Citation: WANG Hao, HOU Xiang-Yang, WANG Xiao, FU Feng. Structural Diversity and Luminescent Properties of Metal-organic Frameworks Based on a Rare Sulfonate and Imidazole Co-Ligand System[J]. Chinese Journal of Structural Chemistry, ;2016, 35(9): 1427-1437. doi: 10.14102/j.cnki.0254-5861.2011-1177 shu

Structural Diversity and Luminescent Properties of Metal-organic Frameworks Based on a Rare Sulfonate and Imidazole Co-Ligand System

1.
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an 716000, China

Received Date: 25 February 2016
Available Online: 4 May 2016
Fund Project: This work was supported by the National Natural Science Foundation of China (21503183) (21503183)Yanan university field scientific research projects (YDBK2015-02) (YDBK2015-02)

Four types of luminescent properties of metal-organic frameworks(MOFs) with formulas[Cd(1,2-BIYB)₂(H₂O)₂]_n·n(AQ-1,5-DAD)(1),[Cd(AQ-1,5-DAD)(1,3-BIYB)₂]_n(2),[Cd(1,3-BIYB)]_n·n(AQ-1,5-DAD)·n H₂O(3), and [Zn(1,4-BIYB)₂]_n·n(AQ-1,5-DAD)₂·6H₂O(4),(Na₂AQ-1,5-DAD=anthraquinone-1,5-disulfonic acid disodium, 1,2-BIYB=1,2-bis(imidazol-1-ylmethyl) benzene, 1,3-BIYB=1,3-bis(imidazol-1-ylmethyl) benzene, 1,4-BIYB=1,4-bis(imidazol-1-ylmethyl)benzene) have been synthesized based on a rare sulfonate and imidazole Co-ligand system under different conditions. The structural features of four types of MOFs 1~4 are as follows:MOFs 1 show a 3D supramolecular compound in which the double one-dimensional chains are further cross-linked by hydrogen bonds. 2 exhibits a 2D network constructed by two different 1D chains. 3 features a 2D supramolecular network, in which the 1D chains and AQ-1,5-DAD are arranged alternately through hydrogen bonds. 4 posseses a 3D supramolecular structure constructed by a 2D network and one-dimensional hydrogen bonding chains. All compounds 1~4 are characterized by elemental analysis, infrared spectroscopy, and thermogravimetric analysis. The luminescence properties of 1~4 have been investigated.
- sulfonate-imidazole system,
- structural diversity,
- luminescent properties
1. [1]
  REN Yi-Xia , AN Miao , GAO Lou-Jun , CHAI Hong-Mei , HOU Xiang-Yang , ZHOU Gui-Jiang . Structural Diversity and Photoluminescent Properties of Two Mn(II) Sulfoterephthalate Complexes from Multi-pyridine N-containing Ligands. Chinese Journal of Structural Chemistry, 2016, 35(4): 550-558. doi: 10.14102/j.cnki.0254-5861.2011-0874
2. [2]
  ZHANG Mei-Li , GAO Na , GAO Lou-Jun . A Cd(II) Coordination Polymer with cds Topology Constructed by Polycarboxylate and Imidazole-containing Ligand. Chinese Journal of Structural Chemistry, 2016, 35(1): 143-149. doi: 10.14102/j.cnki.0254-5861.2011-0795
3. [3]
