Citation: WANG Kai, HUANG Xu-Ke, ZHU Li, CHEN Zi-Lu, LIANG Fu-Pei. A Chain Cadmium(II) Coordination Polymer with Diacylhydrazide: Synthesis, Crystal Structure and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1912-1919. doi: 10.14102/j.cnki.0254-5861.2011-1230 shu

A Chain Cadmium(II) Coordination Polymer with Diacylhydrazide: Synthesis, Crystal Structure and Luminescent Property

  • Corresponding author: LIANG Fu-Pei, fliangoffice@yahoo.com
  • Received Date: 5 April 2016

    Fund Project: the Guangxi Natural Science Foundation 2015GXNSFDA139007, 2014GXNSFBA118055 and 2013GXNSFGA019008the National Natural Science Foundation of China 51572050, 21271050 and 21261004

Figures(9)

  • A novel Cd(II) coordination polymer with diacylhydrazide ligand N,N'-bis(3-methoxysalicyl)-2,6-pyridinedicarbohydrazide (H6msphz),[Cd2(H2msphz)(Py)4]n (1, Py=pyridine) has been synthesized through solvothermal reaction and structurally characterized by single-crystal X-ray diffraction, IR, TGA and PXRD investigations. It crystallizes in triclinic system, space group P1, with a=11.0230(11), b=11.7264(15), c=17.3395(14)Å, α=70.520(9), β=84.806(7), γ=81.965(9)°, V=2089.9(4)Å3, Dc=1.638 g cm-3, μ=1.083 mm-1, F(000)=1032, Z=2 and S=1.040. In complex 1, the H2msphz4- ligand uses not only its coordinated pocket to catch one Cd(II) ion, but also its two terminal groups to chelate other two Cd(II) ions, leading to the formation of a chain structure. The adjacent chains are further assembled together by two kinds of π-π interactions between the Py rings, resulting in the finial double layered supramolecular structure. In addition, complex 1 is found to show photoluminescence in the solid state at room temperature, which can be ascribed to the intraligand ππ* transitions.
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