Citation: MIAO Shao-Bin, LI Zhao-Hao, XU Chun-Yin, JI Bao-Ming. A New 3-Fold Interpenetrating 3D Zn(II) Metal-organic Framework: Synthesis, Structure and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1960-1966. doi: 10.14102/j.cnki.0254-5861.2011-1209 shu

A New 3-Fold Interpenetrating 3D Zn(II) Metal-organic Framework: Synthesis, Structure and Luminescent Property

  • Corresponding author: JI Bao-Ming, lyhxxjbm@126.com
  • Received Date: 21 March 2016

    Fund Project: the National Natural Science Foundation of China 21372112the Science and Technology Research Projects of Education Department of Henan Province 15A150064

Figures(5)

  • A new Zn(II) coordination polymer, namely {[Zn1.5(1,3,5-btc3-)(dtb)(H2O)](H2O)2}n (1) (1,3,5-H3btc=1,3,5-benzenetricarboxylic acid, dtb=1,3-di-(1,2,4-triazole-4-yl)benzene), has been hydrothermally synthesized and structurally characterized. X-ray single-crystal diffraction determination reveals that 1 crystallizes in the monoclinic C2/c space group with a=33.811(12), b=8.406(2), c=17.296(4)Å, β=120.593(2)°, V=4232(2)Å3, Z=4, Mr=1142.88, Dc=1.794 Mg/m3, μ=1.783 mm-1, F(000)=2320, the final R=0.0338 and wR=0.0827 for 3043 observed reflections with I>2σ(I). Compound 1 exhibits 1D Zn(II)-carboxylate chains, which are connected into a 3D porous framework with large channels by dtb, and then three identical 3D networks are interpenetrated with each other. In addition, the luminescence property of the complex has also been investigated.
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    1. [1]

      Allendorf M. D, Bauer C. A, Bhakta R. K, Houk R. J. T. Luminescent metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1330-1352. doi: 10.1039/b802352m

    2. [2]

      Kurmoo M. Magnetic metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1353-1379. doi: 10.1039/b804757j

    3. [3]

      Li J. R, Kuppler R. J, Zhou H. C. Selective gas adsorption and separation in metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1477-1504. doi: 10.1039/b802426j

    4. [4]

      Janiak C. Engineering coordination polymers towards applications[J]. Dalton Trans., 2003,14:2781-2804.  

    5. [5]

      Kitagawa S, Kitaura R, Noro S. Functional porous coordination polymers[J]. Angew. Chem. Int. Ed., 2004,43:2334-2375. doi: 10.1002/(ISSN)1521-3773

    6. [6]

      Wu C. D, Hu A. G, Zhang L, Lin W. B. A homochiral porous metal-organic framework for highly enantioselective heterogeneous asymmetric catalysis[J]. J. Am. Chem. Soc., 2005,127:8940-8941. doi: 10.1021/ja052431t

    7. [7]

      Bai H. Y, Ma J. F, Yang J, Zhang L. P, Ma J. C, Liu Y. Y. Eight two-dimensional and three-dimensional metal-organic frameworks based on a flexible tetrakis(imidazole) ligand: synthesis, topological structures, and photoluminescent properties[J]. Cryst. Growth Des., 2010,10:1946-1959. doi: 10.1021/cg100032n

    8. [8]

      Chang X. H, Zhao Y, Han M. L, Ma L. F, Wang L. Y. Five Cd(II) coordination polymers based on 2,3?,5,5?-biphenyltetracarboxylic acid and N-donor coligands: syntheses, structures and fluorescent properties[J]. CrystEngComm., 2014,16:6417-6425. doi: 10.1039/c4ce00355a

    9. [9]

      Wu H, Liu H. Y, Liu Y. Y, Yang J, Liu B, Ma J. F. An unprecedented 2D → 3D metal-organic polyrotaxane framework constructed from cadmium and a flexible star-like ligand[J]. Chem. Commun., 2011,47:1818-1820. doi: 10.1039/C0CC04724D

    10. [10]

      Wang, X. L.; Le, M.; Lin, H. Y.; Luan, J. ; Liu, G. C.; Zhang, J. W.; Tian, A. X. A 3-fold interpenetrating 3D Cu(II) coordination polymer based on a semi-rigid naphthalene-based bis-pyridyl-bis-amide and thiophene-2,5-dicarboxylate. Inorg. Chem. Commun. 2014, 49, 19-23.

