Citation: YE Ying-Xiang, ZHENG Jian-Hong, ZENG Yan-Ting, LIN Yan-Li, ZHANG Liu-Qin, WANG Li-Hua, ZHANG Zhang-Jing, XIANG Sheng-Chang. Syntheses, Crystal Structures and Luminescent Properties of Two New Zinc(II) Complexes Based on Bifunctional Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1944-1952. doi: 10.14102/j.cnki.0254-5861.2011-1217 shu

Syntheses, Crystal Structures and Luminescent Properties of Two New Zinc(II) Complexes Based on Bifunctional Ligand

College of Chemistry and Chemical Engineering, Fujian Provincial Key Laboratory of Polymer Materials, Fujian Normal University, Fuzhou 350007, China

Corresponding author: WANG Li-Hua, lhwang@fjnu.edu.cn XIANG Sheng-Chang, scxiang@fjnu.edu.cn
Received Date: 25 March 2016
Accepted Date: 17 May 2016

Fund Project: the National Natural Science Foundation of China 21207018, 21273033, 21203024 and 21573042Fujian Science and Technology Department 2014J06003, 2014H6007 and 2016J01046college students' innovative training program 201510394008, 201510394055S. X. gratefully acknowledges the supports from Recruitment Program of Global Young Experts, Program for New Century Excellent Talents in University (NCET-10-0108), and the Award ‘Minjiang Scholar Program’ in Fujian Province

Figures(6)

By using solvothermal method, two novel coordination polymers based on 4-(4-carboxyphen-yl)-1,2,4-triazole (Hcpt) and Zn(II) cations,[Zn(cpt)(OH)]_n·nH₂O (FJU-32) and[Zn(cpt)(atrz)]_n (FJU-33) (Hatrz=3-amino-1,2,4-triazolate), were synthesized and characterized by single-crystal X-ray diffraction analyses, elemental analyses, FT-IR and powder X-ray diffraction. FJU-32 crystallizes in monoclinic, space group P2₁/c with a=3.7441(3), b=23.0384(19), c=11.8562(10)Å, β=99.069(8)°, V=1009.91(15)Å³, D_c=1.898 g/cm³, C₉H₉N₃O₄Zn, M_r=288.57, F(000)=916, μ(MoKα)=2.439 mm^-1, Z=4, R=0.0600 and wR=0.1306 for 2412 observed reflections (I>2σ(I)), and R=0.0704 and wR=0.1349 for all data. FJU-33 crystallizes in monoclinic space group P2₁/c with a=12.7483(5), b=9.9922(3), c=9.8403(3)Å, β=100.756(4)°, V=1231.47(7)Å³, D_c=1.816 g/cm³, C₁₁H₉N₇O₂Zn, M_r=336.62, F(000)=680, μ(CuKα)=2.957 mm^-1, Z=4, R=0.0478 and wR=0.1184 for 2466 observed reflections (I>2σ(I)), and R=0.0687 and wR=0.1309 for all data. In FJU-32, Zn(II) is coordinated to three μ₃-OH groups forming an unprecedented 1D zigzag-like double chain, and the 1D double chains are connected to four neighbouring double chains by the cpt ligands to form an extended 3D porous coordination polymer. In FJU-33, the adjacent[Zn(atrz)] 2D layers are further connected by the cpt ligands via Zn-O coordinated bonds and neighboring interlayer hydrogen-bonding interactions to give rise to an overall 3D pillared layer structure. The neutron triazole group of the cpt ligand has weaker coordination ability than the triazolate anion of atrz ligand. Furthermore, FJU-32 and FJU-33 display high thermal stability up to 300℃, and the solid state fluorescence reveals that two new complexes are potential optical materials.
- bifunctional ligand,
- solvothermal synthesis,
- coordination polymers,
- photoluminescence
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