Citation: LI Rong-Fang, LIU Xin-Fang, WANG Yu-Fang, FENG Xun, MA Lu-Fang. A (3,4)-Connected 3D Heteronuclear Framework with Three Kinds of Discrete Cadmium(II) Ions: Synthesis, Crystal Structure and Luminescence Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1936-1943. doi: 10.14102/j.cnki.0254-5861.2011-1225 shu

A (3,4)-Connected 3D Heteronuclear Framework with Three Kinds of Discrete Cadmium(II) Ions: Synthesis, Crystal Structure and Luminescence Property

College of Chemistry and Chemical Engineering, and Henan Key Laboratory of Function-oriented Porous Materials, Luoyang Normal University, Luoyang, Henan 471934, China

Corresponding author: FENG Xun, fengx@lynu.edu.cn
Received Date: 30 March 2016
Accepted Date: 21 June 2016

Fund Project: the National Natural Science Foundation of China 21273101 and 21302082the Program for Science & Technology Innovation Talents in Universities of Henan Province 2014HASTIT014, 14IRTSTHN008 and 164100510012the Tackle Key Problem of Science and Technology Project of Henan Province 142102310483

Figures(6)

A novel 3D hetero-nuclear framework, namely[K₂Cd₅(Hbptc)₄(H₂O)₁₂·12H₂O]_n (1, H₄bptc=biphenyl-2,3,3',5'-tetracarboxylic acid), was obtained by hydrothermal reaction. X-ray singlecrystal structure analysis reveals that polymer 1 crystallizes in orthorhombic, space group Pbcn with a=26.6152(13), b=11.7449(5), c=29.5923(14)Å, V=9250.3(7)Å³, C₆₄H₇₆Cd₅K₂O₅₆, M_r=2381.44, D_c=1.710 g/cm³, μ(MoKα)=1.323 mm^-1, F(000)=4744, Z=4, the final R=0.0668 and wR=0.1135 for 10613 observed reflections (I>2σ(I)). Polymer 1 displays a 3D network that is built on the unprecedented heterobimetallic[Cd₃Cd₂K] molecular building block with a (3, 4)-connected (6·8·8)₂(6·6·8₂·8₂·12₆·12₆) topology which represents a rare 2-fold interpenetrating 3D framework topology network. The luminescence analyses reveal that polymer 1 shows obvious emission at room temperature in the solid state. In addition, it was also characterized by elemental, IR spectra and TG analyses.
- hetero-nuclear mental framework,
- Cd/K,
- 2-fold interpenetrating,
- luminescence
1. [1]
  Suh M. P, Park H. J, Prasad T. K, Lim D. W. Hydrogen storage in metal-organic frameworks[J]. Chem. Rev., 2011,112:782-835.
2. [2]
  Li J. R, Sculley J, Zhou H. C. Metal-organic frameworks for separations[J]. Chem. Rev., 2012,112:869-932. doi: 10.1021/cr200190s
3. [3]
  Yoon M, Srirambalaji R, Kim K. Homochiral metal-organic frameworks for asymmetric heterogeneous catalysis[J]. Chem. Rev., 2011,112.
4. [4]
  Dhakshinamoorthy A, Garcia H. Catalysis by metal nanoparticles embedded on metal-organic frameworks[J]. Chem. Soc. Rev., 2012,41:5262-5284. doi: 10.1039/c2cs35047e
5. [5]
  Cui Y. J, Yue Y. F, Qian G. D, Chen B. L. Luminescent functional metal-organic frameworks[J]. Chem. Rev., 2012,112:1126-1162. doi: 10.1021/cr200101d
6. [6]
  Feng X, Feng Y. Q. ;Chen J. J, Ng S. W, Wang L. Y, Guo J. Z. Reticular three-dimensional 3d-4f frameworks constructed through substituted imidazole-dicarboxylate: syntheses, luminescence and magnetic properties study[J]. Dalton Trans., 2015,44:804-816. doi: 10.1039/C4DT02047B
7. [7]
  Biswas S, Jena H. S, Adhikary A, Konar S. Two isostructural 3D lanthanide coordination networks (Ln = Gd3+, Dy3+) with squashed cuboid-type nanoscopic cages showing significant cryogenic magnetic refrigeration and slow magnetic relaxation[J]. Inorg. Chem., 2014,53:3926-3928. doi: 10.1021/ic4030316
8. [8]
  Xu Z. Q, Meng W, Li H. J, Hou H. W, Fan Y. T. Guest molecule release triggers changes in the catalytic and magnetic properties of a Fe-parallel to-based 3D metal-organic framework[J]. Inorg. Chem., 2014,53:3260-3262. doi: 10.1021/ic500004s
