Citation: MIAO Shao-Bin, LI Zhao-Hao, XU Chun-Yin, JI Bao-Ming. A New 3-Fold Interpenetrating 3D Zn(II) Metal-organic Framework: Synthesis, Structure and Luminescent Property[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1960-1966. doi: 10.14102/j.cnki.0254-5861.2011-1209 shu

A New 3-Fold Interpenetrating 3D Zn(II) Metal-organic Framework: Synthesis, Structure and Luminescent Property

College of Chemistry and Chemical Engineering, Luoyang Normal University, Luoyang 471022, China

Corresponding author: JI Bao-Ming, lyhxxjbm@126.com
Received Date: 21 March 2016

Fund Project: the National Natural Science Foundation of China 21372112the Science and Technology Research Projects of Education Department of Henan Province 15A150064

Figures(5)

A new Zn(II) coordination polymer, namely {[Zn_1.5(1,3,5-btc^3-)(dtb)(H₂O)](H₂O)₂}_n (1) (1,3,5-H₃btc=1,3,5-benzenetricarboxylic acid, dtb=1,3-di-(1,2,4-triazole-4-yl)benzene), has been hydrothermally synthesized and structurally characterized. X-ray single-crystal diffraction determination reveals that 1 crystallizes in the monoclinic C2/c space group with a=33.811(12), b=8.406(2), c=17.296(4)Å, β=120.593(2)°, V=4232(2)Å³, Z=4, M_r=1142.88, D_c=1.794 Mg/m³, μ=1.783 mm^-1, F(000)=2320, the final R=0.0338 and wR=0.0827 for 3043 observed reflections with I>2σ(I). Compound 1 exhibits 1D Zn(II)-carboxylate chains, which are connected into a 3D porous framework with large channels by dtb, and then three identical 3D networks are interpenetrated with each other. In addition, the luminescence property of the complex has also been investigated.
- metal-organic framework,
- 1,3-di-(1,2,4-triazole-4-yl)benzene,
- crystal structure,
- luminescence
1. [1]
  Allendorf M. D, Bauer C. A, Bhakta R. K, Houk R. J. T. Luminescent metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1330-1352. doi: 10.1039/b802352m
2. [2]
  Kurmoo M. Magnetic metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1353-1379. doi: 10.1039/b804757j
3. [3]
  Li J. R, Kuppler R. J, Zhou H. C. Selective gas adsorption and separation in metal-organic frameworks[J]. Chem. Soc. Rev., 2009,38:1477-1504. doi: 10.1039/b802426j
4. [4]
  Janiak C. Engineering coordination polymers towards applications[J]. Dalton Trans., 2003,14:2781-2804.
5. [5]
  Kitagawa S, Kitaura R, Noro S. Functional porous coordination polymers[J]. Angew. Chem. Int. Ed., 2004,43:2334-2375. doi: 10.1002/(ISSN)1521-3773
6. [6]
  Wu C. D, Hu A. G, Zhang L, Lin W. B. A homochiral porous metal-organic framework for highly enantioselective heterogeneous asymmetric catalysis[J]. J. Am. Chem. Soc., 2005,127:8940-8941. doi: 10.1021/ja052431t
7. [7]
  Bai H. Y, Ma J. F, Yang J, Zhang L. P, Ma J. C, Liu Y. Y. Eight two-dimensional and three-dimensional metal-organic frameworks based on a flexible tetrakis(imidazole) ligand: synthesis, topological structures, and photoluminescent properties[J]. Cryst. Growth Des., 2010,10:1946-1959. doi: 10.1021/cg100032n
8. [8]
  Chang X. H, Zhao Y, Han M. L, Ma L. F, Wang L. Y. Five Cd(II) coordination polymers based on 2,3?,5,5?-biphenyltetracarboxylic acid and N-donor coligands: syntheses, structures and fluorescent properties[J]. CrystEngComm., 2014,16:6417-6425. doi: 10.1039/c4ce00355a
9. [9]
  Wu H, Liu H. Y, Liu Y. Y, Yang J, Liu B, Ma J. F. An unprecedented 2D → 3D metal-organic polyrotaxane framework constructed from cadmium and a flexible star-like ligand[J]. Chem. Commun., 2011,47:1818-1820. doi: 10.1039/C0CC04724D
10. [10]
  Wang, X. L.; Le, M.; Lin, H. Y.; Luan, J. ; Liu, G. C.; Zhang, J. W.; Tian, A. X. A 3-fold interpenetrating 3D Cu(II) coordination polymer based on a semi-rigid naphthalene-based bis-pyridyl-bis-amide and thiophene-2,5-dicarboxylate. Inorg. Chem. Commun. 2014, 49, 19-23.
