Citation: LI Shao-Dong, LU Li-Ping, SU Feng. A Novel Three-dimensional Mn(II) Coordination Polymer Constructed from Biphenyl-3,3',5,5'-tetracarboxylic Acid and Water[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1920-1928. doi: 10.14102/j.cnki.0254-5861.2011-1180 shu

A Novel Three-dimensional Mn(II) Coordination Polymer Constructed from Biphenyl-3,3',5,5'-tetracarboxylic Acid and Water

Institute of Molecular Science, Shanxi University, Taiyuan 030006, China

Corresponding author: LU Li-Ping, luliping@sxu.edu.cn
Received Date: 29 February 2016
Accepted Date: 13 May 2016

Fund Project: the National Natural Science Foundation of China 21571118

Figures(7)

The title Mn(II) coordination polymer, poly{[heptaaqua-(μ₄-bi-phenyl-3,3',5,5'-tetracarboxylate)-bimanganese(II)] pentahydrate},[Mn₂(bpta)(H₂O)₇]_n·5nH₂O (I), is crystallized from a mixture of biphenyl-3,3',5,5'-tetracarboxylic acid (H₄bpta) and MnCl₂·4H₂O in waterethanol under room temperature. Its asymmetric unit consists of one and two halves of crystallographically independent Mn(II) cations, one fully deprotonated H₄bpta ligand, seven coordinated water molecules and five solvent water as guest molecules. In I, each Mn(II) atom is octahedrally coordinated by six oxygen atoms from bpta^4- anions and coordinated water molecules. In the Mn(II) cations, one half Mn(II) ion of them located at a 2-fold axis generating a trinuclear[Mn₃(H₂O)₂(RCOO)₂] linker by μ_1,1-O(water) and μ_1,3-O,O'(carboxylate) bridges and another half Mn(II) ion with an inversion is a mononuclear linker. These neighbouring trinuclear and mononuclear Mn(II) cations are linked together by biphenyl-3,3',5,5'-tetracarboxylates to form a three-dimensional framework with a (4².8⁴) topology of a (4,4)-connected net, in which the positions of the trinuclear[Mn₃(H₂O)₂(R-COO)₂] linker as a 4-connector linking four bpta^4- ligands in I reproduce an eagle-shaped arrangement. The polymeric structure exhibits a water channel with an accessible void of 797.1Å³, amounting to 15.7% of the total unit-cell volume. Each of the cavities in the network is occupied by solvent water molecules.
- Mn(II) coordination polymer,
- water cluster,
- biphenyl-3,3',5,5'-tetracarboxylic acid,
- D₂h symmetric carboxylate ligand,
- topological structure
1. [1]
  Wu H, Yang J, Su Z. M, Batten S. R, Ma J. F. An exceptional 54-fold interpenetrated coordination polymer with 103-srs network topology[J]. J. Am. Chem. Soc., 2011,133:11406-11409. doi: 10.1021/ja202303b
2. [2]
  Gandara F, Furukawa H, Lee S, Yaghi O. M. High methane storage capacity in aluminum metal-organic frameworks[J]. J. Am. Chem. Soc., 2014,136:5271-5274. doi: 10.1021/ja501606h
3. [3]
  Su F, Lu L. P, Feng S. S, Zhu M. L, Gao Z, Dong Y. Synthesis, structures and magnetic properties in 3d-electron-rich isostructural complexes based on chains with sole syn-anti carboxylate bridges[J]. Dalton. Trans., 2015,44:7213-7222. doi: 10.1039/C5DT00412H
4. [4]
  Han Z. B, Xiao Z. Z, Hao M, Yuan D. Q, Liu L, Wei N, Yao H. M, Zhou M. Functional hydrogen-bonded supramolecular framework for K+ ion sensing[J]. Cryst. Growth. Des., 2015,15:531-533. doi: 10.1021/cg501259g
5. [5]
  Horcajada P, Gref R, Baati T, Allan P. K, Maurin G, Couvreur P, Ferey G, Morris R. E, Serre C. Metal-organic frameworks in biomedicine[J]. Chem. Rev., 2012,112:1232-1268. doi: 10.1021/cr200256v
6. [6]
  Li H. N, Li H. Y, Li L. K, Xu L, Hou K, Zang S. Q, Mak T. C. W. Syntheses, structures, and photoluminescent properties of lanthanide coordination polymers based on a zwitterionic aromatic polycarboxylate ligand[J]. Cryst. Growth. Des., 2015,15:4331-4340. doi: 10.1021/acs.cgd.5b00625
7. [7]
  Genna D. T, Wong-Foy A G, Matzger A. J, Sanford M. S. Heterogenization of homogeneous catalysts in metal-organic frameworks via cation exchange[J]. J. Am. Chem. Soc., 2013,135:10586-10589. doi: 10.1021/ja402577s
8. [8]
  Wang Y, Lei Y, Chi S, Luo Y. Rare earth metal bis(silylamide) complexes bearing pyridyl-functionalized indenyl ligand: synthesis, structure and performance in the living polymerization of L-lactide and rac-lactide[J]. Dalton. Trans., 2013,42:1862-1871. doi: 10.1039/C2DT32083E
