Citation: MIAO Shao-Bin, LI Zhao-Hao, XU Chun-Yin, JI Bao-Ming. A New 3-Fold Interpenetrating 3D Zn(II) Metal-organic Framework: Synthesis, Structure and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1960-1966. doi: 10.14102/j.cnki.0254-5861.2011-1209 shu

A New 3-Fold Interpenetrating 3D Zn(II) Metal-organic Framework: Synthesis, Structure and Luminescent Property

College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Corresponding author: JI Bao-Ming, lyhxxjbm@126.com
Received Date: 21 March 2016

Fund Project: the National Natural Science Foundation of China 21372112the Science and Technology Research Projects of Education Department of Henan Province 15A150064

Figures(5)

A new Zn(II) coordination polymer, namely {[Zn_1.5(1,3,5-btc^3-)(dtb)(H₂O)](H₂O)₂}_n (1) (1,3,5-H₃btc=1,3,5-benzenetricarboxylic acid, dtb=1,3-di-(1,2,4-triazole-4-yl)benzene), has been hydrothermally synthesized and structurally characterized. X-ray single-crystal diffraction determination reveals that 1 crystallizes in the monoclinic C2/c space group with a=33.811(12), b=8.406(2), c=17.296(4)Å, β=120.593(2)°, V=4232(2)Å³, Z=4, M_r=1142.88, D_c=1.794 Mg/m³, μ=1.783 mm^-1, F(000)=2320, the final R=0.0338 and wR=0.0827 for 3043 observed reflections with I>2σ(I). Compound 1 exhibits 1D Zn(II)-carboxylate chains, which are connected into a 3D porous framework with large channels by dtb, and then three identical 3D networks are interpenetrated with each other. In addition, the luminescence property of the complex has also been investigated.
- metal-organic framework,
- 1,3-di-(1,2,4-triazole-4-yl)benzene,
- crystal structure,
- luminescence
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