  GAO Zhu-Qing , LI Hong-Jin , GU Jin-Zhong . Syntheses, Crystal Structures and Luminescent and Magnetic Properties of Cerium(Ⅲ) and Zinc(Ⅱ) Coordination Compounds Constructed from 3,5-Dibromobenzoic Acid. Chinese Journal of Structural Chemistry, 2015, 34(2): 227-234. doi: 10.14102/j.cnki.0254-5861.2011-0455
4. [4]
  WANG Jun-Jie , ZHANG Ren-Chun , ZHANG Dao-Jun , CHANG Ze , ZHANG Ying-Hui . A Two-dimensional Anthracene-9,10-dicarboxylate Zinc(Ⅱ) Coordination Polymer Based on Binuclear [Zn₂Cl₂] Nodes: Synthesis, Characterization and Luminescent Properties. Chinese Journal of Structural Chemistry, 2014, 33(5): 695-700.
5. [5]
  WANG Ji-Wu , WANG Hai-Bing , WANG Zi , TANG Ping , WU Ya-Pan . A Novel 3D Cd(Ⅱ) Coordination Polymer with an Unusual 3-Connected (8²·10) Lig Net: Synthesis, Crystal Structure and Luminescent Properties. Chinese Journal of Structural Chemistry, 2014, 33(12): 1843-1848. doi: 10.14102/j.cnki.0254-5861.2011-0417
6. [6]
  SU Qing , ZHAO Tian-Qi , ZHANG Jie , LI Pei , ZHAO Qing , YE Ling . 6,8-Di-tert-butyl-3-(2,4-dimethyl-quinolin-7-yl)-3,4-dihydro-2H-benzo[e] [1,3]oxazine:Synthesis, Crystal Structure and Luminescent Properties. Chinese Journal of Structural Chemistry, 2014, 33(2): 237-243.
7. [7]
  QIN Xiao-Huan , ZOU Hua-Hong , GUI Liu-Cheng , LIAO Yong-Zhi , LI Hai-Ye , HUANG Fu-Ping . Crystal Structure and Luminescent Properties of a Zn(Ⅱ) Coordination Polymer Assembled by Mixed-ligand. Chinese Journal of Structural Chemistry, 2014, 33(9): 1293-1299.
8. [8]
  LI Fu-An , YANG Wei-Chun , MIAO Xu , LI Song-Tian . Hydrothermal Synthesis, Crystal Structure and Properties of a Novel 3D Metal-organic Coordination Polymer with Helical Chains Based on 5-(Imidazol-1-ylmethyl)isophthalic Acid. Chinese Journal of Structural Chemistry, 2016, 35(3): 421-427. doi: 10.14102/j.cnki.0254-5861.2011-0878
9. [9]
  GAO Zhu-Qing , LI Hong-Jin , M. Kirillov Alexander , GU Jin-Zhong . Syntheses, Crystal Structures and Luminescent Properties of Lead(Ⅱ) and Cadmium(Ⅱ) Coordination Polymers Constructed from Biphenyl-2,5,3'-tricarboxylate. Chinese Journal of Structural Chemistry, 2014, 33(6): 888-896.
10. [10]
  ZHAI Li-Jun , ZHANG Jie , GAO Ling-Ling , GAO Ting , JIA Jiao-Jiao , NIU Yu-Lan , HU Tuo-Ping . Two Coordination Polymers Constructed by Aromatic Tetracarboxylic Acid: Luminescent and Magnetic Properties. Chinese Journal of Inorganic Chemistry, 2020, 36(1): 173-182. doi: 10.11862/CJIC.2019.257
11. [11]
  CHEN Jin-Wei , LI Yu , ZOU Xun-Zhong , QIU Wen-Da , CHENG Xiao-Ling . Syntheses, Crystal Structures, Luminescent and Magnetic Properties of Nickel(Ⅱ) and Zinc(Ⅱ) Coordination Polymers Constructed from 5-Chloronicotinic Acid. Chinese Journal of Inorganic Chemistry, 2019, 35(3): 505-514. doi: 10.11862/CJIC.2019.048
12. [12]
  LI Yu , CHEN Yong-Xuan , ZHAO Na , FENG An-Sheng , ZOU Xun-Zhong . Syntheses, Crystal Structures, Luminescent and Magnetic Properties of Two 1D Cadmium(Ⅱ) and Nickel(Ⅱ) Coordination Polymers. Chinese Journal of Inorganic Chemistry, 2020, 36(1): 192-206. doi: 10.11862/CJIC.2020.017
