Citation: ZHANG Dan, LI Guang-Hua, WANG Yu-Shi, YUAN Hong-Ming. KCdBP₂O₇(OH)₂: a New Cadmium Borophosphate with a 2D Layer Framework[J]. Chinese Journal of Structural Chemistry, ;2016, 35(11): 1700-1707. doi: 10.14102/j.cnki.0254-5861.2011-1197 shu

KCdBP₂O₇(OH)₂: a New Cadmium Borophosphate with a 2D Layer Framework

1.
a State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;
2.
b The First Hospital of Jilin University, Jilin University, Changchun 130012, China

Corresponding author: WANG Yu-Shi, YUAN Hong-Ming,
Received Date: 15 March 2016
Available Online: 21 September 2016
Fund Project:

A new cadmium borophosphate, KCdBP₂O₇(OH)₂, was synthesized by using boric acid flux method. The crystal structure was determined by single-crystal X-ray diffraction analysis (monoclinic, space group P2₁/c, a=12.103(2), b=8.8737(18), c=7.1266(14) Å, β=101.69(3)°, V=749.5(3) Å³ and Z=4). The framework of KCdBP₂O₇(OH)₂ is constructed from the connection of infinite [CdO₆] octahedral chains and open-branched chains[(BP₂Φ₉)₂]_n (Φ=O, OH), giving rise to a 2D layered structure viewed along the [100] direction. The K⁺ ionic conductivity measured for KCdBP₂O₇(OH)₂ was 3.47×1-^-8 S·cm^-1 at 583 K.
- cadmium,
- borophosphate,
- chain,
- layer
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