Citation: ZHANG Lei, WU Xiao-Yuan, LU Can-Zhong, CHEN Wen-Zhe. Synthesis and Characterization of a Water-stable Metal-organic Framework Based on Mixed Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1929-1935. doi: 10.14102/j.cnki.0254-5861.2011-1226 shu

Synthesis and Characterization of a Water-stable Metal-organic Framework Based on Mixed Ligands

ZHANG Lei ^a,b ,
WU Xiao-Yuan ^b ,
LU Can-Zhong ^b,*,, ,
CHEN Wen-Zhe ^a,b,*,,

a.
College of Materials Science and Engineering, Fuzhou University, Fuzhou 350116, China
b.
Key Laboratory of Design and Assembly of Functional Nanostructures, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, China

Corresponding author: LU Can-Zhong, czlu@fjirsm.ac.cn CHEN Wen-Zhe, chenwz@fzu.edu.cn
Received Date: 1 April 2016
Accepted Date: 10 May 2016

Fund Project: the 973 key program of the Chinese Ministry of Science and Technology (MOST) 2012CB821705

Figures(7)

A new water-stable metal-organic framework,[Cu₂(bdc)₂(tpt)₃]·2H₂O (1, H₂bdc=terephthalic acid, tpt=2,4,6-tri(4-pyridinyl)-1,3,5-triazine), has been synthesized and characterized by elemental analysis, infrared (IR) spectrum, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD) and single-crystal X-ray diffraction. Compund 1 crystalizes in monoclinic, space group C2/c with a=30.147(5), b=11.0548(17), c=20.867(4)Å, β=115.035(2)°, C₇₀H₄₈Cu₂N₁₈O₁₀, M_r=1428.34, V=6301.0(18)Å³, Z=8, D_c=1.506 g/cm³, μ=0.754 mm^-1, F(000)=2928, GOOF=1.058, λ(MoKα)=0.71073Å, the final R=0.0387 and wR=0.1091 for 6230 observed reflections with I>2σ(I). In compound 1, the half metallacycles[Cu₂(tpt)₃] are linked by the bdc^2- ligands to form a 1D bent ladder-like chain featured with a nano-sized channel, and these chains link each other via intermolecular hydrogen bonds and π-π stacking interactions to form a 3D supramolecular architecture with the voids filled with free water molecules. In addition, the water stability of 1 was investigated by PXRD patterns, which indicate that compound 1 keeps its structural integrity in boiling water for at least three days.
- crystal structure,
- metal-organic framework,
- mixed ligands,
- water-stable
1. [1]
  Zhang J. P, Zhang Y. B, Lin J. B, Chen X. M. Metal azolate frameworks: from crystal engineering to functional materials[J]. Chem. Rev., 2012,112:1001-1033.
2. [2]
  O'Keeffe M, Yaghi O. M. Deconstructing the crystal structures of metal-organic frameworks and related materials into their underlying nets[J]. Chem. Rev., 2012,112:675-702. doi: 10.1021/cr200205j
3. [3]
  Czaja A. U, Trukhan N, Muller U. Industrial applications of metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1284-1293. doi: 10.1039/b804680h
4. [4]
  Li J. R, Kuppler R. J, Zhou H. C. Selective gas adsorption and separation in metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1477-1504. doi: 10.1039/b802426j
5. [5]
  Horcajada P, Gref R, Baati T, Allan P. K, Maurin G, Couvreur P, Ferey G, Morris R. E, Serre C. Metal-organic frameworks in biomedicine[J]. Chem. Rev., 2012,112:1232-1268. doi: 10.1021/cr200256v
6. [6]
  Kreno L. E, Leong K, Farha O. K, Allendorf M, Van Duyne R. P, Hupp J. T. Metal-organic framework materials as chemical sensors[J]. Chem. Rev., 2012,112:1105-1125. doi: 10.1021/cr200324t
7. [7]
  Liu J, Chen L, Cui H, Zhang J, Zhang L, Su C. Y. Applications of metal-organic frameworks in heterogeneous supramolecular catalysis[J]. Chem. Soc. Rev., 2014,43:6011-6061. doi: 10.1039/C4CS00094C
8. [8]
  Du M, Li C. P, Liu C. S, Fang S. M. Design and construction of coordination polymers with mixed-ligand synthetic strategy[J]. Coord. Chem. Rev., 2013,257:1282-1305. doi: 10.1016/j.ccr.2012.10.002
9. [9]