11. [11]
  Chui S. S. Y, Lo S. M. F, Charmant J. P. H, Orpen A. G, Williams I. D. A chemically functionalizable nanoporous material[J]. Science, 1999,283:1148-1150. doi: 10.1126/science.283.5405.1148
12. [12]
  Liu Y. Y, Liu H. Y, Ma J. F, Yang Y, Yang J. Syntheses, structures and photoluminescent properties of Zn(II) and Cd(II) coordination polymers with flexible tripodal triazole-containing ligands[J]. CrystEngComm., 2013,15:1897-1907. doi: 10.1039/c2ce26958a
13. [13]
  Bu, F.; Xiao, S. J. A 4-connected anionic metal-organic nanotube constructed from indium isophthalate. CrystEngComm. 2010, 12, 3385-3387.
14. [14]
  Xue Y. S, Jin F. Y, Zhou L, Liu M. P, Xu Y, Du H. B, Fang M, You X. Z. Structural diversity and properties of coordination polymers built from a rigid octadentenate carboxylic acid[J]. Cryst. Growth Des., 2012,12:6158-6164. doi: 10.1021/cg301319u
15. [15]
  Rao, K. P.; Higuchi, M.; Duan, J.; Kitagawa, S. pH-Dependent interpenetrated, polymorphic, Cd2+- and BTB-based porous coordination polymers with open metal sites. Cryst. Growth Des. 2013, 13, 981-985.
16. [16]
  Sun D, Yan Z. H, Blatov V. A, Wang L, Sun D. F. Syntheses, topological structures, and photoluminescences of six new Zn(II) coordination polymers based on mixed tripodal imidazole ligand and varied polycarboxylates[J]. Cryst. Growth Des., 2013,13:1277-1289. doi: 10.1021/cg3017358
17. [17]
  Aromí G, Barrios L. A, Roubeau O, Gamez P. Triazoles and tetrazoles: prime ligands to generate remarkable coordination materials[J]. Coord. Chem. Rev., 2011,255:485-546. doi: 10.1016/j.ccr.2010.10.038
18. [18]
  Zhu A. X, Lin J. B, Zhang J. P, Chen X. M. Isomeric zinc(II) triazolate frameworks with 3-connected networks: syntheses, structures, and sorption properties[J]. Inorg. Chem., 2009,48:3882-3889. doi: 10.1021/ic802446m
19. [19]
  Ding B, Yi L, Wang Y, Cheng P, Liao D. Z, Yan S. P, Jiang Z. H, Song H. B, Wang H. G. Synthesis of a series of 4-pyridyl-1,2,4-triazolecontaining cadmium(II) luminescent complexes[J]. Dalton Trans., 2006,5:665-675.
20. [20]
  Zhang J. P, Chen X. M. Exceptional framework flexibility and sorption behavior of a multifunctional porous cuprous triazolate framework[J]. J. Am. Chem. Soc., 2008,130:6010-6017. doi: 10.1021/ja800550a
21. [21]
  Haasnoot J. G. Mononuclear, oligonuclear and polynuclear metal coordination compounds with 1,2,4-triazole derivatives as ligands[J]. Coord. Chem. Rev., 2000,200.
