Citation: MIAO Shao-Bin, LI Zhao-Hao, XU Chun-Yin, JI Bao-Ming. A New 3-Fold Interpenetrating 3D Zn(II) Metal-organic Framework: Synthesis, Structure and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1960-1966. doi: 10.14102/j.cnki.0254-5861.2011-1209 shu

A New 3-Fold Interpenetrating 3D Zn(II) Metal-organic Framework: Synthesis, Structure and Luminescent Property

College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Corresponding author: JI Bao-Ming, lyhxxjbm@126.com
Received Date: 21 March 2016
Accepted Date: 13 July 2016

Fund Project: the National Natural Science Foundation of China 21372112the Science and Technology Research Projects of Education Department of Henan Province 15A150064

Figures(5)

A new Zn(II) coordination polymer, namely {[Zn_1.5(1,3,5-btc^3-)(dtb)(H₂O)](H₂O)₂}_n (1) (1,3,5-H₃btc=1,3,5-benzenetricarboxylic acid, dtb=1,3-di-(1,2,4-triazole-4-yl)benzene), has been hydrothermally synthesized and structurally characterized. X-ray single-crystal diffraction determination reveals that 1 crystallizes in the monoclinic C2/c space group with a=33.811(12), b=8.406(2), c=17.296(4)Å, β=120.593(2)°, V=4232(2)Å³, Z=4, M_r=1142.88, D_c=1.794 Mg/m³, μ=1.783 mm^-1, F(000)=2320, the final R=0.0338 and wR=0.0827 for 3043 observed reflections with I>2σ(I). Compound 1 exhibits 1D Zn(II)-carboxylate chains, which are connected into a 3D porous framework with large channels by dtb, and then three identical 3D networks are interpenetrated with each other. In addition, the luminescence property of the complex has also been investigated.
- metal-organic framework,
- 1,3-di-(1,2,4-triazole-4-yl)benzene,
- crystal structure,
- luminescence
1. [1]
  Allendorf M. D, Bauer C. A, Bhakta R. K, Houk R. J. T. Luminescent metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1330-1352. doi: 10.1039/b802352m
2. [2]
  Kurmoo M. Magnetic metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1353-1379. doi: 10.1039/b804757j
3. [3]
  Li J. R, Kuppler R. J, Zhou H. C. Selective gas adsorption and separation in metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1477-1504. doi: 10.1039/b802426j
4. [4]
  Janiak C. Engineering coordination polymers towards applications[J]. Dalton Trans., 2003,14:2781-2804.
5. [5]
  Kitagawa S, Kitaura R, Noro S. Functional porous coordination polymers[J]. Angew. Chem. Int. Ed., 2004,43:2334-2375. doi: 10.1002/(ISSN)1521-3773
6. [6]
  Wu C. D, Hu A. G, Zhang L, Lin W. B. A homochiral porous metal-organic framework for highly enantioselective heterogeneous asymmetric catalysis[J]. J. Am. Chem. Soc., 2005,127:8940-8941. doi: 10.1021/ja052431t
7. [7]
  Bai H. Y, Ma J. F, Yang J, Zhang L. P, Ma J. C, Liu Y. Y. Eight two-dimensional and three-dimensional metal-organic frameworks based on a flexible tetrakis(imidazole) ligand: synthesis, topological structures, and photoluminescent properties[J]. Cryst. Growth Des., 2010,10:1946-1959. doi: 10.1021/cg100032n
8. [8]
  Chang X. H, Zhao Y, Han M. L, Ma L. F, Wang L. Y. Five Cd(II) coordination polymers based on 2,3?,5,5?-biphenyltetracarboxylic acid and N-donor coligands: syntheses, structures and fluorescent properties[J]. CrystEngComm., 2014,16:6417-6425. doi: 10.1039/c4ce00355a
9. [9]
  Wu H, Liu H. Y, Liu Y. Y, Yang J, Liu B, Ma J. F. An unprecedented 2D → 3D metal-organic polyrotaxane framework constructed from cadmium and a flexible star-like ligand[J]. Chem. Commun., 2011,47:1818-1820. doi: 10.1039/C0CC04724D
10. [10]
  Wang, X. L.; Le, M.; Lin, H. Y.; Luan, J. ; Liu, G. C.; Zhang, J. W.; Tian, A. X. A 3-fold interpenetrating 3D Cu(II) coordination polymer based on a semi-rigid naphthalene-based bis-pyridyl-bis-amide and thiophene-2,5-dicarboxylate. Inorg. Chem. Commun. 2014, 49, 19-23.
