Citation: CHENG Yue, WANG Xiao-Fang, LV Bei, HU Huai-Ming. Syntheses, Structures and Properties for Zn^II Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1953-1959. doi: 10.14102/j.cnki.0254-5861.2011-1215 shu

Syntheses, Structures and Properties for Zn^II Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand

College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China

Corresponding author: HU Huai-Ming, chemhu1@nwu.edu.cn
Received Date: 24 March 2016
Accepted Date: 6 June 2016

Fund Project: the National Natural Science Foundation of China 21173164 and 21473133

Figures(5)

Two new Zn^II coordination polymers, namely,[ZnL(o-bdc)]_n (1) and [ZnL(m-bdc)]_n·nH₂O (2) (L=4'-(3-pyridyl)-3,2':6',3"-terpyridine, H₂(o-bdc)=benzene-1,2-dicarboxylic acid, H₂(m-bdc)=benzene-1,3-dicarboxylic acid), were synthesized by hydrothermal methods. The crystal structures have been determined by single-crystal X-ray diffraction. Compound 1 crystallizes in monoclinic C2/c space group, with a=28.016(2), b=11.3815(11), c=19.8071(17)Å, β=133.961(2)°, V=4546.2(7)Å³, Z=8, M_r=539.83, D_c=1.577 Mg/m³, μ=1.127 mm^-1, F(000)=2208, the final R=0.0426 and wR=0.0986 for 2875 observed reflections with I>2σ(I) and displays a 1D coordination chain. While compound 2 crystallizes in monoclinic C2/c space group, with a=15.6003(14), b=11.9152(11), c=26.633(3)Å, β=94.320(2)°, V=4936.5(8)Å³, Z=4, M_r=1115.67, D_c=1.496 Mg/m³, μ=1.043 mm^-1, F(000)=2272, the final R=0.0499 and wR=0.1342 for 2659 observed reflections with I>2σ(I) and shows a classical 3D cds topological network with point symbol of {6⁵.8}. Furthermore, thermal stability and luminescent properties of 1 and 2 have also been investigated.
- Zn^II coordination polymers,
- terpyridyl derivatives,
- crystal structures,
- luminescence
1. [1]
  Du M, Li C, Chen M, Ge Z, Wang X, Wang L, Liu C. Divergent kinetic and thermodynamic hydration of a porous Cu(II) coordination polymer with exclusive CO2 sorption selectivity[J]. J. Am. Chem. Soc., 2014,136:10906-10909. doi: 10.1021/ja506357n
2. [2]
  Lu J. F, Min S. T, Ge H. G. Synthesis, crystal structures and properties of two-dimensional complexes constructed by dicarboxylate and bis(imidazole) co-ligands[J]. J. Chem. Res., 2014,11:726-730.
3. [3]
  Luo G. G, Wu D. L, Wu J. H, Xia J. X, Liu L, Dai J. C. Direct observation of conformational change of adipate dianions encapsulated in water clusters[J]. CrystEngComm., 2012,14:5377-5380. doi: 10.1039/c2ce25200g
4. [4]
  Férey G, Serre C. Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences[J]. Chem. Soc. Rev., 2009,38:1380-1399. doi: 10.1039/b804302g
5. [5]
  Wang Z. H, Wang D. F, Zhang T, Huang R. B, Zheng L. S. Synthesis, characterization, crystal structures and thermal and photoluminescence studies of dimethylpyrazine-carboxylate mixed ligand silver(I) coordination polymers with various multinuclear silver units[J]. CrystEngComm., 2014,16:5028-5039. doi: 10.1039/C4CE00072B
6. [6]
  Shinde D. B, Kandambeth S, Pachfule P, Kumar R. R, Banerjee R. Bifunctional covalent organic frameworks with two dimensional organocatalytic micropores[J]. Chem. Commun., 2015,51:310-313. doi: 10.1039/C4CC07104B
7. [7]
  Li Y. W, Li D. C, Xu J, Hao H. G, Wang S. N, Dou J. M, Hu T. L, Bu X. H. Structural modulation in two CuII-based MOFs by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect[J]. Dalton Trans., 2014,43:15708-15712. doi: 10.1039/C4DT02321H
8. [8]
  Qiao J. Z, Zhan M. S, Hu T. P. Syntheses, crystal structures, photoluminescent/magnetic properties of four new coordination polymers based on 2,3?,4,5?-biphenyltetracarboxylic acid[J]. RSC Adv., 2014,4:62285-62294.
9. [9]
  Chang X, Zhao Y, Han M, Ma L, Wang L. Five Cd(II) coordination polymers based on 2,3?,5,5?-biphenyltetracarboxylic acid and N-donor coligands: syntheses, structures and fluorescent properties[J]. CrystEngComm., 2014,16:6417-6424. doi: 10.1039/c4ce00355a
10. [10]
  Ding J. G, Yin C, Zheng L. Y, Han S. S, Li B. L, Wu B. Tuning cadmium coordination architectures using 1,4-bis(1,2,4-triazol-1-ylmethyl) benzene and sulfoisophthalate[J]. RSC Adv., 2014,4:24594-24600. doi: 10.1039/c4ra02291b