9. [9]
  Cook T. R, Zheng Y. R, Stang P. J. Metal-organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal-organic materials[J]. Chem. Rev., 2013,113:734-777. doi: 10.1021/cr3002824
10. [10]
  Li R. F, Liu X. F, Zhang T, Zhang X. Y, Feng X. Hydrothermal syntheses, structures, and magnetic properties of two new Mn(II) complexes with biphenyl-2,3,3?,5?-tetracarboxylic acid[J]. J. Mol. Struct., 2014,1075.
11. [11]
  Li H. H, Ma N, Li K. H. A 3D mesomeric supramolecular structure of a Cu(II) coordination polymer with 11?-biphenyl-22?33?-tetracarboxylic acid and 55 ′-dimethyl-22 ′-bipyridine ligands. J[J]. Inorg. Organomet. Polym. Mater., 2012,22:1320-1324. doi: 10.1007/s10904-012-9767-8
12. [12]
  Yang Z, Liu J, Liang X. Q, Jiang Y, Zhang T, Han B, Sun F. X, Liu L. Two novel 2D metal-organic frameworks based on biphenyl-2,2?,6,6?- tetracarboxylic acid: synthesis, structures and luminescent properties[J]. Inorg. Chem. Commun., 2012,16:92-94. doi: 10.1016/j.inoche.2011.12.003
13. [13]
  Tian D, Pang Y, Zhou Y. H, Guan L, Zhang H. A series of complexes based on biphenyl- 2,5,2?,5?-tetracarboxylic acid: syntheses, crystal structures, luminescent and magnetic properties[J]. CrystEngComm., 2011,13:957-966. doi: 10.1039/C0CE00281J
14. [14]
  Pan Z. R, Xu J, Yao X. Q, Li Y. Z, Guo Z. J, Zheng H. G. Syntheses, structures, magnetic and photoluminescence properties of metal-organic frameworks based on aromatic polycarboxylate acids[J]. CrystEngComm., 2011,13:1617-1624. doi: 10.1039/C0CE00490A
15. [15]
  Guo, S. Q.; Tian, D.; Zheng, X.; Zhang, H. A (3,4,10)-connected 3D sandwich-type metal-organic framework with trinuclear zinc(II) cluster and two kinds of discrete zinc(II) ions. Inorg. Chem. Commun. 2011, 14, 1876-1879.
16. [16]
  Li B, Zang S. Q, Ji C, Hou H. W, Mak T. C. W. Syntheses, structures, and properties of silver-organic frameworks constructed with 1,1?-biphenyl- 2,2 ′,6,6 ′-tetracarboxylic acid[J]. Cryst. Growth. Des., 2012,12:1443-1451. doi: 10.1021/cg2015447
17. [17]
  Zhang S, Xie G, Zou Y, Chen S, Gao S. Syntheses, structures, and magnetism of two coordination compounds with 3,3?,4,4?- biphenyltetracarboxylic acid and 1,10-phenanthroline[J]. J. Coord. Chem., 2012,65:1062-1070. doi: 10.1080/00958972.2012.666535
18. [18]
  Du F. L, Zhao M. L, Long X. F, Du S. W. A new acentric heterometallic inorganic-organic hybrid framework with an unusual {Cd3Na4}n array: NLO and ferroelectric properties[J]. Inorg. Chem. Commun., 2013,38:39-42. doi: 10.1016/j.inoche.2013.10.011
19. [19]
  Li R. F, Liu X. F, Zhang T, Wang L. Y, Ma L. F, Feng X. Two unique lanthanide-organic frameworks based on biphenyl-2,3,3?,5?-tetracarboxylic acid: syntheses, crystal structures and luminescence properties[J]. Polyhedron, 2015,99:238-243. doi: 10.1016/j.poly.2015.07.061
20. [20]
  Sheldrick, G. M. SHELXS 97, Program for the Solution of Crystal Structure (University of Gottingen, Germany 1997).
21. [21]
  Sheldrick, G. M. SHELXL 97, Program for the Refinement of Crystal Structure (University of Gottingen, Germany 1997).
22. [22]
  Sheldrick, G. M. SADABS Siemens Area Correction Absorption Program (University of G?ttingen: G?ttingen, Germany 1994).
23. [23]
  Spek, P. A. L. A Multipurpose Crystallographic Tool (Utrecht University, Utrecht, The Netherlands 2001).
24. [24]
  Bellamy, L. J. The infrared spectra of complex molecules (John Wiley & Sons, New York 1958).
25. [25]