22. [22]
  Liu K, Shi W, Cheng P. The coordination chemistry of Zn(II), Cd(II) and Hg(II) complexes with 1,2,4-triazole derivatives[J]. Dalton Trans., 2011,40:8475-8490. doi: 10.1039/c0dt01578d
23. [23]
  Zhou X. H, Du X. D, Li G. N, Zuo J. L, You X. Z. Coordination polymers assembled from 3,5-pyrazoledicarboxylic acid and bis(triazolyl) ligands: chiral and meso-structures induced by ligand flexibility and a six-connected self-catenated network[J]. Cryst. Growth Des., 2009,9:4487-4496. doi: 10.1021/cg900509r
24. [24]
  Yang P, Wu X. X, Huo J. Z, Ding B, Wang Y, Wang X. G. Hydrothermal synthesis and characterization of a series of luminescent Zn(II) and Cd(II) coordination polymers with the new versatile multidentate ligand 1,3-di-(1,2,4-triazol-4-yl)benzene[J]. CrystEngComm., 2013,15:8097-8109. doi: 10.1039/c3ce40946e
25. [25]
  Miao S. B, Li Z. H, Ji B. M, Deng D. S, Xu C. Y, Zhou L. Synthesis, crystal structure, and properties of a 3D Cu(I) coordination polymer based on Cu3(CN)2 clusters and 1,3-di-(1,2,4-triazole-4-yl)benzene[J]. J. Clust. Sci., 2014,25:1137-1145. doi: 10.1007/s10876-014-0695-3
26. [26]
  Miao S. B, Ji B. M, Wang Y. F, Li Z. H, Deng D. S, Xu C. Y, Zhou L. A new 3D pillared-layer porous framework with intersecting open channels in the Co/triazolate/carboxylate system: synthesis, structure and magnetism[J]. Inorg. Chem. Commun., 2015,62:47-50. doi: 10.1016/j.inoche.2015.10.024
27. [27]
  Qin X, Fan Z, Xu Y. Y, Ding B, Wang Y, Wang X. G. Two novel 3D porous copper(II) and zinc(II) frameworks with 1,3-di-(1,2,4-triazole- 4-yl)benzene: 4-connected dmp network versus 6-connnected α-Po network based on trinuclear zinc(II) clusters[J]. Inorg. Chem. Commun., 2013,37:166-169. doi: 10.1016/j.inoche.2013.09.032
28. [28]
  Sheldrick, G. M. SHELXS-97. Program for the Solution of Crystal Structures. University of G?ttingen: Germany 1997.
29. [29]
  Sheldrick, G. M. SHELXL-97. Program for the Refinement of Crystal Structures. University of G?ttingen: Germany 1997.
30. [30]
  Yang, L.; Powell, D. R.; Houser, R. P. Structural variation in copper(I) complexes with pyridylmethylamide ligands: structural analysis with a new four-coordinate geometry index, τ4. Dalton Trans. 2007, 9, 955-964.
31. [31]
  Chen W, Wang J. Y, Chen C, Yue Q, Yuan H. M, Chen J. S, Wang S. N. Photoluminescent metal-organic polymer constructed from trimetallic clusters and mixed carboxylates[J]. Inorg. Chem., 2003,42:944-946. doi: 10.1021/ic025871j
32. [32]
  Bai H. Y, Yang J, Liu B, Ma J. F, Kan W. Q, Liu Y. Y, Liu Y. Y. Syntheses, structures, and photoluminescence of five silver(I) coordination polymers based on tetrakis(imidazol-1-ylmethyl)methane[J]. CrystEngCommun., 2011,13:5877-5884. doi: 10.1039/c0ce00834f
33. [33]
  Kong Z. G, Guo S. N, Yu M, Feng S. Y, Hu B. A new luminescent Cd(II) coordination polymer constructed by mixed 1,4-naphthalenedicarboxylate and N-donor chelating ligand[J]. Chin. J. Struct. Chem., 2016,35:591-596.
34. [34]
  Jin S, Gu Q. Y, Chen J, Wang Y. Z, Yuan G. Z. Crystal structures and photoluminescent properties of two Cd2+ coordination polymers constructed from an 8-hydroxyquinolinate ligand[J]. Chin. J. Struct. Chem., 2016,35929.
1. [1]
  HU Biao , YU Di , HUANG Kai , YU Shu-Juan . Metal-ion Interactions with Sugars: Crystal Structure of Bis(4-dehydro-L-arabinose) Calcium Methanol Bishydrate. Chinese Journal of Structural Chemistry, 2015, 34(5): 764-770. doi: 10.14102/j.cnki.0254-5861.2011-0517
2. [2]
  SUN Jie , WANG Ai-Yun , LI Qing , ZHOU Ju-Hua . Synthesis, Structure and Luminescence of a ZnII Complex Derived from 1,2-Benzenedicarboxylic Acid Ligand. Chinese Journal of Structural Chemistry, 2016, 34(10): 1533-1538. doi: 10.14102/j.cnki.0254-5861.2011-0761
3. [3]
  XU Jun , MA De-Yun , QIN Liang . A New 2D Barium-organic Framework Built from 1H-Benzimidazole-5,6-dicarboxylate with Luminescent and Antibacterial Studies. Chinese Journal of Structural Chemistry, 2014, 33(3): 387-394.
4. [4]
  ZHU Xiao-Fei , WANG Ning , XIE Xiao-Yan , HOU Rui-Bin , ZHOU De-Feng , LI Ya-Feng , HU Jun , LI Xin-Yuan , LIU He , NIE Wang . A New 3D Metal-organic Framework with Tetranuclear Cadmium(Ⅱ) Clusters:Synthesis, Structure, and Luminescent Property. Chinese Journal of Structural Chemistry, 2014, 33(2): 277-283.
5. [5]
  WANG Xiu-Yan , LIU Fu-Yi , ZHANG Yan-Na , XU Zhan-Lin . Synthesis, Crystal Structure and Photoluminescence of a New Zn(Ⅱ) Dimer Constructed by 1,10-Phenanthroline Derivative and Flexible Dicarboxylate. Chinese Journal of Structural Chemistry, 2014, 33(1): 33-36.
6. [6]
  XU Bo , LI Ling , LI Jie , LI Cun-Cheng . Crystal Structure and Luminescent Property of a Coordination Complex Constructed with Pyrazine and 1,4-Phenylenediacetic Acid. Chinese Journal of Structural Chemistry, 2014, 33(12): 1826-1830. doi: 10.14102/j.cnki.0254-5861.2011-0378
7. [7]
  ZHANG Xu , GE Ming , HECKE Kristof Van , CUI Guang-Hua . Synthesis, Crystal Structure and Catalytic Properties of a 2D Cobalt(Ⅱ) Coordination Polymer Based on Mixed Ligands. Chinese Journal of Structural Chemistry, 2015, 34(4): 599-605. doi: 10.14102/j.cnki.0254-5861.2011-0542
8. [8]
  WANG Peng-Fei , TAO Xiao-Lin , WANG Jin-Ling , WU Guo-Zhi , WANG Xin . A New 2D Layered Barium Coordination Polymer [Ba(3-NPA)]_n: Synthesis, Crystal Structure, Thermal Stability and Luminescent Properties. Chinese Journal of Structural Chemistry, 2014, 33(3): 339-344.
9. [9]
  LEI Xiao-Wu , YUE Cheng-Yang , ZHANG Hui-Ping , ZHAI Xiu-Rong , FENG Li-Juan . Synthesis, Crystal Structure and Luminescent Properties of One New Ag(I) Complex Based on 3-Aminopyrazine-2-carboxylic Acid. Chinese Journal of Structural Chemistry, 2014, 33(4): 635-641.
10. [10]
  SU Wen-Yi , LI Guo-Bi , PAN Rong-Kai , TANG Fei-Qiong , ZHONG Ling , LIU Sheng-Gui . Synthesis, Crystal Structure and Luminescent Property of Cadmium Complex Based on 2-(2-(1Hbenzo[d]imidazol-2-yl)benzyl)-1H-benzo[d]-imidazole. Chinese Journal of Structural Chemistry, 2014, 33(6): 909-914.
11. [11]
  WU Qi-Ting , WU Li-Bin , LI Guo-Bi , LIU Sheng-Gui , PAN Rong-Kai , SU Wen-Yi , HUANG Qian-Wen . Synthesis, Crystal Structure and Luminescent Property of a Dinuclear Cadmium Complex Based on 1,2,3,4-Tetra(1H-benzo[d]imidazol-2-yl)butane. Chinese Journal of Structural Chemistry, 2015, 34(2): 260-266. doi: 10.14102/j.cnki.0254-5861.2011-0464
12. [12]
  LI Shu-Jing , LI Ke , QU Bo-Tao , ZHENG Wei . Synthesis, Crystal Structure and Properties of a New Zn(Ⅱ) Coordination Polymer Constructed from 2,3-Pyridine Dicarboxylic Acid and 1,1'-(1,4-Butanediyl)bis(imidazole). Chinese Journal of Structural Chemistry, 2014, 33(2): 193-198.
13. [13]
  GONG Ya-Qiong , MI Tao-Qing , JIANG Fei-Long . Synthesis, Crystal Structure and Photoluminescence of a Zn(Ⅱ) Coordination Polymer Derived from 1,1'-Biphenyl-2,2',6,6'-tetracarboxylic Acid. Chinese Journal of Structural Chemistry, 2015, 34(7): 1087-1091. doi: 10.14102/j.cnki.0254-5861.2011-0587
14. [14]
  GUO Feng . A Novel 6-Connected Self-interpenetrated Zn(II) Coordination Polymer Based on 1,4-Bis(2-methylimidazole-3-ium-1-yl)biphenyl and Dicarboxylate Ligand: Synthesis, Crystal Structure and Luminescent Property. Chinese Journal of Structural Chemistry, 2016, 34(10): 1579-1584. doi: 10.14102/j.cnki.0254-5861.2011-0697
15. [15]
  ZHANG Fang-Wei , ZHOU Yan-Fang , DONG Jin-Qiao , LIU Bai-Zhan , ZHENG Sai-Jing , CUI Yong . Synthesis and Crystal Structure of a Novel Chiral 3D Metal-organic Framework Based on an N-methyl Substituted Salan Ligand. Chinese Journal of Structural Chemistry, 2014, 33(8): 1154-1158.
16. [16]
  XUE Li-Ping , SHAN Li-Li , FENG Wen-Jing . Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology. Chinese Journal of Structural Chemistry, 2016, 35(2): 293-297. doi: 10.14102/j.cnki.0254-5861.2011-0845
17. [17]
  KONG Zhi-Guo , WANG Wei , ZHANG Bing . Synthesis, Crystal Structure and Luminescence of a New Two-dimensional Pb(II) Coordination Polymer. Chinese Journal of Structural Chemistry, 2016, 34(10): 1503-1507. doi: 10.14102/j.cnki.0254-5861.2011-0715
18. [18]
  XUE Li-Ping , SHAN Li-Li , FENG Wen-Jing . Synthesis, Crystal Structure and Luminescence of a Cadmium(II) Coordination Polymer with 3,6-Connected rtl Topology. Chinese Journal of Structural Chemistry, 2016, 35(2): 293-297. doi: 10.14102/j.cnki.0254-5861.2011-0845
19. [19]
  ZOU Shu-Zhi , DU Shao-Wu . Syntheses, Structures and Luminescent Properties of Two Europium-based Metal-organic Frameworks. Chinese Journal of Structural Chemistry, 2015, 34(8): 1265-1272. doi: 10.14102/j.cnki.0254-5861.2011-0650
20. [20]
  LI Wen-Bin , GAO Zhu-Qing , GU Jin-Zhong . Synthesis, Crystal Structure, and Magnetic Properties of a Co Metal-organic Framework with Mixed Dicarboxylate and Tricarboxylate Ligands. Chinese Journal of Structural Chemistry, 2016, 35(2): 257-263. doi: 10.14102/j.cnki.0254-5861.2011-0929

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(2907)
HTML views(46)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142