9. [9]
  Yang, J. X.; Zhang, X.; Cheng, J. K.; Zhang, J.; Yao, Y. G. pH influence on the structural variations of 4,4′-oxydiphthalate coordination polymers. Cryst. Growth. Des. 2012, 12, 333-345.
10. [10]
  Zhang J, Wojtas L, Larsen R. W, Eddaoudi M, Zaworotko M. J. Temperature and concentration control over interpenetration in a metal-organic material[J]. J. Am. Chem. Soc., 2009,131:17040-17041. doi: 10.1021/ja906911q
11. [11]
  Guo Z, Wu H, Srinivas G, Zhou Y, Xiang S, Chen Z, Yang Y, Zhou W, O?Keeffe M, Chen B. A metal-organic framework with optimized open metal sites and pore spaces for high methane storage at room temperature[J]. Angew. Chem. Int. Ed. Engl., 2011,50:3178-3181. doi: 10.1002/anie.201007583
12. [12]
  Wang R, Meng Q, Zhang L, Wang H, Dai F, Guo W, Zhao L, Sun D. Investigation of the effect of pore size on gas uptake in two metal-organic frameworks[J]. Chem. Commun., 2014,50:4911-4914. doi: 10.1039/c4cc00477a
13. [13]
  Lin X, Jia J, Zhao X, Thomas K. M, Blake A. J, Walker G. S, Champness N. R, Hubberstey P, Schroder M. High H2 adsorption by coordination-framework materials[J]. Angew. Chem. Int. Ed. Engl., 2006,45:7358-7364. doi: 10.1002/(ISSN)1521-3773
14. [14]
  Su F, Lu L. P, Zhu M. L, Feng S. S. One pot synthesis, structure and magnetic property of a pseudo-interpenetrated 2D copper framework based on coordinated 1,1?-biphenyl-3,3?,5,5?-tetracarboxylate and synthon[J]. J. Mol. Struct., 2016.
15. [15]
  Zhao H, Dong Y, Liu H. Two new luminescent Zn(II) compounds constructed from guanazole and aromatic polycarboxylate ligands[J]. J. Mol. Struct., 2016.
16. [16]
  Krap, C. P.; Newby, R.; Dhakshinamoorthy, A.; Garcia, H.; Cebula, I.; Easun, T. L.; Savage, M.; Eyley, J. E.; Gao, S.; Blake, A. J.; Lewis, W.; Beton, P. H.; Warren, M. R.; Allan, D. R.; Frogley, M. D.; Tang, C. C.; Cinque, G.; Yang, S.; Schroder, M. Enhancement of CO2 adsorption and catalytic properties by Fe-doping of [Ga2(OH)2(L)] (H4L = biphenyl-3,3?,5,5?-tetracarboxylic acid), MFM-300(Ga2). Inorg. Chem. 2016, 55, 1076-88.
17. [17]
  Bruker. APEX2 and SAINT. Bruker AXS Inc., Madison, Wisconsin, USA 2008.
18. [18]
  Sheldrick G. M. A short history of SHELX. Acta Crystallogr[J]. Sect. A, 2015,74:3-8.
19. [19]
  Brandenburg, K. DIAMOND: Crystal and Molecular Structure Visualization, Version 3.1b, Crystal Impact GbR,Bonn, Germany 2006.
20. [20]
  Mercury 2.3 Supplied with Cambridge Structural Database, CCDC, Cambridge, U.K 2003-2004.
21. [21]
  Spek A. L. Structure validation in chemical crystallography[J]. Acta Cryst., 2009,65:148-155.
22. [22]
  Mascal, M.; Infantes L.; Chisholm J. Water oligomers in crystal hydrates-what?s news and what isn?t? Angew. Chem. Int. Ed. Engl. 2005, 45, 32-36.
23. [23]
  Blatov, V. A. IUCr Comput. Commission. Newsl. 2006, 7, 4-38.
24. [24]
  Allen F. H. The Cambridge structural database: a quarter of a million crystal structures and rising[J]. Acta Cryst. B, 2002,58:380-388. doi: 10.1107/S0108768102003890
25. [25]
  Meng Q, Dai F, Zhang L, Wang R, Sun D. Synthesis, structure, and magnetism of three manganese-organic framework with PtS topology[J]. Sci. China. Chem., 2014,57:1507-1513. doi: 10.1007/s11426-014-5153-4
26. [26]
  Zhang X, Fan L, Sun Z, Zhang W, Li D, Dou J, Han L. Syntheses, structures, and properties of a series of multidimensional metal-organic polymers based on 3,3′,5,5′-biphenyltetracarboxylic acid and N-donor ancillary ligands[J]. Cryst. Growth. Des., 2013,13:792-803. doi: 10.1021/cg301502u
27. [27]
  Ghosh S. K, Bharadwaj P. K. Coexistence of water dimer; hexamer clusters in 3D metal-organic framework structures of Ce(III) and Pr(III) with pyridine-2,6-dicarboxylic acid[J]. Inorg. Chem., 2003,42:8250-8254. doi: 10.1021/ic034976z
28. [28]
  Turner D. R, Hursthouse M. B, Light M. E, Steed J. W. Linear distortion of octahedral metal centres by multiple hydrogen bonds in modular ML4 systems[J]. Chem. Comun., 2004,1354.
29. [29]
  Li H. N, Li H. Y, Li L. K, Xu L, Hou K, Zang S. Q, Mak T. C. W. Role of solvents in coordination supramolecular systems[J]. Chem. Commun., 2011,47:5958-5972. doi: 10.1039/c1cc10935a
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