Citation: ZHANG Lei, WU Xiao-Yuan, LU Can-Zhong, CHEN Wen-Zhe. Synthesis and Characterization of a Water-stable Metal-organic Framework Based on Mixed Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1929-1935. doi: 10.14102/j.cnki.0254-5861.2011-1226 shu

Synthesis and Characterization of a Water-stable Metal-organic Framework Based on Mixed Ligands

ZHANG Lei ^a,b ,
WU Xiao-Yuan ^b ,
LU Can-Zhong ^b,*,, ,
CHEN Wen-Zhe ^a,b,*,,

a.
College of Materials Science and Engineering, Fuzhou University, Fuzhou 350116, China
b.
Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: LU Can-Zhong, czlu@fjirsm.ac.cn CHEN Wen-Zhe, chenwz@fzu.edu.cn
Received Date: 01 April 2016

Fund Project: the 973 key program of the Chinese Ministry of Science and Technology (MOST) 2012CB821705

Figures(7)

A new water-stable metal-organic framework,[Cu₂(bdc)₂(tpt)₃]·2H₂O (1, H₂bdc=terephthalic acid, tpt=2,4,6-tri(4-pyridinyl)-1,3,5-triazine), has been synthesized and characterized by elemental analysis, infrared (IR) spectrum, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. Compund 1 crystalizes in monoclinic, space group C2/c with a=30.147(5), b=11.0548(17), c=20.867(4)Å, β=115.035(2)°, C₇₀H₄₈Cu₂N₁₈O₁₀, M_r=1428.34, V=6301.0(18)Å³, Z=8, D_c=1.506 g/cm³, μ=0.754 mm^-1, F(000)=2928, GOOF=1.058, λ(MoKα)=0.71073Å, the final R=0.0387 and wR=0.1091 for 6230 observed reflections with I>2σ(I). In compound 1, the half metallacycles[Cu₂(tpt)₃] are linked by the bdc^2- ligands to form a 1D bent ladder-like chain featured with a nano-sized channel, and these chains link each other via intermolecular hydrogen bonds and π-π stacking interactions to form a 3D supramolecular architecture with the voids filled with free water molecules. In addition, the water stability of 1 was investigated by PXRD patterns, which indicate that compound 1 keeps its structural integrity in boiling water for at least three days.
- crystal structure,
- metal-organic framework,
- mixed ligands,
- water-stable
1. [1]
  Zhang J. P, Zhang Y. B, Lin J. B, Chen X. M. Metal azolate frameworks: from crystal engineering to functional materials[J]. Chem. Rev., 2012,112:1001-1033.
2. [2]
  O'Keeffe M, Yaghi O. M. Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets[J]. Chem. Rev., 2012,112:675-702. doi: 10.1021/cr200205j
3. [3]
  Czaja A. U, Trukhan N, Muller U. Industrial applications of metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1284-1293. doi: 10.1039/b804680h
4. [4]
  Li J. R, Kuppler R. J, Zhou H. C. Selective gas adsorption and separation in metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1477-1504. doi: 10.1039/b802426j
5. [5]
  Horcajada P, Gref R, Baati T, Allan P. K, Maurin G, Couvreur P, Ferey G, Morris R. E, Serre C. Metal-organic frameworks in biomedicine[J]. Chem. Rev., 2012,112:1232-1268. doi: 10.1021/cr200256v
6. [6]
  Kreno L. E, Leong K, Farha O. K, Allendorf M, Van Duyne R. P, Hupp J. T. Metal-organic framework materials as chemical sensors[J]. Chem. Rev., 2012,112:1105-1125. doi: 10.1021/cr200324t
7. [7]
  Liu J, Chen L, Cui H, Zhang J, Zhang L, Su C. Y. Applications of metal-organic frameworks in heterogeneous supramolecular catalysis[J]. Chem. Soc. Rev., 2014,43:6011-6061. doi: 10.1039/C4CS00094C
8. [8]
