Citation: CHENG Yue, WANG Xiao-Fang, LV Bei, HU Huai-Ming. Syntheses, Structures and Properties for Zn^II Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1953-1959. doi: 10.14102/j.cnki.0254-5861.2011-1215 shu

Syntheses, Structures and Properties for Zn^II Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand

College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China

Corresponding author: HU Huai-Ming, chemhu1@nwu.edu.cn
Received Date: 24 March 2016

Fund Project: the National Natural Science Foundation of China 21173164 and 21473133

Figures(5)

Two new Zn^II coordination polymers, namely,[ZnL(o-bdc)]_n (1) and [ZnL(m-bdc)]_n·nH₂O (2) (L=4'-(3-pyridyl)-3,2':6',3"-terpyridine, H₂(o-bdc)=benzene-1,2-dicarboxylic acid, H₂(m-bdc)=benzene-1,3-dicarboxylic acid), were synthesized by hydrothermal methods. The crystal structures have been determined by single-crystal X-ray diffraction. Compound 1 crystallizes in monoclinic C2/c space group, with a=28.016(2), b=11.3815(11), c=19.8071(17)Å, β=133.961(2)°, V=4546.2(7)Å³, Z=8, M_r=539.83, D_c=1.577 Mg/m³, μ=1.127 mm^-1, F(000)=2208, the final R=0.0426 and wR=0.0986 for 2875 observed reflections with I>2σ(I) and displays a 1D coordination chain. While compound 2 crystallizes in monoclinic C2/c space group, with a=15.6003(14), b=11.9152(11), c=26.633(3)Å, β=94.320(2)°, V=4936.5(8)Å³, Z=4, M_r=1115.67, D_c=1.496 Mg/m³, μ=1.043 mm^-1, F(000)=2272, the final R=0.0499 and wR=0.1342 for 2659 observed reflections with I>2σ(I) and shows a classical 3D cds topological network with point symbol of {6⁵.8}. Furthermore, thermal stability and luminescent properties of 1 and 2 have also been investigated.
- Zn^II coordination polymers,
- terpyridyl derivatives,
- crystal structures,
- luminescence
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Syntheses, Structures and Properties for ZnII Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand

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通讯作者: 陈斌, bchen63@163.com

Syntheses, Structures and Properties for Zn^II Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand