Citation: GAO Hui, LI Bing, JIN Xiao-Dong, BI Shu-Xian, TIAN Xiao-Yan, LIU Wan-Yi. Catalytic Kinetic on the Thermal Decomposition of Ammonium Perchlorate with a New Energetic Complex Based on 3,5-Bis(3-pyridyl)-1H-1,2,4-triazole[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1902-1911. doi: 10.14102/j.cnki.0254-5861.2011-1165 shu

Catalytic Kinetic on the Thermal Decomposition of Ammonium Perchlorate with a New Energetic Complex Based on 3,5-Bis(3-pyridyl)-1H-1,2,4-triazole

Department of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China

Corresponding author: LI Bing, nxdaxue@126.com
Received Date: 3 February 2016
Accepted Date: 28 April 2016

Fund Project: the National Natural Science Foundation of China 21263019 and 21467022

Figures(10)

A new energetic complex,[Co(3,3'-Hbpt)(Htm)]·H₂O (1, 3,3'-Hbpt=3,5-bis(3-pyridyl)-1H-1,2,4-triazole and H₃tm=trimesic acid), has been synthesized by hydrothermal reactions and characterized by single-crystal X-ray diffraction, elementary analysis, IR spectroscopy, thermogravimetric analysis and X-ray powder diffraction. Single-crystal X-ray diffraction indicates that the complex belongs to triclinic system, space group P1 with a=10.0911(1), b=10.2573(1), c=10.6393(1)Å, α=103.793(2), β=101.041(2), γ=107.918(3)°, V=974.9(2)Å³, Z=2, D_c=1.732 g·cm^-3, μ=0.941 mm^-1, M_r=508.31, F(000)=518, the final R=0.0523 and wR=0.0935 with I>2σ(I). In the title complex, Co(II) ions are connected by Htm^2- anions generating 1D ladder-like chains which are linked by 3,3'-Hbpt to form 1D cages. In addition, the thermal decomposition of ammonium perchlorate (AP) with complex 1 was explored by differential scanning calorimetry (DSC). AP is completely decomposed in a shorter time in the presence of complex 1, and the decomposition heat of the mixture is 2.531 kJ·g^-1, significantly higher than that of pure AP. By Kissinger's method, the ratio of Ea/ln(A) is 11.05 for the mixture, which indicates that complex 1 shows good catalytic activity toward the AP decomposition.
- 3,5-bis(3-pyridyl)-1H-1,2,4-triazole,
- ammonium perchlorate,
- catalytic,
- thermal decomposition
1. [1]
  Zhang, S.; Yang, Q.; Liu, X. Y.; Qu, X. N.; Wei, Q.; Xie, G.; Chen, S. P.; Gao, S. L. High-energy metal-organic frameworks (HE-MOFs): synthesis, structure and energetic performance. Coord. Chem. Rev. 2016, 307, 292-312.
2. [2]
  Li, S. H.; Wang, Y.; Qi, C.; Zhao, X. X.; Zhang, J. C.; Zhang, S. W.; Pang, S. P. 3D energetic metal-organic frameworks: synthesis and properties of high energy materials. Angew. Chem. Int. Ed. 2013, 52, 14031-14035.
3. [3]
  Zhao, F. Q.; Xue, L.; Xing, X. L.; Hu, R. Z.; Zhou, Z. M.; Gao, H. X.; Yi, J. H.; Xu, S. Y.; Pei, Q. Thermochemical properties and thermokinetic behavior of energetic triazole ionic salts. Sci. China Chem. 2011, 54, 461-474.
4. [4]
  Thottempudi, V.; Gao, H. X.; Shreeve, J. M. Trinitromethyl-substituted 5-nitro- or 3-azo-1,2,4-triazoles: synthesis, characterization, and energetic properties. J. Am. Chem. Soc. 2011, 133, 6464-6471.
5. [5]
  Wei, J. P.; Zhang, D.; Yang, Q.; Chen, S. P.; Gao, S. L. 0D Cu(II) and 1D mixed-valence Cu(I)/Cu(II) coordination compounds based on mixed ligands: syntheses, structures and catalytic thermal decomposition for HMX. Inorg. Chem. Commun. 2013, 30, 13-16.
6. [6]
  Li, B.; Chen, S. P.; Xie, G.; Yang, Q.; Gao, S, L. Coligand benzenedicarboxylate modulated zinc(II)-3,5-bis(3-pyridyl)-1H-1,2,4-triazole frameworks: synthesis, structure and luminescent property. Struct. Chem. 2012, 23, 417-423.
7. [7]