  Du M, Li C. P, Liu C. S, Fang S. M. Design and construction of coordination polymers with mixed-ligand synthetic strategy[J]. Coord. Chem. Rev., 2013,257:1282-1305. doi: 10.1016/j.ccr.2012.10.002
9. [9]
  Yin Z, Zhou Y. L, Zeng M. H, Kurmoo M. The concept of mixed organic ligands in metal-organic frameworks: design, tuning and functions[J]. Dalton Trans., 2015,44:5258-5275. doi: 10.1039/C4DT04030A
10. [10]
  Zhang L; Yang W. B, Wu X. Y, Huo M, Lu C. Z, Chen W. Z. A polyhedron-based cobalt-organic framework for gas adsorption and separation[J]. Inorg. Chem. Commun., 2016,67:10-13. doi: 10.1016/j.inoche.2016.02.019
11. [11]
  Zhang M. L, Gao N, Gao L. J. A Cd(II) coordination polymer with cds topology constructed by polycarboxylate and imidazole-containing ligand. Chin. J[J]. Struct. Chem., 2016,35:143-149.
12. [12]
  Li H. L, Eddaoudi M, O'Keeffe M, Yaghi O. M. Design and synthesis of an exceptionally stable and highly porous metal-organic framework[J]. Nature, 1999,402:276-279. doi: 10.1038/46248
13. [13]
  Férey G, Mellot-Draznieks C, Serre C, Millange F, Dutour J, Surblé S, Margiolaki I. A chromium terephthalate-based solid with unusually large pore volumes and surface area[J]. Science, 2005,309:2040-2042. doi: 10.1126/science.1116275
14. [14]
  Inokuma Y, Kawano M, Fujita M. Crystalline molecular flasks[J]. Nat. Chem., 2011,3:349-358. doi: 10.1038/nchem.1031
15. [15]
  Zhang L, Kuang X. F, Wu X. Y, Yang W. B, Lu C. Z. Supramolecular interactions induced hinge-like motion of a metal-organic framework accompanied by anisotropic thermal expansion[J]. Dalton Trans., 2014,43:7146-7452. doi: 10.1039/c3dt53580k
16. [16]
  Li W, Li M. X, Shao M, Zhu S. R. Microporous metal-organic frameworks constructed by Cu(I)/Zn(II), tpt and 1,4-benzenedicarboxylate[J]. Inorg. Chem. Commun., 2007,10:753-756. doi: 10.1016/j.inoche.2007.03.026
17. [17]
  Wei Y. S, Zhang M, Liao P. Q, Lin R. B, Li T. Y, Shao G, Zhang J. P, Chen X. M. Coordination templated[J]. Nat. Commun., 2015,68348. doi: 10.1038/ncomms9348
18. [18]
  Zhao X, Bu X, Zhai Q. G, Tran H, Feng P. Pore space partition by symmetry-matching regulated ligand insertion and dramatic tuning on carbon dioxide uptake[J]. J. Am. Chem. Soc., 2015,137:1396-1399. doi: 10.1021/ja512137t
19. [19]
  Burtch N. C, Jasuja H, Walton K. S. Water stability and adsorption in metal-organic frameworks[J]. Chem. Rev., 2014,114:10575-10612. doi: 10.1021/cr5002589
20. [20]
  Canivet J, Fateeva A, Guo Y, Coasne B, Farrusseng D. Water adsorption in MOFs: fundamentals and applications[J]. Chem. Soc. Rev., 2014,43:5594-5617. doi: 10.1039/C4CS00078A
21. [21]
  Li M. X, Miao Z. X, Shao M, Liang S. W, Zhu S. R. Metal-organic frameworks constructed from 2,4,6-tris(4-pyridyl)-1,3,5-triazine[J]. Inorg. Chem., 2008,47:4481-4489. doi: 10.1021/ic701346x
22. [22]
  Sheldrick, G. M. SHELXS97, Program for Crystal Structure Solution. University of G?ttingen, Germany 1997.
23. [23]
  Sheldrick, G. M. SHELXL97, Program for Crystal Structure Solution. University of G?ttingen, Germany 1997.
24. [24]
  Li Y. W, Li D. C, Xu J, Hao H. G, Wang S. N, Dou J. M, Hu T. L, Bu X. H. Structural modulation in two CuII-based MOFs by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect[J]. Dalton Trans., 2014,43:15708-15712. doi: 10.1039/C4DT02321H
25. [25]
