⅱ) Coordination Polymer Based on 3,5-Dinitro-salicylic Acid and 1,10-Phenanthroline. Chinese Journal of Structural Chemistry, 2015, 34(8): 1295-1299. doi: 10.14102/j.cnki.0254-5861.2011-0692
12. [12]
  JIANG Da-Yu , SUI Wei , LIU Bo , WANG Qing-Wei . A Novel Three-dimensional(4,4)-Connected Coordination Polymer Based on Benzotriazole and Thiophene-2,5-dicarboxylic Acid: Synthesis, Crystal Structure,and Luminescence Properties. Chinese Journal of Structural Chemistry, 2016, 35(9): 1445-1450. doi: 10.14102/j.cnki.0254-5861.2011-1136
13. [13]
  KONG Chun-Yan . Hydrothermal Synthesis, Crystal Structure and Luminescent Property of a New Cd(Ⅱ) Coordination Polymer with Four-fold Interpenetrated dia Topology. Chinese Journal of Structural Chemistry, 2015, 34(2): 267-271. doi: 10.14102/j.cnki.0254-5861.2011-0477
14. [14]
  KONG Zhi-Guo , WANG Wei , BI Hui-Ying , HAN Qian , HE Gui-Yuan , LI Fang-Yuan . A New Two-dimensional Cadmium(II) Coordination Polymer Constructed by 1,10- Phenanthroline Derivative and Flexible Dicarboxylate: Syntheses, Structure, Thermal Behavior and Luminescence. Chinese Journal of Structural Chemistry, 2015, 34(5): 719-724. doi: 10.14102/j.cnki.0254-5861.2011-0544
15. [15]
  WANG Xiu-Yan , LIU Fu-Yi , ZHANG Yan-Na , GENG Li-Rong , ZHOU Hao , XU Zhan-Lin . A New Cadmium(Ⅱ) Coordination Polymer Constructed by 2-(2-Chloro-6-fluorophenyl)-1H-imidazo[4,5-f][1, 10]phenanthroline and 1,2,3-Benzenecarboxylate: Synthesis, Structure and Luminescence. Chinese Journal of Structural Chemistry, 2014, 33(3): 468-472.
16. [16]
  YANG He , JIANG Yang , XU Bo , LI Cun-Cheng . Synthesis, Crystal Structure and Luminescent Property of a New Indium(III) Coordination Polymer. Chinese Journal of Structural Chemistry, 2016, 35(11): 1723-1727. doi: 10.14102/j.cnki.0254-5861.2011-1153
17. [17]
  ZHANG Xu , GE Ming , HECKE Kristof Van , CUI Guang-Hua . Synthesis, Crystal Structure and Catalytic Properties of a 2D Cobalt(Ⅱ) Coordination Polymer Based on Mixed Ligands. Chinese Journal of Structural Chemistry, 2015, 34(4): 599-605. doi: 10.14102/j.cnki.0254-5861.2011-0542
18. [18]
  WANG Peng-Fei , TAO Xiao-Lin , WANG Jin-Ling , WU Guo-Zhi , WANG Xin . A New 2D Layered Barium Coordination Polymer [Ba(3-NPA)]_n: Synthesis, Crystal Structure, Thermal Stability and Luminescent Properties. Chinese Journal of Structural Chemistry, 2014, 33(3): 339-344.
19. [19]
  XU Bo , LI Ling , LI Jie , LI Cun-Cheng . Crystal Structure and Luminescent Property of a Coordination Complex Constructed with Pyrazine and 1,4-Phenylenediacetic Acid. Chinese Journal of Structural Chemistry, 2014, 33(12): 1826-1830. doi: 10.14102/j.cnki.0254-5861.2011-0378
20. [20]
  LI Shu-Jing , LI Ke , QU Bo-Tao , ZHENG Wei . Synthesis, Crystal Structure and Properties of a New Zn(Ⅱ) Coordination Polymer Constructed from 2,3-Pyridine Dicarboxylic Acid and 1,1'-(1,4-Butanediyl)bis(imidazole). Chinese Journal of Structural Chemistry, 2014, 33(2): 193-198.

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(3180)
HTML views(77)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142