  Yin Z, Zhou Y. L, Zeng M. H, Kurmoo M. The concept of mixed organic ligands in metal-organic frameworks: design, tuning and functions[J]. Dalton Trans., 2015,44:5258-5275. doi: 10.1039/C4DT04030A
10. [10]
  Zhang L; Yang W. B, Wu X. Y, Huo M, Lu C. Z, Chen W. Z. A polyhedron-based cobalt-organic framework for gas adsorption and separation[J]. Inorg. Chem. Commun., 2016,67:10-13. doi: 10.1016/j.inoche.2016.02.019
11. [11]
  Zhang M. L, Gao N, Gao L. J. A Cd(II) coordination polymer with cds topology constructed by polycarboxylate and imidazole-containing ligand. Chin. J[J]. Struct. Chem., 2016,35:143-149.
12. [12]
  Li H. L, Eddaoudi M, O'Keeffe M, Yaghi O. M. Design and synthesis of an exceptionally stable and highly porous metal-organic framework[J]. Nature, 1999,402:276-279. doi: 10.1038/46248
13. [13]
  Férey G, Mellot-Draznieks C, Serre C, Millange F, Dutour J, Surblé S, Margiolaki I. A chromium terephthalate-based solid with unusually large pore volumes and surface area[J]. Science, 2005,309:2040-2042. doi: 10.1126/science.1116275
14. [14]
  Inokuma Y, Kawano M, Fujita M. Crystalline molecular flasks[J]. Nat. Chem., 2011,3:349-358. doi: 10.1038/nchem.1031
15. [15]
  Zhang L, Kuang X. F, Wu X. Y, Yang W. B, Lu C. Z. Supramolecular interactions induced hinge-like motion of a metal-organic framework accompanied by anisotropic thermal expansion[J]. Dalton Trans., 2014,43:7146-7452. doi: 10.1039/c3dt53580k
16. [16]
  Li W, Li M. X, Shao M, Zhu S. R. Microporous metal-organic frameworks constructed by Cu(I)/Zn(II), tpt and 1,4-benzenedicarboxylate[J]. Inorg. Chem. Commun., 2007,10:753-756. doi: 10.1016/j.inoche.2007.03.026
17. [17]
  Wei Y. S, Zhang M, Liao P. Q, Lin R. B, Li T. Y, Shao G, Zhang J. P, Chen X. M. Coordination templated[J]. Nat. Commun., 2015,68348. doi: 10.1038/ncomms9348
18. [18]
  Zhao X, Bu X, Zhai Q. G, Tran H, Feng P. Pore space partition by symmetry-matching regulated ligand insertion and dramatic tuning on carbon dioxide uptake[J]. J. Am. Chem. Soc., 2015,137:1396-1399. doi: 10.1021/ja512137t
19. [19]
  Burtch N. C, Jasuja H, Walton K. S. Water stability and adsorption in metal-organic frameworks[J]. Chem. Rev., 2014,114:10575-10612. doi: 10.1021/cr5002589
20. [20]
  Canivet J, Fateeva A, Guo Y, Coasne B, Farrusseng D. Water adsorption in MOFs: fundamentals and applications[J]. Chem. Soc. Rev., 2014,43:5594-5617. doi: 10.1039/C4CS00078A
21. [21]
  Li M. X, Miao Z. X, Shao M, Liang S. W, Zhu S. R. Metal-organic frameworks constructed from 2,4,6-tris(4-pyridyl)-1,3,5-triazine[J]. Inorg. Chem., 2008,47:4481-4489. doi: 10.1021/ic701346x
22. [22]
  Sheldrick, G. M. SHELXS97, Program for Crystal Structure Solution. University of G?ttingen, Germany 1997.
23. [23]
  Sheldrick, G. M. SHELXL97, Program for Crystal Structure Solution. University of G?ttingen, Germany 1997.
24. [24]
  Li Y. W, Li D. C, Xu J, Hao H. G, Wang S. N, Dou J. M, Hu T. L, Bu X. H. Structural modulation in two CuII-based MOFs by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect[J]. Dalton Trans., 2014,43:15708-15712. doi: 10.1039/C4DT02321H
25. [25]
  Kong G. Q, Ou S, Zou C, Wu C. D. Assembly and post-modification of a metal-organic nanotube for highly efficient catalysis[J]. J. Am. Chem. Soc., 2012,134:19851-19857. doi: 10.1021/ja309158a
26. [26]
  Murdock C. R, Jenkins D. M. Isostructural synthesis of porous metal-organic nanotubes[J]. J. Am. Chem. Soc., 2014,136:10983-10988. doi: 10.1021/ja5042226
27. [27]
  Zhang, L.; Yang, W. B.; K, X. F.; Wu, X. Y.; Lu, C. Z. pH-dependent assembly of two polyoxometalate host-guest structural isomers based on keggin polyoxoanion templates. Dalton Trans. 2014, 43, 16328-11634.
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