  Kong G. Q, Ou S, Zou C, Wu C. D. Assembly and post-modification of a metal-organic nanotube for highly efficient catalysis[J]. J. Am. Chem. Soc., 2012,134:19851-19857. doi: 10.1021/ja309158a
26. [26]
  Murdock C. R, Jenkins D. M. Isostructural synthesis of porous metal-organic nanotubes[J]. J. Am. Chem. Soc., 2014,136:10983-10988. doi: 10.1021/ja5042226
27. [27]
  Zhang, L.; Yang, W. B.; K, X. F.; Wu, X. Y.; Lu, C. Z. pH-dependent assembly of two polyoxometalate host-guest structural isomers based on keggin polyoxoanion templates. Dalton Trans. 2014, 43, 16328-11634.
1. [1]
  LI Wen-Bin , GAO Zhu-Qing , GU Jin-Zhong . Synthesis, Crystal Structure, and Magnetic Properties of a Co Metal-organic Framework with Mixed Dicarboxylate and Tricarboxylate Ligands. Chinese Journal of Structural Chemistry, 2016, 35(2): 257-263. doi: 10.14102/j.cnki.0254-5861.2011-0929
2. [2]
  LI Wen-Bin , GAO Zhu-Qing , GU Jin-Zhong . Synthesis, Crystal Structure, and Magnetic Properties of a Co Metal-organic Framework with Mixed Dicarboxylate and Tricarboxylate Ligands. Chinese Journal of Structural Chemistry, 2016, 35(2): 257-263. doi: 10.14102/j.cnki.0254-5861.2011-0929
3. [3]
  ZHANG Guang-Hui , LU Jiu-Fu . Synthesis, Structure and Fluorescent Property of a New Isolated Zn₆Co₉ Heteronuclear Cluster Constructed by Four Kinds of Ligands. Chinese Journal of Structural Chemistry, 2016, 35(11): 1666-1672. doi: 10.14102/j.cnki.0254-5861.2011-1188
4. [4]
  ZHANG Fang-Wei , ZHOU Yan-Fang , DONG Jin-Qiao , LIU Bai-Zhan , ZHENG Sai-Jing , CUI Yong . Synthesis and Crystal Structure of a Novel Chiral 3D Metal-organic Framework Based on an N-methyl Substituted Salan Ligand. Chinese Journal of Structural Chemistry, 2014, 33(8): 1154-1158.
5. [5]
  HU Biao , YU Di , HUANG Kai , YU Shu-Juan . Metal-ion Interactions with Sugars: Crystal Structure of Bis(4-dehydro-L-arabinose) Calcium Methanol Bishydrate. Chinese Journal of Structural Chemistry, 2015, 34(5): 764-770. doi: 10.14102/j.cnki.0254-5861.2011-0517
6. [6]
  SHENG Dong-Hai , DAN Wen-Yan , LUO Gen-Xiang , DENG Ming-Li . A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO₂ Adsorption and Luminescent Property. Chinese Journal of Structural Chemistry, 2016, 35(2): 264-270. doi: 10.14102/j.cnki.0254-5861.2011-0838
7. [7]
  SHENG Dong-Hai , DAN Wen-Yan , LUO Gen-Xiang , DENG Ming-Li . A New Coordination Polymer Built of 4-(5H-tetrazol)-benzoic Acid and 3,5-Dimethyl-1H,1,2,4-Triazole Showing a Rarely Observed (3,5)-Connected lhh Topology: Synthesis, Structure, CO₂ Adsorption and Luminescent Property. Chinese Journal of Structural Chemistry, 2016, 35(2): 264-270. doi: 10.14102/j.cnki.0254-5861.2011-0838
8. [8]
  YAN Xiao-Lin , GUO Hai-Fu , YAN Peng , ZHU Jia-Min , WANG Ying , TAN Jia-Mei , DING Min , ZHENG Yong-Rui . Synthesis, Characterization and Drug Delivery of a Water-Stable and Methyl-Functionalized 2D Zinc(Ⅱ) Metal-Organic Framework. Chinese Journal of Inorganic Chemistry, 2019, 35(7): 1267-1274. doi: 10.11862/CJIC.2019.137
9. [9]
  MIAO Shao-Bin , LI Zhao-Hao , XU Chun-Yin , JI Bao-Ming . A New 3-Fold Interpenetrating 3D Zn(II) Metal-organic Framework: Synthesis, Structure and Luminescent Property. Chinese Journal of Structural Chemistry, 2016, 35(12): 1960-1966. doi: 10.14102/j.cnki.0254-5861.2011-1209