11. [11]
  Chui S. S. Y, Lo S. M. F, Charmant J. P. H, Orpen A. G, Williams I. D. A chemically functionalizable nanoporous material[J]. Science, 1999,283:1148-1150. doi: 10.1126/science.283.5405.1148
12. [12]
  Liu Y. Y, Liu H. Y, Ma J. F, Yang Y, Yang J. Syntheses, structures and photoluminescent properties of Zn(II) and Cd(II) coordination polymers with flexible tripodal triazole-containing ligands[J]. CrystEngComm., 2013,15:1897-1907. doi: 10.1039/c2ce26958a
13. [13]
  Bu, F.; Xiao, S. J. A 4-connected anionic metal-organic nanotube constructed from indium isophthalate. CrystEngComm. 2010, 12, 3385-3387.
14. [14]
  Xue Y. S, Jin F. Y, Zhou L, Liu M. P, Xu Y, Du H. B, Fang M, You X. Z. Structural diversity and properties of coordination polymers built from a rigid octadentenate carboxylic acid[J]. Cryst. Growth Des., 2012,12:6158-6164. doi: 10.1021/cg301319u
15. [15]
  Rao, K. P.; Higuchi, M.; Duan, J.; Kitagawa, S. pH-Dependent interpenetrated, polymorphic, Cd2+- and BTB-based porous coordination polymers with open metal sites. Cryst. Growth Des. 2013, 13, 981-985.
16. [16]
  Sun D, Yan Z. H, Blatov V. A, Wang L, Sun D. F. Syntheses, topological structures, and photoluminescences of six new Zn(II) coordination polymers based on mixed tripodal imidazole ligand and varied polycarboxylates[J]. Cryst. Growth Des., 2013,13:1277-1289. doi: 10.1021/cg3017358
17. [17]
  Aromí G, Barrios L. A, Roubeau O, Gamez P. Triazoles and tetrazoles: prime ligands to generate remarkable coordination materials[J]. Coord. Chem. Rev., 2011,255:485-546. doi: 10.1016/j.ccr.2010.10.038
18. [18]
  Zhu A. X, Lin J. B, Zhang J. P, Chen X. M. Isomeric zinc(II) triazolate frameworks with 3-connected networks: syntheses, structures, and sorption properties[J]. Inorg. Chem., 2009,48:3882-3889. doi: 10.1021/ic802446m
19. [19]
  Ding B, Yi L, Wang Y, Cheng P, Liao D. Z, Yan S. P, Jiang Z. H, Song H. B, Wang H. G. Synthesis of a series of 4-pyridyl-1,2,4-triazolecontaining cadmium(II) luminescent complexes[J]. Dalton Trans., 2006,5:665-675.
20. [20]
  Zhang J. P, Chen X. M. Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework[J]. J. Am. Chem. Soc., 2008,130:6010-6017. doi: 10.1021/ja800550a
21. [21]
  Haasnoot J. G. Mononuclear, oligonuclear and polynuclear metal coordination compounds with 1,2,4-triazole derivatives as ligands[J]. Coord. Chem. Rev., 2000,200.
22. [22]
  Liu K, Shi W, Cheng P. The coordination chemistry of Zn(II), Cd(II) and Hg(II) complexes with 1,2,4-triazole derivatives[J]. Dalton Trans., 2011,40:8475-8490. doi: 10.1039/c0dt01578d
23. [23]
  Zhou X. H, Du X. D, Li G. N, Zuo J. L, You X. Z. Coordination polymers assembled from 3,5-pyrazoledicarboxylic acid and bis(triazolyl) ligands: chiral and meso-structures induced by ligand flexibility and a six-connected self-catenated network[J]. Cryst. Growth Des., 2009,9:4487-4496. doi: 10.1021/cg900509r
24. [24]
  Yang P, Wu X. X, Huo J. Z, Ding B, Wang Y, Wang X. G. Hydrothermal synthesis and characterization of a series of luminescent Zn(II) and Cd(II) coordination polymers with the new versatile multidentate ligand 1,3-di-(1,2,4-triazol-4-yl)benzene[J]. CrystEngComm., 2013,15:8097-8109. doi: 10.1039/c3ce40946e
25. [25]
  Miao S. B, Li Z. H, Ji B. M, Deng D. S, Xu C. Y, Zhou L. Synthesis, crystal structure, and properties of a 3D Cu(I) coordination polymer based on Cu3(CN)2 clusters and 1,3-di-(1,2,4-triazole-4-yl)benzene[J]. J. Clust. Sci., 2014,25:1137-1145. doi: 10.1007/s10876-014-0695-3
26. [26]
  Miao S. B, Ji B. M, Wang Y. F, Li Z. H, Deng D. S, Xu C. Y, Zhou L. A new 3D pillared-layer porous framework with intersecting open channels in the Co/triazolate/carboxylate system: synthesis, structure and magnetism[J]. Inorg. Chem. Commun., 2015,62:47-50. doi: 10.1016/j.inoche.2015.10.024
27. [27]
  Qin X, Fan Z, Xu Y. Y, Ding B, Wang Y, Wang X. G. Two novel 3D porous copper(II) and zinc(II) frameworks with 1,3-di-(1,2,4-triazole- 4-yl)benzene: 4-connected dmp network versus 6-connnected α-Po network based on trinuclear zinc(II) clusters[J]. Inorg. Chem. Commun., 2013,37:166-169. doi: 10.1016/j.inoche.2013.09.032
28. [28]
  Sheldrick, G. M. SHELXS-97. Program for the Solution of Crystal Structures. University of G?ttingen: Germany 1997.
