Citation: CHENG Yue, WANG Xiao-Fang, LV Bei, HU Huai-Ming. Syntheses, Structures and Properties for Zn^II Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1953-1959. doi: 10.14102/j.cnki.0254-5861.2011-1215 shu

Syntheses, Structures and Properties for Zn^II Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand

College of Chemistry and Materials Science, Northwest University, Xi'an 710127, China

Corresponding author: HU Huai-Ming, chemhu1@nwu.edu.cn
Received Date: 24 March 2016

Fund Project: the National Natural Science Foundation of China 21173164 and 21473133

Figures(5)

Two new Zn^II coordination polymers, namely,[ZnL(o-bdc)]_n (1) and [ZnL(m-bdc)]_n·nH₂O (2) (L=4'-(3-pyridyl)-3,2':6',3"-terpyridine, H₂(o-bdc)=benzene-1,2-dicarboxylic acid, H₂(m-bdc)=benzene-1,3-dicarboxylic acid), were synthesized by hydrothermal methods. The crystal structures have been determined by single-crystal X-ray diffraction. Compound 1 crystallizes in monoclinic C2/c space group, with a=28.016(2), b=11.3815(11), c=19.8071(17)Å, β=133.961(2)°, V=4546.2(7)Å³, Z=8, M_r=539.83, D_c=1.577 Mg/m³, μ=1.127 mm^-1, F(000)=2208, the final R=0.0426 and wR=0.0986 for 2875 observed reflections with I>2σ(I) and displays a 1D coordination chain. While compound 2 crystallizes in monoclinic C2/c space group, with a=15.6003(14), b=11.9152(11), c=26.633(3)Å, β=94.320(2)°, V=4936.5(8)Å³, Z=4, M_r=1115.67, D_c=1.496 Mg/m³, μ=1.043 mm^-1, F(000)=2272, the final R=0.0499 and wR=0.1342 for 2659 observed reflections with I>2σ(I) and shows a classical 3D cds topological network with point symbol of {6⁵.8}. Furthermore, thermal stability and luminescent properties of 1 and 2 have also been investigated.
- Zn^II coordination polymers,
- terpyridyl derivatives,
- crystal structures,
- luminescence
1. [1]
  Du M, Li C, Chen M, Ge Z, Wang X, Wang L, Liu C. Divergent kinetic and thermodynamic hydration of a porous Cu(II) coordination polymer with exclusive CO2 sorption selectivity[J]. J. Am. Chem. Soc., 2014,136:10906-10909. doi: 10.1021/ja506357n
2. [2]
  Lu J. F, Min S. T, Ge H. G. Synthesis, crystal structures and properties of two-dimensional complexes constructed by dicarboxylate and bis(imidazole) co-ligands[J]. J. Chem. Res., 2014,11:726-730.
3. [3]
  Luo G. G, Wu D. L, Wu J. H, Xia J. X, Liu L, Dai J. C. Direct observation of conformational change of adipate dianions encapsulated in water clusters[J]. CrystEngComm., 2012,14:5377-5380. doi: 10.1039/c2ce25200g
4. [4]
  Férey G, Serre C. Large breathing effects in three-dimensional porous hybrid matter: facts, analyses, rules and consequences[J]. Chem. Soc. Rev., 2009,38:1380-1399. doi: 10.1039/b804302g
5. [5]
  Wang Z. H, Wang D. F, Zhang T, Huang R. B, Zheng L. S. Synthesis, characterization, crystal structures and thermal and photoluminescence studies of dimethylpyrazine-carboxylate mixed ligand silver(I) coordination polymers with various multinuclear silver units[J]. CrystEngComm., 2014,16:5028-5039. doi: 10.1039/C4CE00072B
6. [6]
  Shinde D. B, Kandambeth S, Pachfule P, Kumar R. R, Banerjee R. Bifunctional covalent organic frameworks with two dimensional organocatalytic micropores[J]. Chem. Commun., 2015,51:310-313. doi: 10.1039/C4CC07104B
7. [7]
  Li Y. W, Li D. C, Xu J, Hao H. G, Wang S. N, Dou J. M, Hu T. L, Bu X. H. Structural modulation in two CuII-based MOFs by synergistic assembly involving the mixed-ligand synthetic strategy and the solvent effect[J]. Dalton Trans., 2014,43:15708-15712. doi: 10.1039/C4DT02321H
8. [8]
  Qiao J. Z, Zhan M. S, Hu T. P. Syntheses, crystal structures, photoluminescent/magnetic properties of four new coordination polymers based on 2,3?,4,5?-biphenyltetracarboxylic acid[J]. RSC Adv., 2014,4:62285-62294.
9. [9]
  Chang X, Zhao Y, Han M, Ma L, Wang L. Five Cd(II) coordination polymers based on 2,3?,5,5?-biphenyltetracarboxylic acid and N-donor coligands: syntheses, structures and fluorescent properties[J]. CrystEngComm., 2014,16:6417-6424. doi: 10.1039/c4ce00355a
10. [10]
  Ding J. G, Yin C, Zheng L. Y, Han S. S, Li B. L, Wu B. Tuning cadmium coordination architectures using 1,4-bis(1,2,4-triazol-1-ylmethyl) benzene and sulfoisophthalate[J]. RSC Adv., 2014,4:24594-24600. doi: 10.1039/c4ra02291b
11. [11]
  Pan M, Su C. Y. Coordination assembly of Borromean structures[J]. CrystEngComm., 2014,16:7847-7859. doi: 10.1039/C4CE00616J
12. [12]
  Du M, Li C. P, Liu C. S, Fang S. M. Design and construction of coordination polymers with mixed-ligand synthetic strategy[J]. Coord. Chem. Rev., 2013,257:1282-1305. doi: 10.1016/j.ccr.2012.10.002
13. [13]