13. [13]
  GAO Xiang , XU Wei , WU Chang-Li , ZHU Xi-Miao , OU Yong-Cong , WU Jian-Zhong . Syntheses, Crystal Structures and Luminescent Properties of Dinuclear d¹⁰ Complexes Based on a Ligand Formed in Situ by 8-Hydroxyquinoline. Chinese Journal of Inorganic Chemistry, 2018, 34(9): 1768-1774. doi: 10.11862/CJIC.2018.213
14. [14]
  LI Yu , ZOU Xun-Zhong , QIU Wen-Da , ZHUANG Wen-Liu , ZHAO Na , CHENG Xiao-Ling . Syntheses, Crystal Structures, and Luminescent Properties of Three Cobalt(Ⅱ), Lead(Ⅱ) and Zinc(Ⅱ) Complexes Constructed from Mixed Biphenyl Tricarboxylic Acid and N-Donor Ligands. Chinese Journal of Inorganic Chemistry, 2019, 35(2): 329-336. doi: 10.11862/CJIC.2019.002
15. [15]
  WANG Fei , TIAN Yi-Guang , ZHANG Qiao . Synthesis, Crystal Structure and luminescent Properties of Sr_0.955Al_2-xB_xSi₂O₈: 0.025Eu²⁺ Phosphors. Chinese Journal of Inorganic Chemistry, 2019, 35(6): 1085-1092. doi: 10.11862/CJIC.2019.126
16. [16]
  LI Yu , ZHAO Zhen-Yu , ZOU Xun-Zhong , FENG An-Sheng , GU Jin-Zhong . Syntheses, Crystal Structures, Luminescent and Magnetic Properties of 2D Manganese(Ⅱ) and Zinc(Ⅱ) Coordination Polymers Based on an Ether-Bridged Tetracarboxylic Acid. Chinese Journal of Inorganic Chemistry, 2020, 36(2): 377-384. doi: 10.11862/CJIC.2020.042
17. [17]
  LI Yu , PAN Guang-Min , ZOU Xun-Zhong , FENG An-Sheng , YOU Ao , QIU Wen-Da . Syntheses, Crystal Structures, Luminescent and Magnetic Properties of One 0D Zinc(Ⅱ) and Two 1D Manganese(Ⅱ) Coordination Compounds Assembled from Pyridine-Tricarboxylate Blocks. Chinese Journal of Inorganic Chemistry, 2019, 35(10): 1853-1860. doi: 10.11862/CJIC.2019.206
18. [18]
  LI Yu , ZOU Xun-Zhong , ZHUANG Wen-Liu , QIU Wen-Da , GU Jin-Zhong . Syntheses, Crystal Structures and Luminescent Properties of Two Zinc(Ⅱ) Coordination Polymers Constructed from Ether-Bridged Tricarboxylic Acid. Chinese Journal of Inorganic Chemistry, 2019, 35(1): 149-154. doi: 10.11862/CJIC.2019.009
19. [19]
  LI Yu-Ling , ZHAO Yue , SUN Wei-Yin . Two Zn(Ⅱ) and Cd(Ⅱ) Metal-Organic Frameworks with Mixed Ligands: Synthesis, Structure, Sorption and Luminescent Properties. Chinese Journal of Inorganic Chemistry, 2020, 36(6): 1176-1184. doi: 10.11862/CJIC.2020.131
20. [20]
  LI Cai-Hong , ZHANG Rui-Feng . Syntheses, Structures and Photoluminescent Properties of Three 4d-4f Heterometallic Coordination Polymers. Chinese Journal of Inorganic Chemistry, 2016, 32(4): 713-719. doi: 10.11862/CJIC.2016.081

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(1395)
HTML views(5)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Address：Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888

DownLoad: Full-Size Img PowerPoint

Return