Citation: CHENG Yue, WANG Xiao-Fang, LV Bei, HU Huai-Ming. Syntheses, Structures and Properties for ZnII Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1953-1959. doi: 10.14102/j.cnki.0254-5861.2011-1215 shu

Syntheses, Structures and Properties for ZnII Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand

  • Corresponding author: HU Huai-Ming, chemhu1@nwu.edu.cn
  • Received Date: 24 March 2016

    Fund Project: the National Natural Science Foundation of China  21173164 and 21473133

Figures(5)

  • Two new ZnII coordination polymers, namely,[ZnL(o-bdc)]n (1) and [ZnL(m-bdc)]n·nH2O (2) (L=4'-(3-pyridyl)-3,2':6',3"-terpyridine, H2(o-bdc)=benzene-1,2-dicarboxylic acid, H2(m-bdc)=benzene-1,3-dicarboxylic acid), were synthesized by hydrothermal methods. The crystal structures have been determined by single-crystal X-ray diffraction. Compound 1 crystallizes in monoclinic C2/c space group, with a=28.016(2), b=11.3815(11), c=19.8071(17)Å, β=133.961(2)°, V=4546.2(7)Å3, Z=8, Mr=539.83, Dc=1.577 Mg/m3, μ=1.127 mm-1, F(000)=2208, the final R=0.0426 and wR=0.0986 for 2875 observed reflections with I>2σ(I) and displays a 1D coordination chain. While compound 2 crystallizes in monoclinic C2/c space group, with a=15.6003(14), b=11.9152(11), c=26.633(3)Å, β=94.320(2)°, V=4936.5(8)Å3, Z=4, Mr=1115.67, Dc=1.496 Mg/m3, μ=1.043 mm-1, F(000)=2272, the final R=0.0499 and wR=0.1342 for 2659 observed reflections with I>2σ(I) and shows a classical 3D cds topological network with point symbol of {65.8}. Furthermore, thermal stability and luminescent properties of 1 and 2 have also been investigated.
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