11. [11]
  Pan M, Su C. Y. Coordination assembly of Borromean structures[J]. CrystEngComm., 2014,16:7847-7859. doi: 10.1039/C4CE00616J
12. [12]
  Du M, Li C. P, Liu C. S, Fang S. M. Design and construction of coordination polymers with mixed-ligand synthetic strategy[J]. Coord. Chem. Rev., 2013,257:1282-1305. doi: 10.1016/j.ccr.2012.10.002
13. [13]
  Heine J, Gunne J. S, Dehnen S. Formation of a strandlike polycatenane of icosahedral cages for reversible one-dimensional encapsulation of guests[J]. J. Am. Chem. Soc., 2011,133:10018-10021. doi: 10.1021/ja2030273
14. [14]
  Hou L, Li D, Shi W. J, Yin Y. G, Ng S. W. Ligand-controlled mixed-valence copper rectangular grid-type coordination polymers based on pyridylterpyridine[J]. Inorg. Chem., 2005,44:7825-7832. doi: 10.1021/ic050558d
15. [15]
  Gou L, Xu L. F, Hu H. M, Wang B. C, Chen X. L, Tang Z. X. NiII-CdII heterometallic coordination compounds constructed from metal-containing N,N?-rodlike building block (Ni(4?-(3-pyridyl)-2,2?:6?,2??- terpyridine)2)2+ cation[J]. Z. Anorg. Allg. Chem., 2008,634:1215-1220. doi: 10.1002/(ISSN)1521-3749
16. [16]
  Li N, Gou L, Hu H. M, Chen S. H, Chen X. L, Wang B. C, Wu Q. R, Yang M. L, Xue G. L. The effect of organic acid on self-assembly process: syntheses and characterizations of six novel cadmium(II)/zinc(II) complexes derived from mixed ligands[J]. Inorg. Chim. Acta, 2009,362:3475-3483. doi: 10.1016/j.ica.2009.03.033
17. [17]
  Yang X. L, Shangguan Y. Q, Hu H. M, Xu B, Wang B. C, Xie J, Yuan F, Yang M. L, Dong F. X, Xue G. L. Synthesis, crystal structures and luminescent properties of zinc(II) metal-organic frameworks constructed from terpyridyl derivative ligand[J]. J. Solid State Chem., 2014,216:13-22. doi: 10.1016/j.jssc.2014.04.017
18. [18]
  Christopher B. S, Colin L. R, Alexandre N. S. Poly(ethyleneglycol) (PEG): a versatile reaction medium in gaining access to 4?-(pyridyl)-terpyridines[J]. Green Chem., 2005,7:650-654. doi: 10.1039/b507581p
19. [19]
  Zhang X, Hou L, Liu B, Cui L, Wang Y. Y, Wu B. Syntheses, structures, and luminescent properties of six new zinc(II) coordination polymers constructed by flexible tetracarboxylate and various pyridine ligands[J]. Cryst. Growth Des., 2013,13:3177-3187. doi: 10.1021/cg400579w
20. [20]
  Lu J. F, Shi J, Zheng N, Guo X. H, Ge H. G. Synthesis, crystal structure and luminescent property of a Ag(Ι) coordination polymer with a 3D sandwich-like framework[J]. Chin. J. Struct. Chem., 2016,35:293-297.
21. [21]
  Si C. D, Hu D. C, Fan Y, Wu Y, Yao X. Q, Yang Y. X, Liu J. C. Seven coordination polymers derived from semirigid tetracarboxylic acids and N-donor ligands: topological structures, unusual magnetic properties, and photoluminescences[J]. Cryst. Growth Des., 2015,15:2419-2432. doi: 10.1021/acs.cgd.5b00205
1. [1]
  Long TANG , Yaxin BIAN , Luyuan CHEN , Xiangyang HOU , Xiao WANG , Jijiang WANG . Syntheses, structures, and properties of three coordination polymers based on 5-ethylpyridine-2,3-dicarboxylic acid and N-containing ligands. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1975-1985. doi: 10.11862/CJIC.20240180
2. [2]
  Xiaxia LIU , Xiaofang MA , Luxia GUO , Xianda HAN , Sisi FENG . Structure and magnetic properties of Mn(Ⅱ) coordination polymers regulated by N-auxiliary ligands. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 587-596. doi: 10.11862/CJIC.20240269
3. [3]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
4. [4]
  Yanfen PENG , Xinyue WANG , Tianbao LIU , Xiaoshuo WU , Yujing WEI . Syntheses and luminescence of four Cd(Ⅱ)/Zn(Ⅱ) complexes constructed by 1,3‐bis(4H‐1,2,4‐triazole)benzene. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1416-1426. doi: 10.11862/CJIC.20250018
5. [5]
  Xiaofen GUAN , Yating LIU , Jia LI , Yiwen HU , Haiyuan DING , Yuanjing SHI , Zhiqiang WANG , Wenmin WANG . Synthesis, crystal structure, and DNA-binding of binuclear lanthanide complexes based on a multidentate Schiff base ligand. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2486-2496. doi: 10.11862/CJIC.20240122
