Citation: ZHANG Lei, WU Xiao-Yuan, LU Can-Zhong, CHEN Wen-Zhe. Synthesis and Characterization of a Water-stable Metal-organic Framework Based on Mixed Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1929-1935. doi: 10.14102/j.cnki.0254-5861.2011-1226 shu

Synthesis and Characterization of a Water-stable Metal-organic Framework Based on Mixed Ligands

  • Corresponding author: LU Can-Zhong, czlu@fjirsm.ac.cn CHEN Wen-Zhe, chenwz@fzu.edu.cn
  • Received Date: 1 April 2016

    Fund Project: the 973 key program of the Chinese Ministry of Science and Technology (MOST) 2012CB821705

Figures(7)

  • A new water-stable metal-organic framework,[Cu2(bdc)2(tpt)3]·2H2O (1, H2bdc=terephthalic acid, tpt=2,4,6-tri(4-pyridinyl)-1,3,5-triazine), has been synthesized and characterized by elemental analysis, infrared (IR) spectrum, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. Compund 1 crystalizes in monoclinic, space group C2/c with a=30.147(5), b=11.0548(17), c=20.867(4)Å, β=115.035(2)°, C70H48Cu2N18O10, Mr=1428.34, V=6301.0(18)Å3, Z=8, Dc=1.506 g/cm3, μ=0.754 mm-1, F(000)=2928, GOOF=1.058, λ(Mo)=0.71073Å, the final R=0.0387 and wR=0.1091 for 6230 observed reflections with I>2σ(I). In compound 1, the half metallacycles[Cu2(tpt)3] are linked by the bdc2- ligands to form a 1D bent ladder-like chain featured with a nano-sized channel, and these chains link each other via intermolecular hydrogen bonds and π-π stacking interactions to form a 3D supramolecular architecture with the voids filled with free water molecules. In addition, the water stability of 1 was investigated by PXRD patterns, which indicate that compound 1 keeps its structural integrity in boiling water for at least three days.
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