  Li, B.; Chen, S. P.; Yang, Q.; Gao, S. L. R-phenyldicarboxyl (R = H, NO2 and COOH) modular effect on Ni(II) coordination polymers incorporated with a versatile connector 1H-3-(3-pyridyl)-5-(4-pyridyl)-1,2,4-triazole. Polyhedron 2011, 30, 1213-1218.
8. [8]
  Huang, F. P.; Zhang, Q.; Yu, Q.; Bian, H. D.; Liang, H.; Yan, S. P.; Liao, D. Z.; Cheng, P. Coordination assemblies of CoII/NiII/ZnII/CdII with succinic acid and bent connectors: structural diversity and spin-canted antiferromagnetism. Cryst. Growth Des. 2012, 12, 1890-1898.
9. [9]
  Yang, C.; Huang, F. P.; Li, H. Y.; Yao, D.; Bian, H. D.; Yu, Q.; Xuan, D. F. Syntheses and crystal structures of three pillared complexes based on H2AIP and triazole-bipyridine ligands. J. Coord. Chem. 2013, 66, 3939-3948.
10. [10]
  Li, T.; Meng, Q. F.; Li, B.; Jin, X. D.; Gao, H.; Chen, X. Y.; Song, W. M.; Liu, W. Y. Assembly of a new fluorescent Cd(II) coordination compound with a versatile multidentate N-donor building block 3-(2-Pyridyl)-5-(3?-pyridyl)-1,2,4-triazole. Chin. J. Struct. Chem. 2015, 34, 1525-1532.
11. [11]
  Qin, X. H.; Zou, H. H.; Gui, L. C.; Liao, Y. Z.; Li, H. Y.; Huang, F. P. Crystal structure and luminescent properties of a Zn(II) coordination polymer assembled by mixed-ligand. Chin. J. Struct. Chem. 2014, 33, 1293-1299.
12. [12]
  Xu, Q. F.; Ge, J. F.; Zhou, Q. X.; Lu, J. M.; Ji, S. J.; Wang, L. H.; Zhang, Y.; Jin, X. M.; Wu, B. Hydrothermal synthesis, structure, and luminescent properties of selected Zn(II)/Cd(II) coordination polymers constructed from 3,5-bis(x-pyridyl)-1,2,4-triazole (x = 3, 4). Dalton Trans. 2011, 40, 2805-2814.
13. [13]
  Li, B.; Wei, Q.; Yang, Q.; Chen, S. P.; Gao, S. L. Synthesis, structure, and thermophysical properties of an energetic complex Co(3-(2-pyridyl)-5-(3?-pyridyl)-1H-1,2,4-triazole)3?H₂O. J. Chem. Eng. Data 2011, 56, 3043-3046.
14. [14]
  Xie, G.; Li, B.; Chen, S. P.; Yang, Q.; Wei, W.; Gao, S. L. Cobalt(II) coordination polymers built on isomeric dipyridyl triazole ligands with pyromellitic acid: synthesis, characterization and their effects on the thermal decomposition of ammonium perchlorate. Sci. China Chem. 2012, 55, 443-450.
15. [15]
  Li, B.; Shen, D.; Chen, X. Y.; Li, T.; Ren, J. L.; Hu, Q. L.; Liu, W. Y. A new 1-D energetic complex [Cu(2,3?-bpt)2?H₂O]n: synthesis, structure and catalytic thermal decomposition for ammonium perchlorate. J. Coord. Chem. 2014, 67, 2028-2038.
16. [16]
  Chen, L. J.; Li, L. P.; Li, G. S. Synthesis of CuO nanorods and their catalytic activity in the thermal decomposition of ammonium perchlorate. J. Alloys. Compd. 2008, 464, 532-536.
17. [17]
  Yang, Q.; Chen, S. P.; Xie, G.; Gao, S. L. Synthesis, crystal structure, sensitivity, and effect on thermal decomposition of ammonium perchlorate: an energetic compound Cu(HATZ)(PDA)(H₂O). J. Coord. Chem. 2012, 65, 2584-2592.
18. [18]
  Yu, Z. X.; Chen, L. F.; Lu, L. D.; Yang, X. J.; Wang, X. DSC/TG-MS study on in situ catalytic thermal decomposition of ammonium perchlorate over CoC2O4. Chin. J. Catal. 2009, 30, 19-23.
19. [19]
  Li, B.; Han, J.; Yang, Q. F.; Tian, X. Y.; Chen, X. Y. A new energetic complex [Co(2,4,3-tpt)2(H₂O)2]·2NO3: synthesis, structure, and catalytic thermal decomposition for ammonium perchlorate. Z. Anorg. Allg. Chem. 2015, 641, 2371-2375.
20. [20]
  Klap?tke, T. M.; Minar, N. K.; Stierstorfer, J. Investigations of bis(methyltetrazolyl)triazenes as nitrogen-rich ingredients in solid rocket propellants - synthesis, characterization and properties. Polyhedron 2009, 28, 13-26.
21. [21]
  Browne, E. 1,2,4-Triazol-3-ylpyridines. Aust. J. Chem. 1975, 28, 2543-2546.
22. [22]
  Wu, H. X. Construction of a photocatalytic cobalt(II) coordination polymer with 4-connected diamond topology. Chin. J. Struct. Chem. 2015, 34, 1593-1597.