  Heine J, Gunne J. S, Dehnen S. Formation of a strandlike polycatenane of icosahedral cages for reversible one-dimensional encapsulation of guests[J]. J. Am. Chem. Soc., 2011,133:10018-10021. doi: 10.1021/ja2030273
14. [14]
  Hou L, Li D, Shi W. J, Yin Y. G, Ng S. W. Ligand-controlled mixed-valence copper rectangular grid-type coordination polymers based on pyridylterpyridine[J]. Inorg. Chem., 2005,44:7825-7832. doi: 10.1021/ic050558d
15. [15]
  Gou L, Xu L. F, Hu H. M, Wang B. C, Chen X. L, Tang Z. X. NiII-CdII heterometallic coordination compounds constructed from metal-containing N,N?-rodlike building block (Ni(4?-(3-pyridyl)-2,2?:6?,2??- terpyridine)2)2+ cation[J]. Z. Anorg. Allg. Chem., 2008,634:1215-1220. doi: 10.1002/(ISSN)1521-3749
16. [16]
  Li N, Gou L, Hu H. M, Chen S. H, Chen X. L, Wang B. C, Wu Q. R, Yang M. L, Xue G. L. The effect of organic acid on self-assembly process: syntheses and characterizations of six novel cadmium(II)/zinc(II) complexes derived from mixed ligands[J]. Inorg. Chim. Acta, 2009,362:3475-3483. doi: 10.1016/j.ica.2009.03.033
17. [17]
  Yang X. L, Shangguan Y. Q, Hu H. M, Xu B, Wang B. C, Xie J, Yuan F, Yang M. L, Dong F. X, Xue G. L. Synthesis, crystal structures and luminescent properties of zinc(II) metal-organic frameworks constructed from terpyridyl derivative ligand[J]. J. Solid State Chem., 2014,216:13-22. doi: 10.1016/j.jssc.2014.04.017
18. [18]
  Christopher B. S, Colin L. R, Alexandre N. S. Poly(ethyleneglycol) (PEG): a versatile reaction medium in gaining access to 4?-(pyridyl)-terpyridines[J]. Green Chem., 2005,7:650-654. doi: 10.1039/b507581p
19. [19]
  Zhang X, Hou L, Liu B, Cui L, Wang Y. Y, Wu B. Syntheses, structures, and luminescent properties of six new zinc(II) coordination polymers constructed by flexible tetracarboxylate and various pyridine ligands[J]. Cryst. Growth Des., 2013,13:3177-3187. doi: 10.1021/cg400579w
20. [20]
  Lu J. F, Shi J, Zheng N, Guo X. H, Ge H. G. Synthesis, crystal structure and luminescent property of a Ag(Ι) coordination polymer with a 3D sandwich-like framework[J]. Chin. J. Struct. Chem., 2016,35:293-297.
21. [21]
  Si C. D, Hu D. C, Fan Y, Wu Y, Yao X. Q, Yang Y. X, Liu J. C. Seven coordination polymers derived from semirigid tetracarboxylic acids and N-donor ligands: topological structures, unusual magnetic properties, and photoluminescences[J]. Cryst. Growth Des., 2015,15:2419-2432. doi: 10.1021/acs.cgd.5b00205
1. [1]
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2. [2]
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3. [3]
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4. [4]
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6. [6]
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8. [8]
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9. [9]
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10. [10]
  XU Bo , LI Ling , LI Jie , LI Cun-Cheng . Crystal Structure and Luminescent Property of a Coordination Complex Constructed with Pyrazine and 1,4-Phenylenediacetic Acid. Chinese Journal of Structural Chemistry, 2014, 33(12): 1826-1830. doi: 10.14102/j.cnki.0254-5861.2011-0378
11. [11]
  ZHANG Xu , GE Ming , HECKE Kristof Van , CUI Guang-Hua . Synthesis, Crystal Structure and Catalytic Properties of a 2D Cobalt(Ⅱ) Coordination Polymer Based on Mixed Ligands. Chinese Journal of Structural Chemistry, 2015, 34(4): 599-605. doi: 10.14102/j.cnki.0254-5861.2011-0542
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13. [13]
  LI Shu-Jing , LI Ke , QU Bo-Tao , ZHENG Wei . Synthesis, Crystal Structure and Properties of a New Zn(Ⅱ) Coordination Polymer Constructed from 2,3-Pyridine Dicarboxylic Acid and 1,1'-(1,4-Butanediyl)bis(imidazole). Chinese Journal of Structural Chemistry, 2014, 33(2): 193-198.
14. [14]
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15. [15]
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16. [16]
  GUO Feng . A Novel 6-Connected Self-interpenetrated Zn(II) Coordination Polymer Based on 1,4-Bis(2-methylimidazole-3-ium-1-yl)biphenyl and Dicarboxylate Ligand: Synthesis, Crystal Structure and Luminescent Property. Chinese Journal of Structural Chemistry, 2016, 34(10): 1579-1584. doi: 10.14102/j.cnki.0254-5861.2011-0697
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沈阳化工大学材料科学与工程学院沈阳 110142

Syntheses, Structures and Properties for ZnII Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand

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通讯作者: 陈斌, bchen63@163.com

Syntheses, Structures and Properties for Zn^II Coordination Polymers Based on a Functional 4'-(3-Pyridyl)-3,2': 6',3"-terpyridine Ligand