    11. [11]

      Chui S. S. Y, Lo S. M. F, Charmant J. P. H, Orpen A. G, Williams I. D. A chemically functionalizable nanoporous material[J]. Science, 1999,283:1148-1150. doi: 10.1126/science.283.5405.1148

    12. [12]

      Liu Y. Y, Liu H. Y, Ma J. F, Yang Y, Yang J. Syntheses, structures and photoluminescent properties of Zn(II) and Cd(II) coordination polymers with flexible tripodal triazole-containing ligands[J]. CrystEngComm., 2013,15:1897-1907. doi: 10.1039/c2ce26958a

    13. [13]

      Bu, F.; Xiao, S. J. A 4-connected anionic metal-organic nanotube constructed from indium isophthalate. CrystEngComm. 2010, 12, 3385-3387.

    14. [14]

      Xue Y. S, Jin F. Y, Zhou L, Liu M. P, Xu Y, Du H. B, Fang M, You X. Z. Structural diversity and properties of coordination polymers built from a rigid octadentenate carboxylic acid[J]. Cryst. Growth Des., 2012,12:6158-6164. doi: 10.1021/cg301319u

    15. [15]

      Rao, K. P.; Higuchi, M.; Duan, J.; Kitagawa, S. pH-Dependent interpenetrated, polymorphic, Cd2+- and BTB-based porous coordination polymers with open metal sites. Cryst. Growth Des. 2013, 13, 981-985.

    16. [16]

      Sun D, Yan Z. H, Blatov V. A, Wang L, Sun D. F. Syntheses, topological structures, and photoluminescences of six new Zn(II) coordination polymers based on mixed tripodal imidazole ligand and varied polycarboxylates[J]. Cryst. Growth Des., 2013,13:1277-1289. doi: 10.1021/cg3017358

    17. [17]

      Aromí G, Barrios L. A, Roubeau O, Gamez P. Triazoles and tetrazoles: prime ligands to generate remarkable coordination materials[J]. Coord. Chem. Rev., 2011,255:485-546. doi: 10.1016/j.ccr.2010.10.038

    18. [18]

      Zhu A. X, Lin J. B, Zhang J. P, Chen X. M. Isomeric zinc(II) triazolate frameworks with 3-connected networks: syntheses, structures, and sorption properties[J]. Inorg. Chem., 2009,48:3882-3889. doi: 10.1021/ic802446m

    19. [19]

      Ding B, Yi L, Wang Y, Cheng P, Liao D. Z, Yan S. P, Jiang Z. H, Song H. B, Wang H. G. Synthesis of a series of 4-pyridyl-1,2,4-triazolecontaining cadmium(II) luminescent complexes[J]. Dalton Trans., 2006,5:665-675.  

    20. [20]

      Zhang J. P, Chen X. M. Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework[J]. J. Am. Chem. Soc., 2008,130:6010-6017. doi: 10.1021/ja800550a

    21. [21]

      Haasnoot J. G. Mononuclear, oligonuclear and polynuclear metal coordination compounds with 1,2,4-triazole derivatives as ligands[J]. Coord. Chem. Rev., 2000,200.  

