Citation: JIAO Zhi-Wei, DUAN Cui-Cui, CAO Lei-Ganga, CUI Yan, LIU Feng-Bin, WANG Hai-Jun. Synthesis, Structure Characterization and Thermal Analysis of a New Cadmium Zinc Borate in the Pseudo-binary System Cd₃B₂O₆-Zn₃B₂O₆[J]. Chinese Journal of Structural Chemistry, ;2016, 35(11): 1679-1685. doi: 10.14102/j.cnki.0254-5861.2011-1189 shu

Synthesis, Structure Characterization and Thermal Analysis of a New Cadmium Zinc Borate in the Pseudo-binary System Cd₃B₂O₆-Zn₃B₂O₆

1.
a College of Mechanical Engineering and Materials Science, North China University of Technology, Beijing 100144, China;
2.
b Gansu Research Institute of Chemical Industry, Lanzhou 730020, China

Received Date: 8 March 2016
Available Online: 20 June 2016
Fund Project: This work was supported by the Special Foundation for Young Scientists of Beijing (No. 2014000020124G009) (No. 2014000020124G009)

Cd-rich portion of the pseudo-binary system Cd₃B₂O₆-Zn₃B₂O₆ was investigated. A new cadmium zinc borate, Cd_2.42Zn_0.58B₂O₆, was synthesized successfully by a traditional solid-state reaction method. The compound crystallizes in the monoclinic space group C2/c with a=17.3048, b=8.4356, c=10.2962 Å, β=93.157°, V=1500.7(2) Å³, D_c=5.683 g/cm³, F(000)=2301, Z=24, R=0.0351 and wR=0.0741. In its structure, BO₃ triangle, CdO₆ and CdO₅ (or ZnO₅) polyhedra are joined together by sharing bridging O atoms to form an intricate three-dimensional framework. A comparison of the structures of Cd_2.42Zn_0.58B₂O₆, α-Cd₃B₂O₆ and β-Cd₃B₂O₆ is presented. The IR spectrum confirms the presence of BO₃ unit. The UV cut-off wavelength of Cd_2.42Zn_0.58B₂O₆ is 313 nm. The differential thermal analysis (DTA) suggests that Cd_2.42Zn_0.58B₂O₆ is an incongruent melting compound.
- borate,
- crystal structure,
- IR,
- DTA
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