29. [29]
  Sheldrick, G. M. SHELXL-97. Program for the Refinement of Crystal Structures. University of G?ttingen: Germany 1997.
30. [30]
  Yang, L.; Powell, D. R.; Houser, R. P. Structural variation in copper(I) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, τ4. Dalton Trans. 2007, 9, 955-964.
31. [31]
  Chen W, Wang J. Y, Chen C, Yue Q, Yuan H. M, Chen J. S, Wang S. N. Photoluminescent metal-organic polymer constructed from trimetallic clusters and mixed carboxylates[J]. Inorg. Chem., 2003,42:944-946. doi: 10.1021/ic025871j
32. [32]
  Bai H. Y, Yang J, Liu B, Ma J. F, Kan W. Q, Liu Y. Y, Liu Y. Y. Syntheses, structures, and photoluminescence of five silver(I) coordination polymers based on tetrakis(imidazol-1-ylmethyl)methane[J]. CrystEngCommun., 2011,13:5877-5884. doi: 10.1039/c0ce00834f
33. [33]
  Kong Z. G, Guo S. N, Yu M, Feng S. Y, Hu B. A new luminescent Cd(II) coordination polymer constructed by mixed 1,4-naphthalenedicarboxylate and N-donor chelating ligand[J]. Chin. J. Struct. Chem., 2016,35:591-596.
34. [34]
  Jin S, Gu Q. Y, Chen J, Wang Y. Z, Yuan G. Z. Crystal structures and photoluminescent properties of two Cd2+ coordination polymers constructed from an 8-hydroxyquinolinate ligand[J]. Chin. J. Struct. Chem., 2016,35929.
1. [1]
  Yukun CHEN , Kexin FENG , Bolun ZHANG , Wentao SONG , Jianjun ZHANG . Syntheses, crystal structures, and diametrically opposed mechanically-stimulated luminescence response of two Mg(Ⅱ) metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1227-1234. doi: 10.11862/CJIC.20240448
2. [2]
  Huan ZHANG , Jijiang WANG , Guang FAN , Long TANG , Erlin YUE , Chao BAI , Xiao WANG , Yuqi ZHANG . A highly stable cadmium(Ⅱ) metal-organic framework for detecting tetracycline and p-nitrophenol. Chinese Journal of Inorganic Chemistry, 2024, 40(3): 646-654. doi: 10.11862/CJIC.20230291
3. [3]
  Yanfen PENG , Xinyue WANG , Tianbao LIU , Xiaoshuo WU , Yujing WEI . Syntheses and luminescence of four Cd(Ⅱ)/Zn(Ⅱ) complexes constructed by 1,3‐bis(4H‐1,2,4‐triazole)benzene. Chinese Journal of Inorganic Chemistry, 2025, 41(7): 1416-1426. doi: 10.11862/CJIC.20250018
4. [4]
  Jie ZHANG , Xin LIU , Zhixin LI , Yuting PEI , Yuqi YANG , Huimin LI , Zhiqiang LIU . Assembling a luminescence silencing system based on post-synthetic modification strategy: A highly sensitive and selective turn-on metal-organic framework probe for ascorbic acid detection. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 823-833. doi: 10.11862/CJIC.20230310
5. [5]
  Weichen WANG , Chunhua GONG , Junyong ZHANG , Yanfeng BI , Hao XU , Jingli XIE . Construction of two metal-organic frameworks by rigid bis(triazole) and carboxylate mixed-ligands and their catalytic properties for CO₂ cycloaddition reaction. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1377-1386. doi: 10.11862/CJIC.20230415
6. [6]
  Lu LIU , Huijie WANG , Haitong WANG , Ying LI . Crystal structure of a two-dimensional Cd(Ⅱ) complex and its fluorescence recognition of p-nitrophenol, tetracycline, 2, 6-dichloro-4-nitroaniline. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1180-1188. doi: 10.11862/CJIC.20230489
7. [7]
  Meirong HAN , Xiaoyang WEI , Sisi FENG , Yuting BAI . A zinc-based metal-organic framework for fluorescence detection of trace Cu²⁺. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1603-1614. doi: 10.11862/CJIC.20240150
8. [8]
  Chao LIU , Jiang WU , Zhaolei JIN . Synthesis, crystal structures, and antibacterial activities of two zinc(Ⅱ) complexes bearing 5-phenyl-1H-pyrazole group. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 1986-1994. doi: 10.11862/CJIC.20240153
9. [9]