    22. [22]

      Liu K, Shi W, Cheng P. The coordination chemistry of Zn(II), Cd(II) and Hg(II) complexes with 1,2,4-triazole derivatives[J]. Dalton Trans., 2011,40:8475-8490. doi: 10.1039/c0dt01578d

    23. [23]

      Zhou X. H, Du X. D, Li G. N, Zuo J. L, You X. Z. Coordination polymers assembled from 3,5-pyrazoledicarboxylic acid and bis(triazolyl) ligands: chiral and meso-structures induced by ligand flexibility and a six-connected self-catenated network[J]. Cryst. Growth Des., 2009,9:4487-4496. doi: 10.1021/cg900509r

    24. [24]

      Yang P, Wu X. X, Huo J. Z, Ding B, Wang Y, Wang X. G. Hydrothermal synthesis and characterization of a series of luminescent Zn(II) and Cd(II) coordination polymers with the new versatile multidentate ligand 1,3-di-(1,2,4-triazol-4-yl)benzene[J]. CrystEngComm., 2013,15:8097-8109. doi: 10.1039/c3ce40946e

    25. [25]

      Miao S. B, Li Z. H, Ji B. M, Deng D. S, Xu C. Y, Zhou L. Synthesis, crystal structure, and properties of a 3D Cu(I) coordination polymer based on Cu3(CN)2 clusters and 1,3-di-(1,2,4-triazole-4-yl)benzene[J]. J. Clust. Sci., 2014,25:1137-1145. doi: 10.1007/s10876-014-0695-3

    26. [26]

      Miao S. B, Ji B. M, Wang Y. F, Li Z. H, Deng D. S, Xu C. Y, Zhou L. A new 3D pillared-layer porous framework with intersecting open channels in the Co/triazolate/carboxylate system: synthesis, structure and magnetism[J]. Inorg. Chem. Commun., 2015,62:47-50. doi: 10.1016/j.inoche.2015.10.024

    27. [27]

      Qin X, Fan Z, Xu Y. Y, Ding B, Wang Y, Wang X. G. Two novel 3D porous copper(II) and zinc(II) frameworks with 1,3-di-(1,2,4-triazole- 4-yl)benzene: 4-connected dmp network versus 6-connnected α-Po network based on trinuclear zinc(II) clusters[J]. Inorg. Chem. Commun., 2013,37:166-169. doi: 10.1016/j.inoche.2013.09.032

    28. [28]

      Sheldrick, G. M. SHELXS-97. Program for the Solution of Crystal Structures. University of G?ttingen: Germany 1997.

    29. [29]

      Sheldrick, G. M. SHELXL-97. Program for the Refinement of Crystal Structures. University of G?ttingen: Germany 1997.

    30. [30]

      Yang, L.; Powell, D. R.; Houser, R. P. Structural variation in copper(I) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, τ4. Dalton Trans. 2007, 9, 955-964.

    31. [31]

      Chen W, Wang J. Y, Chen C, Yue Q, Yuan H. M, Chen J. S, Wang S. N. Photoluminescent metal-organic polymer constructed from trimetallic clusters and mixed carboxylates[J]. Inorg. Chem., 2003,42:944-946. doi: 10.1021/ic025871j

    32. [32]

      Bai H. Y, Yang J, Liu B, Ma J. F, Kan W. Q, Liu Y. Y, Liu Y. Y. Syntheses, structures, and photoluminescence of five silver(I) coordination polymers based on tetrakis(imidazol-1-ylmethyl)methane[J]. CrystEngCommun., 2011,13:5877-5884. doi: 10.1039/c0ce00834f

    33. [33]

      Kong Z. G, Guo S. N, Yu M, Feng S. Y, Hu B. A new luminescent Cd(II) coordination polymer constructed by mixed 1,4-naphthalenedicarboxylate and N-donor chelating ligand[J]. Chin. J. Struct. Chem., 2016,35:591-596.  

    34. [34]

      Jin S, Gu Q. Y, Chen J, Wang Y. Z, Yuan G. Z. Crystal structures and photoluminescent properties of two Cd2+ coordination polymers constructed from an 8-hydroxyquinolinate ligand[J]. Chin. J. Struct. Chem., 2016,35929.  

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