Citation: WANG Kai, HUANG Xu-Ke, ZHU Li, CHEN Zi-Lu, LIANG Fu-Pei. A Chain Cadmium(II) Coordination Polymer with Diacylhydrazide: Synthesis, Crystal Structure and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1912-1919. doi: 10.14102/j.cnki.0254-5861.2011-1230 shu

A Chain Cadmium(II) Coordination Polymer with Diacylhydrazide: Synthesis, Crystal Structure and Luminescent Property

WANG Kai ^a ,
HUANG Xu-Ke ^b ,
ZHU Li ^b ,
CHEN Zi-Lu ^b ,
LIANG Fu-Pei ^a,b,*,,

a.
Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, China
b.
State Key Laboratory for the Chemistry and Molecular Engineering of Medicinal Resources, School of Chemistry and Pharmacy, Guangxi Normal University, Guilin 541004, China

Corresponding author: LIANG Fu-Pei, fliangoffice@yahoo.com
Received Date: 05 April 2016

Fund Project: the Guangxi Natural Science Foundation 2015GXNSFDA139007, 2014GXNSFBA118055 and 2013GXNSFGA019008the National Natural Science Foundation of China 51572050, 21271050 and 21261004

Figures(9)

A novel Cd(II) coordination polymer with diacylhydrazide ligand N,N'-bis(3-methoxysalicyl)-2,6-pyridinedicarbohydrazide (H₆msphz),[Cd₂(H₂msphz)(Py)₄]_n (1, Py=pyridine) has been synthesized through solvothermal reaction and structurally characterized by single-crystal X-ray diffraction, IR, TGA and PXRD investigations. It crystallizes in triclinic system, space group P1, with a=11.0230(11), b=11.7264(15), c=17.3395(14)Å, α=70.520(9), β=84.806(7), γ=81.965(9)°, V=2089.9(4)Å³, D_c=1.638 g cm^-3, μ=1.083 mm^-1, F(000)=1032, Z=2 and S=1.040. In complex 1, the H₂msphz^4- ligand uses not only its coordinated pocket to catch one Cd(II) ion, but also its two terminal groups to chelate other two Cd(II) ions, leading to the formation of a chain structure. The adjacent chains are further assembled together by two kinds of π-π interactions between the Py rings, resulting in the finial double layered supramolecular structure. In addition, complex 1 is found to show photoluminescence in the solid state at room temperature, which can be ascribed to the intraligand π→π^* transitions.
- coordination polymer,
- diacylhydrazide,
- crystal structure,
- luminescence
1. [1]
  Zhang J. P, Zhang Y. B, Lin J. B, Chen X. M. Metal azolate frameworks: from crystal engineering to functional materials[J]. Chem. Rev., 2012,112:1001-1033. doi: 10.1021/cr200139g
2. [2]
  Kudo A, Miseki Y. Heterogeneous photocatalyst materials for water splitting[J]. Chem. Soc. Rev., 2009,38:253-278. doi: 10.1039/B800489G
3. [3]
  Zhao J. P, Han S. D, Zhao R, Yang Q, Chang Z, Bu X. H. Tuning the structure and magnetism of heterometallic sodium(1+)-cobalt(2+) formate coordination polymers by varying the metal ratio and solvents[J]. Inorg. Chem., 2013,52:2862-2869. doi: 10.1021/ic301936k
4. [4]
  Rocha J, Carlos L. D, Paz F. A. A, Ananias D. Luminescent multifunctional lanthanides-based metal-organic frameworks[J]. Chem. Soc. Rev., 2011,40:926-940. doi: 10.1039/C0CS00130A
5. [5]
  Carlos L. D, Ferreira R. A. S, Bermudez V. D. Z, Julian-Lopez B, Escribano P. Progress on lanthanide-based organic-inorganic hybrid phosphors[J]. Chem. Soc. Rev., 2011,40:536-549. doi: 10.1039/C0CS00069H
6. [6]
  Cook T. R, Zheng Y. R, Stang P. J. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials[J]. Chem. Rev., 2013,113:734-777. doi: 10.1021/cr3002824
7. [7]
  O'Keeffe M, Yaghi O. M. Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets[J]. Chem. Rev., 2012,112:675-702. doi: 10.1021/cr200205j