  Xiaoxia WANG , Ya'nan GUO , Feng SU , Chun HAN , Long SUN . Synthesis, structure, and electrocatalytic oxygen reduction reaction properties of metal antimony-based chalcogenide clusters. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1201-1208. doi: 10.11862/CJIC.20230478
10. [10]
  Ting WANG , Peipei ZHANG , Shuqin LIU , Ruihong WANG , Jianjun ZHANG . A Bi-CP-based solid-state thin-film sensor: Preparation and luminescence sensing for bioamine vapors. Chinese Journal of Inorganic Chemistry, 2024, 40(8): 1615-1621. doi: 10.11862/CJIC.20240134
11. [11]
  Haoying ZHAI , Lanzong WEN , Wenjie LIAO , Qin LI , Wenjun ZHOU , Kun CAO . Metal-organic framework-derived sulfur-doped iron-cobalt tannate nanorods for efficient oxygen evolution reaction performance. Chinese Journal of Inorganic Chemistry, 2025, 41(5): 1037-1048. doi: 10.11862/CJIC.20240320
12. [12]
  Tian TIAN , Meng ZHOU , Jiale WEI , Yize LIU , Yifan MO , Yuhan YE , Wenzhi JIA , Bin HE . Ru-doped Co₃O₄/reduced graphene oxide: Preparation and electrocatalytic oxygen evolution property. Chinese Journal of Inorganic Chemistry, 2025, 41(2): 385-394. doi: 10.11862/CJIC.20240298
13. [13]
  Ruikui YAN , Xiaoli CHEN , Miao CAI , Jing REN , Huali CUI , Hua YANG , Jijiang WANG . Design, synthesis, and fluorescence sensing performance of highly sensitive and multi-response lanthanide metal-organic frameworks. Chinese Journal of Inorganic Chemistry, 2024, 40(4): 834-848. doi: 10.11862/CJIC.20230301
14. [14]
  Yao HUANG , Yingshu WU , Zhichun BAO , Yue HUANG , Shangfeng TANG , Ruixue LIU , Yancheng LIU , Hong LIANG . Copper complexes of anthrahydrazone bearing pyridyl side chain: Synthesis, crystal structure, anticancer activity, and DNA binding. Chinese Journal of Inorganic Chemistry, 2025, 41(1): 213-224. doi: 10.11862/CJIC.20240359
15. [15]
  Jia JI , Zhaoyang GUO , Wenni LEI , Jiawei ZHENG , Haorong QIN , Jiahong YAN , Yinling HOU , Xiaoyan XIN , Wenmin WANG . Two dinuclear Gd(Ⅲ)-based complexes constructed by a multidentate diacylhydrazone ligand: Crystal structure, magnetocaloric effect, and biological activity. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 761-772. doi: 10.11862/CJIC.20240344
16. [16]
  Hongren RONG , Gexiang GAO , Zhiwei LIU , Ke ZHOU , Lixin SU , Hao HUANG , Wenlong LIU , Qi LIU . High-performance supercapacitor based on 1D cobalt-based coordination polymer. Chinese Journal of Inorganic Chemistry, 2025, 41(6): 1183-1195. doi: 10.11862/CJIC.20250034
17. [17]
  Yinling HOU , Jia JI , Hong YU , Xiaoyun BIAN , Xiaofen GUAN , Jing QIU , Shuyi REN , Ming FANG . A rhombic Dy₄-based complex showing remarkable single-molecule magnet behavior. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 605-612. doi: 10.11862/CJIC.20240251
18. [18]
  Lulu DONG , Jie LIU , Hua YANG , Yupei FU , Hongli LIU , Xiaoli CHEN , Huali CUI , Lin LIU , Jijiang WANG . Synthesis, crystal structure, and fluorescence properties of Cd-based complex with pcu topology. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 809-820. doi: 10.11862/CJIC.20240171
19. [19]
  Xiumei LI , Yanju HUANG , Bo LIU , Yaru PAN . Syntheses, crystal structures, and quantum chemistry calculation of two Ni(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2024, 40(10): 2031-2039. doi: 10.11862/CJIC.20240109
20. [20]
  Xiumei LI , Linlin LI , Bo LIU , Yaru PAN . Syntheses, crystal structures, and characterizations of two cadmium(Ⅱ) coordination polymers. Chinese Journal of Inorganic Chemistry, 2025, 41(3): 613-623. doi: 10.11862/CJIC.20240273

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(5026)
HTML views(181)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142