Citation: WANG Hao, HOU Xiang-Yang, WANG Xiao, FU Feng. Structural Diversity and Luminescent Properties of Metal-organic Frameworks Based on a Rare Sulfonate and Imidazole Co-Ligand System[J]. Chinese Journal of Structural Chemistry, ;2016, 35(9): 1427-1437. doi: 10.14102/j.cnki.0254-5861.2011-1177 shu

Structural Diversity and Luminescent Properties of Metal-organic Frameworks Based on a Rare Sulfonate and Imidazole Co-Ligand System

1.
Department of Chemistry and Chemical Engineering, Shaanxi Key Laboratory of Chemical Reaction Engineering, Yan'an University, Yan'an 716000, China

Received Date: 25 February 2016

Fund Project: This work was supported by the National Natural Science Foundation of China (21503183) (21503183)Yanan university field scientific research projects (YDBK2015-02) (YDBK2015-02)

Four types of luminescent properties of metal-organic frameworks(MOFs) with formulas[Cd(1,2-BIYB)₂(H₂O)₂]_n·n(AQ-1,5-DAD)(1),[Cd(AQ-1,5-DAD)(1,3-BIYB)₂]_n(2),[Cd(1,3-BIYB)]_n·n(AQ-1,5-DAD)·n H₂O(3), and [Zn(1,4-BIYB)₂]_n·n(AQ-1,5-DAD)₂·6H₂O(4),(Na₂AQ-1,5-DAD=anthraquinone-1,5-disulfonic acid disodium, 1,2-BIYB=1,2-bis(imidazol-1-ylmethyl) benzene, 1,3-BIYB=1,3-bis(imidazol-1-ylmethyl) benzene, 1,4-BIYB=1,4-bis(imidazol-1-ylmethyl)benzene) have been synthesized based on a rare sulfonate and imidazole Co-ligand system under different conditions. The structural features of four types of MOFs 1~4 are as follows:MOFs 1 show a 3D supramolecular compound in which the double one-dimensional chains are further cross-linked by hydrogen bonds. 2 exhibits a 2D network constructed by two different 1D chains. 3 features a 2D supramolecular network, in which the 1D chains and AQ-1,5-DAD are arranged alternately through hydrogen bonds. 4 posseses a 3D supramolecular structure constructed by a 2D network and one-dimensional hydrogen bonding chains. All compounds 1~4 are characterized by elemental analysis, infrared spectroscopy, and thermogravimetric analysis. The luminescence properties of 1~4 have been investigated.
- sulfonate-imidazole system,
- structural diversity,
- luminescent properties
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