6. [6]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
7. [7]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273
8. [8]
  Yukun CHEN , Kexin FENG , Bolun ZHANG , Wentao SONG , Jianjun ZHANG . Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448
9. [9]
  Zhenghua ZHAO , Qin ZHANG , Yufeng LIU , Zifa SHI , Jinzhong GU . Syntheses, crystal structures, catalytic and anti-wear properties of nickel(Ⅱ) and zinc(Ⅱ) coordination polymers based on 5-(2-carboxyphenyl)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 621-628. doi: 10.11862/CJIC.20230342
10. [10]
  Weizhong LING , Xiangyun CHEN , Wenjing LIU , Yingkai HUANG , Yu LI . Syntheses, crystal structures, and catalytic properties of three zinc(Ⅱ), cobalt(Ⅱ) and nickel(Ⅱ) coordination polymers constructed from 5-(4-carboxyphenoxy)nicotinic acid. Chinese Journal of Inorganic Chemistry, 2024, 40(9): 1803-1810. doi: 10.11862/CJIC.20240068
11. [11]
  Peng Meng , Qian-Cheng Luo , Aidan Brock , Xiaodong Wang , Mahboobeh Shahbazi , Aaron Micallef , John McMurtrie , Dongchen Qi , Yan-Zhen Zheng , Jingsan Xu . Molar ratio induced crystal transformation from coordination complex to coordination polymers. Chinese Chemical Letters, 2024, 35(4): 108542-. doi: 10.1016/j.cclet.2023.108542
12. [12]
  Gaofeng WANG , Shuwen SUN , Yanfei ZHAO , Lixin MENG , Bohui WEI . Structural diversity and luminescence properties of three zinc coordination polymers based on bis(4-(1H-imidazol-1-yl)phenyl)methanone. Chinese Journal of Inorganic Chemistry, 2024, 40(5): 849-856. doi: 10.11862/CJIC.20230479
13. [13]
  Yuanpeng Ye , Longfei Yao , Guofeng Liu . Engineering circularly polarized luminescence through symmetry manipulation in achiral tetraphenylpyrazine structures. Chinese Journal of Structural Chemistry, 2025, 44(2): 100460-100460. doi: 10.1016/j.cjsc.2024.100460
14. [14]
  Hongjie SHEN , Haozhe MIAO , Yuhe YANG , Yinghua LI , Deguang HUANG , Xiaofeng ZHANG . Synthesis, crystal structure, and fluorescence properties of two Cu(Ⅰ) complexes based on pyridyl ligand. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 855-863. doi: 10.11862/CJIC.20250009
15. [15]
  Shuwen SUN , Gaofeng WANG . Two cadmium coordination polymers constructed by varying Ⅴ-shaped co-ligands: Syntheses, structures, and fluorescence properties. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 613-620. doi: 10.11862/CJIC.20230368
16. [16]
  Haitang WANG , Yanni LING , Xiaqing MA , Yuxin CHEN , Rui ZHANG , Keyi WANG , Ying ZHANG , Wenmin WANG . Construction, crystal structures, and biological activities of two Ln^Ⅲ₃ complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1474-1482. doi: 10.11862/CJIC.20240188
17. [17]
  Changqing MIAO , Fengjiao CHEN , Wenyu LI , Shujie WEI , Yuqing YAO , Keyi WANG , Ni WANG , Xiaoyan XIN , Ming FANG . Crystal structures, DNA action, and antibacterial activities of three tetranuclear lanthanide-based complexes. Chinese Journal of Inorganic Chemistry, 2024, 40(12): 2455-2465. doi: 10.11862/CJIC.20240192
18. [18]
  Yuxin CHEN , Yanni LING , Yuqing YAO , Keyi WANG , Linna LI , Xin ZHANG , Qin WANG , Hongdao LI , Wenmin WANG . Construction, structures, and interaction with DNA of two Sm^Ⅲ₄ complexes. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1141-1150. doi: 10.11862/CJIC.20240258
19. [19]
  Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
20. [20]
  Yang Li , Yihan Chen , Jiaxin Luo , Qihuan Li , Yiwu Quan , Yixiang Cheng . Enhanced circularly polarized luminescence emission promoted by achiral dichroic oligomers of F8BT in cholesteric liquid crystal. Chinese Chemical Letters, 2024, 35(11): 109864-. doi: 10.1016/j.cclet.2024.109864

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(4556)
HTML views(126)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses, Structures and Properties for ZnII Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand

Metrics

通讯作者: 陈斌, bchen63@163.com

Syntheses, Structures and Properties for Zn^II Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand