Citation: ZHANG Lei, WU Xiao-Yuan, LU Can-Zhong, CHEN Wen-Zhe. Synthesis and Characterization of a Water-stable Metal-organic Framework Based on Mixed Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1929-1935. doi: 10.14102/j.cnki.0254-5861.2011-1226 shu

Synthesis and Characterization of a Water-stable Metal-organic Framework Based on Mixed Ligands

ZHANG Lei ^a,b ,
WU Xiao-Yuan ^b ,
LU Can-Zhong ^b,*,, ,
CHEN Wen-Zhe ^a,b,*,,

a.
College of Materials Science and Engineering, Fuzhou University, Fuzhou 350116, China
b.
Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: LU Can-Zhong, czlu@fjirsm.ac.cn CHEN Wen-Zhe, chenwz@fzu.edu.cn
Received Date: 1 April 2016

Fund Project: the 973 key program of the Chinese Ministry of Science and Technology (MOST) 2012CB821705

Figures(7)

A new water-stable metal-organic framework,[Cu₂(bdc)₂(tpt)₃]·2H₂O (1, H₂bdc=terephthalic acid, tpt=2,4,6-tri(4-pyridinyl)-1,3,5-triazine), has been synthesized and characterized by elemental analysis, infrared (IR) spectrum, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. Compund 1 crystalizes in monoclinic, space group C2/c with a=30.147(5), b=11.0548(17), c=20.867(4)Å, β=115.035(2)°, C₇₀H₄₈Cu₂N₁₈O₁₀, M_r=1428.34, V=6301.0(18)Å³, Z=8, D_c=1.506 g/cm³, μ=0.754 mm^-1, F(000)=2928, GOOF=1.058, λ(MoKα)=0.71073Å, the final R=0.0387 and wR=0.1091 for 6230 observed reflections with I>2σ(I). In compound 1, the half metallacycles[Cu₂(tpt)₃] are linked by the bdc^2- ligands to form a 1D bent ladder-like chain featured with a nano-sized channel, and these chains link each other via intermolecular hydrogen bonds and π-π stacking interactions to form a 3D supramolecular architecture with the voids filled with free water molecules. In addition, the water stability of 1 was investigated by PXRD patterns, which indicate that compound 1 keeps its structural integrity in boiling water for at least three days.
- crystal structure,
- metal-organic framework,
- mixed ligands,
- water-stable
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