Citation: LI Shao-Dong, LU Li-Ping, SU Feng. A Novel Three-dimensional Mn(II) Coordination Polymer Constructed from Biphenyl-3,3',5,5'-tetracarboxylic Acid and Water[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1920-1928. doi: 10.14102/j.cnki.0254-5861.2011-1180 shu

A Novel Three-dimensional Mn(II) Coordination Polymer Constructed from Biphenyl-3,3',5,5'-tetracarboxylic Acid and Water

Institute of Molecular Science, Shanxi University, Taiyuan 030006, China

Corresponding author: LU Li-Ping, luliping@sxu.edu.cn
Received Date: 29 February 2016

Fund Project: the National Natural Science Foundation of China 21571118

Figures(7)

The title Mn(II) coordination polymer, poly{[heptaaqua-(μ₄-bi-phenyl-3,3',5,5'-tetracarboxylate)-bimanganese(II)] pentahydrate},[Mn₂(bpta)(H₂O)₇]_n·5nH₂O (I), is crystallized from a mixture of biphenyl-3,3',5,5'-tetracarboxylic acid (H₄bpta) and MnCl₂·4H₂O in waterethanol under room temperature. Its asymmetric unit consists of one and two halves of crystallographically independent Mn(II) cations, one fully deprotonated H₄bpta ligand, seven coordinated water molecules and five solvent water as guest molecules. In I, each Mn(II) atom is octahedrally coordinated by six oxygen atoms from bpta^4- anions and coordinated water molecules. In the Mn(II) cations, one half Mn(II) ion of them located at a 2-fold axis generating a trinuclear[Mn₃(H₂O)₂(RCOO)₂] linker by μ_1,1-O(water) and μ_1,3-O,O'(carboxylate) bridges and another half Mn(II) ion with an inversion is a mononuclear linker. These neighbouring trinuclear and mononuclear Mn(II) cations are linked together by biphenyl-3,3',5,5'-tetracarboxylates to form a three-dimensional framework with a (4².8⁴) topology of a (4,4)-connected net, in which the positions of the trinuclear[Mn₃(H₂O)₂(R-COO)₂] linker as a 4-connector linking four bpta^4- ligands in I reproduce an eagle-shaped arrangement. The polymeric structure exhibits a water channel with an accessible void of 797.1Å³, amounting to 15.7% of the total unit-cell volume. Each of the cavities in the network is occupied by solvent water molecules.
- Mn(II) coordination polymer,
- water cluster,
- biphenyl-3,3',5,5'-tetracarboxylic acid,
- D₂h symmetric carboxylate ligand,
- topological structure
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