8. [8]
  Zhang W. X, Liao P. Q, Lin R. B, Wei Y. S, Zeng M. H, Chen X. M. Metal cluster-based functional porous coordination polymers[J]. Coordin. Chem. Rev., 2015,263.
9. [9]
  Xiang S. C, Hu S. M, Sheng T. L, Chen J. S, Wu X. T. Structural diversity of infinite 3d-4f heterometallic cluster compounds driven by various lanthanide radii[J]. Chem. Eur. J., 2009,15:12496-12502. doi: 10.1002/chem.200900520
10. [10]
  Wang K, Chen Z. L, Zou H. H, Zhang Z, Sun W. Y, Liang F. P. Two types of Cu-Ln heterometallic coordination polymers with 2-hydroxyisophthalate: syntheses, structures, and magnetic properties[J]. Cryst. Growth Des., 2015,15:2883-2890. doi: 10.1021/acs.cgd.5b00327
11. [11]
  Prakash M. J, Lah M. S. Metal-organic macrocycles, metal-organic polyhedra and metal-organic frameworks[J]. Chem. Commun., 2009,3326.
12. [12]
  Kurmoo M. Magnetic metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1353-1379. doi: 10.1039/b804757j
13. [13]
  Qin, S. N.; Chen, Z. L.; Liu, D. C.; Huang, W. Y.; Liang, F. P. A 1D copper(II) chain featuring novel hexanuclear secondary building blocks: synthesis, crystal structure and magnetic property. Inorg. Chem. Commun. 2011, 14, 784-787.
14. [14]
  Qin S. N, Chen Z. L, Liu D. C, Huang W. Y, Liang F. P. Synthesis, crystal structure, and luminescent properties of metal complexes bearing 2,6-pyridine-diacylhydrazide ligands: supramolecular assemblies via intermolecular interactions[J]. Trans. Met. Chem., 2011,36:369-378. doi: 10.1007/s11243-011-9479-x
15. [15]
  G uo, Y. N, X u, G. F, Gamez P, Zhao L, Lin S. Y, Deng R, Tang J. K, Zhang H. J. Two-step relaxation in a linear tetranuclear dysprosium(III) aggregate showing single-molecule magnet behavior[J]. J. Am. Chem. Soc., 2010,132:8538-8539. doi: 10.1021/ja103018m
16. [16]
  Sheldrick, G. M. SHELXS-97, Program for Crystal Structure Solution. University of G?ttingen 1997.
17. [17]
  Sheldrick, G. M. SHELXL 97, Program for the Refinement of Crystal Structure. University of G?ttingen 1997.
18. [18]
  Dolomanov, O. V.; Bourthis, L. J.; Gildea, R. L.; Howard, J. A. K.; Puschmann, H. J. OLEX2: a complete structure solution, refinement and analysis program. Appl. Crystallogr. 2009, 42, 339-341.
19. [19]
  Wang K, Zou H. H, Chen Z. L, Zhang Z, Sun W. Y, Liang F. P. A series of 3D metal organic frameworks based on[J]. Dalton Trans., 2014,43:12989-12995. doi: 10.1039/C4DT01593B
20. [20]
  Zh ao, S. N, Su S. Q, Song X. Z, Zhu M, Hao Z. M, Meng X, Song S. Y, Zhang H. J. A series of metal-organic frameworks constructed from a V-shaped tripodal carboxylate ligand: syntheses, structures, photoluminescent, and magnetic properties[J]. Cryst. Growth Des., 2013,13:2756-2765. doi: 10.1021/cg3018387
21. [21]
  Singh R, Bharadwaj P. K. Coordination polymers built with a linear bis-imidazole and different dicarboxylates: unusual entanglement and emission properties[J]. Cryst. Growth Des., 2013,13:3722-3733. doi: 10.1021/cg400756z
22. [22]
  Liu C. S, Wang J. J, Chang Z, Yan L. F, Bu X. H. Cadmium(II) coordination polymers based on a bulky anthracene-based dicarboxylate ligand: crystal structures and luminescent properties[J]. CrystEngComm., 2010,12:1833-1841. doi: 10.1039/b923516g
23. [23]
  Zheng S. L, Yang J. H, Yu X. L, Chen X. M, Wong W. T. Syntheses, structures, photoluminescence, and theoretical studies of d(10) metal complexes of 2,2'-dihydroxy-[J]. Inorg. Chem., 2004,43:830-838. doi: 10.1021/ic034847i
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