  Zang S, Su Y, Li Y. Z, Lin J, Duan X, Meng Q, Gao S. Four 2D metal-organic networks incorporating Cd-cluster SUBs: hydrothermal synthesis, structures and photoluminescent properties[J]. CrystEngComm., 2009,11:122-129. doi: 10.1039/B806899B
26. [26]
  Li, R. F.; Gu, Y. X.; Liu, X. F.; Feng, X.; Ma, L. F. Syntheses, structures, and properties of two zinc(II) metal-organic frameworks based on biphenyl- 2,3,3?,5?-tetracarboxylic acid and N-donor ancillary ligands. Z. Anorg. Allg. Chem. 2015, 641, 1114-1118.
27. [27]
  Qiao J. Z, Zhan M. S, Hu T. P. One novel 3D tetranuclear cadmium coordination polymer based on 2,3?,4,5?-biphenyltetracarboxylic acid: synthesis, crystal structure and luminescence[J]. Inorg. Chem. Commun., 2015,55:157-160. doi: 10.1016/j.inoche.2015.03.019
1. [1]
  Peng Jun LIU , Ying Liang LIU . Preparation of CaS:Eu²⁺ Phosphor by Microwave Heating Method and its Luminescence. Chinese Chemical Letters, 2000, 11(9): 843-846.
2. [2]
  GUO Sheng-Nan , ZHAO Xin-Yu , SUN Rong-Ze , ZHANG Yue , MIAO Jia-Qi , KONG Zhi-Guo . A New 1D Cd(Ⅱ) Coordination Polymer Constructed by 2,2'-H₂biimidazole: [Cd(H₂biim)₂(SO₄)]_n·3nH₂O. Chinese Journal of Structural Chemistry, 2014, 33(12): 1796-1800. doi: 10.14102/j.cnki.0254-5861.2011-0361
3. [3]
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4. [4]
  LI Ting , MENG Qing-Fen , LI Bing , JIN Xiao-Dong , GAO Hui , CHEN Xiao-Yan , SONG Wei-Ming , LIU Wan-Yi . Assembly of a New Fluorescent Cd(II) Coordination Compound with a Versatile Multidentate N-Donor Building Block 3-(2-Pyridyl)-5-(3'-pyridyl)-1,2,4-triazole. Chinese Journal of Structural Chemistry, 2016, 34(10): 1525-1532. doi: 10.14102/j.cnki.0254-5861.2011-0742
5. [5]
  XU Jun , MA De-Yun , QIN Liang . A New 2D Barium-organic Framework Built from 1H-Benzimidazole-5,6-dicarboxylate with Luminescent and Antibacterial Studies. Chinese Journal of Structural Chemistry, 2014, 33(3): 387-394.
6. [6]
  KONG Chun-Yan . Hydrothermal Synthesis, Crystal Structure and Luminescent Property of a New Cd(Ⅱ) Coordination Polymer with Four-fold Interpenetrated dia Topology. Chinese Journal of Structural Chemistry, 2015, 34(2): 267-271. doi: 10.14102/j.cnki.0254-5861.2011-0477
7. [7]
  Zhen-Tao LI , Li-Wen DING , Yu-Ling WANG . Two Cd(II)-biphenyl-3, 3'-disulfonyl-4, 4'-dicarboxylate-2, 2'-bipyridine Compounds: Structures and Luminescence. Chinese Journal of Structural Chemistry, 2020, 39(1): 132-139. doi: 10.14102/j.cnki.0254-5861.2011-2380
8. [8]
  Zhao-Ting LIN , Yu-Ling WANG , Qing-Yan LIU . Crystal Structure and Luminescence of a Cd(II) Compound Based on the 3, 3΄, 5, 5΄-Tetrafluorobiphenyl- 4, 4΄-dicarboxylate and Adenine Ligands. Chinese Journal of Structural Chemistry, 2020, 39(11): 2041-2045. doi: 10.14102/j.cnki.0254–5861.2011–2736
9. [9]
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10. [10]
  KONG Zhi-Guo , GUO Sheng-Nan , YU Miao , FENG Si-Yang , HU Bo . A New Luminescent Cd(II) Coordination Polymer Constructed by Mixed 1,4-Naphthalenedicarboxylate and N-donor Chelating Ligand. Chinese Journal of Structural Chemistry, 2016, 35(4): 591-596. doi: 10.14102/j.cnki.0254-5861.2011-0908
11. [11]
  XU Bo , LI Zhi-Wang , JIANG Yang , LI Cun-Cheng . A Luminescent Cd(II) Coordination Polymer Constructed from Isophthalic Acid and 1,3-Bis-(4-pyridyl)propane. Chinese Journal of Structural Chemistry, 2015, 34(6): 925-930. doi: 10.14102/j.cnki.0254-5861.2011-0638
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13. [13]
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14. [14]
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19. [19]
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