Citation: LI Rong-Fang, LIU Xin-Fang, WANG Yu-Fang, FENG Xun, MA Lu-Fang. A (3,4)-Connected 3D Heteronuclear Framework with Three Kinds of Discrete Cadmium(II) Ions: Synthesis, Crystal Structure and Luminescence Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1936-1943. doi: 10.14102/j.cnki.0254-5861.2011-1225 shu

A (3,4)-Connected 3D Heteronuclear Framework with Three Kinds of Discrete Cadmium(II) Ions: Synthesis, Crystal Structure and Luminescence Property

College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-oriented Porous Materials, Luoyang Normal University, Luoyang, Henan 471934, China

Corresponding author: FENG Xun, fengx@lynu.edu.cn
Received Date: 30 March 2016
Accepted Date: 21 June 2016

Fund Project: the National Natural Science Foundation of China 21273101 and 21302082the Program for Science & Technology Innovation Talents in Universities of Henan Province 2014HASTIT014, 14IRTSTHN008 and 164100510012the Tackle Key Problem of Science and Technology Project of Henan Province 142102310483

Figures(6)

A novel 3D hetero-nuclear framework, namely[K₂Cd₅(Hbptc)₄(H₂O)₁₂·12H₂O]_n (1, H₄bptc=biphenyl-2,3,3',5'-tetracarboxylic acid), was obtained by hydrothermal reaction. X-ray singlecrystal structure analysis reveals that polymer 1 crystallizes in orthorhombic, space group Pbcn with a=26.6152(13), b=11.7449(5), c=29.5923(14)Å, V=9250.3(7)Å³, C₆₄H₇₆Cd₅K₂O₅₆, M_r=2381.44, D_c=1.710 g/cm³, μ(MoKα)=1.323 mm^-1, F(000)=4744, Z=4, the final R=0.0668 and wR=0.1135 for 10613 observed reflections (I>2σ(I)). Polymer 1 displays a 3D network that is built on the unprecedented heterobimetallic[Cd₃Cd₂K] molecular building block with a (3, 4)-connected (6·8·8)₂(6·6·8₂·8₂·12₆·12₆) topology which represents a rare 2-fold interpenetrating 3D framework topology network. The luminescence analyses reveal that polymer 1 shows obvious emission at room temperature in the solid state. In addition, it was also characterized by elemental, IR spectra and TG analyses.
- hetero-nuclear mental framework,
- Cd/K,
- 2-fold interpenetrating,
- luminescence
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