10. [10]
  CHEN Yong-Qiang , TIAN Yuan . A Zinc(Ⅱ) Coordination Framework Based on Terpyridine and 5-Nitroisophthalic Acid Mixed Ligands: Synthesis, Crystal Structure and Fluorescence Property. Chinese Journal of Structural Chemistry, 2014, 33(11): 1587-1592. doi: 10.14102/j.cnki.0254-5861.2011-0282
11. [11]
  TAN Hai-Yan , LIU Cheng , WANG Zhao-Hui , WU Jin-Ping . Simple Preparation, Structure and Conductivity of Nickel(Ⅱ) Benzenetricarboxylate Ni₃(BTC)₂·12H₂O. Chinese Journal of Structural Chemistry, 2014, 33(3): 401-406.
12. [12]
  RONG Jie-Wei , ZHANG Wen-Wei . Syntheses, Structures and Photoluminescent Properties of Metal-Organic Frameworks Based on Triangle Flexible Multi-Carboxylic Ligand. Chinese Journal of Inorganic Chemistry, 2018, 34(12): 2307-2315. doi: 10.11862/CJIC.2018.281
13. [13]
  LIU Zhen , CHEN Xiao , FENG Yun-Long . Two Series of (4, 8)-Connected Lanthanide-Metal Organic Frameworks Based on a Tetra-carboxylate Ligand for Sensing of Small Molecules. Chinese Journal of Inorganic Chemistry, 2016, 32(8): 1413-1420. doi: 10.11862/CJIC.2016.175
14. [14]
  ZHANG Xu , GE Ming , HECKE Kristof Van , CUI Guang-Hua . Synthesis, Crystal Structure and Catalytic Properties of a 2D Cobalt(Ⅱ) Coordination Polymer Based on Mixed Ligands. Chinese Journal of Structural Chemistry, 2015, 34(4): 599-605. doi: 10.14102/j.cnki.0254-5861.2011-0542
15. [15]
  WANG Xiu-Yan , ZHAO Zhong-Yu , LIU Rui , XU Ye , LI Xin-Hang , XU Zhan-Lin . Synthesis, Crystal Structure and Luminescence of a New Zn(II) Complex [Zn(1,2,3-HBTC)(L)]₂ Constructed by Mixed Ligands. Chinese Journal of Structural Chemistry, 2015, 34(5): 725-728. doi: 10.14102/j.cnki.0254-5861.2011-0545
16. [16]
  SUN Zhi-Hao , WANG Yong , MA Xiao , WANG Yan-Long , HU Sheng-Min , SHENG Tian-Lu , WU Xin-Tao . Synthesis, Crystal Structure and MMCT Property of a New Mixed-valence Cyanide-bridged Binuclear Complex. Chinese Journal of Structural Chemistry, 2014, 33(9): 1305-1310.
17. [17]
  NIE Xu-Liang , HU Chun-Yan , HUANG Chang-Gan , SHANG-GUAN Xin-Chen . Synthesis and Crystal Structure of a Three-dimensional Cobalt Coordination Polymer Assembled by Ozagrel Ligands. Chinese Journal of Structural Chemistry, 2015, 34(1): 117-122. doi: 10.14102/j.cnki.0254-5861.2011-0419
18. [18]
  ZHU Xiao-Fei , WANG Ning , XIE Xiao-Yan , HOU Rui-Bin , ZHOU De-Feng , LI Ya-Feng , HU Jun , LI Xin-Yuan , LIU He , NIE Wang . A New 3D Metal-organic Framework with Tetranuclear Cadmium(Ⅱ) Clusters:Synthesis, Structure, and Luminescent Property. Chinese Journal of Structural Chemistry, 2014, 33(2): 277-283.
19. [19]
  CHEN Hui , MA Cheng-Bing , CHEN Chang-Neng . Synthesis and Crystal Structure of a 2D Cu Framework Constructed from Dinuclear Building Units. Chinese Journal of Structural Chemistry, 2014, 33(12): 1807-1812. doi: 10.14102/j.cnki.0254-5861.2011-0359
20. [20]
  ZHAO Wei-Xing , WEN Pu-Hong , WANG Yan , JIANG Luan , FENG Guo-Dong , LI Zong-Xiao . Synthesis, Crystal Structure and Physical Properties of a Novel Cadmium(II) Supramolecular 3D Framework. Chinese Journal of Structural Chemistry, 2015, 34(5): 786-793. doi: 10.14102/j.cnki.0254-5861.2011-0576

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(3920)
HTML views(80)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142