23. [23]
  Wang, J. M.; Li, B.; Sun, L.; Li, T.; Zhou, H, L.; Ren, J. L.; Hu, Q. L. Synthesis, structure, thermostability and DFT calculations of a cobalt(II) coordination compound comstructed by oxybis (benzoic acid) and pyridyl-triazole. Chin. J. Inorg. Chem. 2014, 30, 683-688.
24. [24]
  Chen, L.; Wang, Y. L.; Liu, Q. Y.; Yao, Y. Solvothermal synthesis, crystal structure and luminescent property of a two-dimensional lead(II) compound: [Pb(bmzbc)2]n. Chin. J. Struct. Chem. 2016, 35, 61-68.
25. [25]
  Kurpiel-Gorgol, R.; Brzyska, W. Spectral and the thermal studies of Y(III) and heavy lanthanide 4-chlorophthalates. J. Therm. Anal. Calorim. 2005, 82, 389-394.
26. [26]
  Han, J.; Li, T.; Li, B. A new nickel(II) coordination compound constructed by pyridyl-triazole and oxybis (benzoic acid): synthesis, crystal structure and the effect on the thermal decomposition of ammonium perchlorate. Chin. J. Struct. Chem. 2015, 34, 253-259.
27. [27]
  Kulkarni, P. B.; Reddy, T. S.; Nair, J. K.; Nazare, A. N.; Talawar, M. B.; Mukundan, T.; Asthana, S. N. Studies on salts of 3-nitro-1,2,4-triazol-5-one (NTO) and 2,4,6-trinitroanilino benzoic acid (TABA): potential energetic ballistic modifiers. J. Hazard. Mater. 2005, 123, 54-60.
28. [28]
  Cheng, Z. Y.; Zhang, G. F.; Fan, X. Z.; Bi, F. Q.; Zhao, F. Q.; Zhang, W. Q.; Gao, Z. W. Synthesis, characterization, migration and catalytic effects of energetic ionic ferrocene compounds on thermal decomposition of main components of solid propellants Inorg. Chim. Acta 2014, 421, 191-199.
29. [29]
  Patil, P. R.; Krishnamurthy, V. N.; Joshi, S. S. Differential scanning calorimetric study of HTPB based composite propellants in presence of nano ferric oxide. Propell. Explos. Pyrot. 2006, 31, 442-446.
30. [30]
  Li, L. P.; Sun, X. F.; Qiu, X. Q.; Xu, J. X.; Li, G. S. Nature of catalytic activities of CoO nanocrystals in thermal decomposition of ammonium perchlorate. Inorg. Chem. 2008, 47, 8839-8846.
31. [31]
  Wang, W. T.; Chen, S. P.; Gao, S. L. Syntheses and characterization of lead(II) N,N-bis[1(2)H-tetrazol-5-yl]amine compounds and effects on thermal decomposition of ammonium perchlorate. Eur. J. Inorg. Chem. 2009, 10, 3475-3480.
1. [1]
  HAN Jing , LI Ting , LI Bing . A New Nickel(Ⅱ) Coordination Compound Constructed by Pyridyl-triazole and Oxybis (Benzoic Acid): Synthesis, Crystal Structure and the Effect on the Thermal Decomposition of Ammonium Perchlorate. Chinese Journal of Structural Chemistry, 2015, 34(2): 253-259. doi: 10.14102/j.cnki.0254-5861.2011-0461
2. [2]
  Xue-Zhi GAO , Huan SONG , Bing LI , Rui WANG , Xiao-Shuang ZHU , Xiao-Yan TIAN . Synthesis, Crystal Structure, and Catalytic Performance of a Cd(Ⅱ) Complex Based on 3-Carboxyl-5-ammino-1, 2, 4-triazole. Chinese Journal of Inorganic Chemistry, 2022, 38(9): 1808-1816. doi: 10.11862/CJIC.2022.193
3. [3]
  ZHAI Lian-Jie , WAGN Bo-Zhou , FAN Xue-Zhong , LI Xiang-Zhi . Synthesis, Crystal Structure and Thermal Decomposition of a New Energetic Potassium Salt of Bis(dinitromethyl)difurazanyl Ether. Chinese Journal of Structural Chemistry, 2014, 33(9): 1353-1359.
4. [4]
  Hong Ping LI , Jun LIU , Hai Fei ZHANG , Bu Xing HAN . Effect of Co-solvent and Pressure on the Thermal Decomposition of 2, 2' Azobis-(isobutyronitrile) in Supercritical CO₂. Chinese Chemical Letters, 2001, 12(8): 713-714.
5. [5]
  Bao Xue ZHOU , Shu Qin JIANG , Ding ZHOU , Yu Ting ZHAO . Preparation and Thermal Decomposition of [Cr (salen) (H₂O)₂] Cl. Chinese Chemical Letters, 1999, 10(5): 429-432.
6. [6]
  ZHANG Fu-Lan , HUANG Hui-Shenga , XIE Xiao-Hua . Theoretical Studies on the Thermal Decomposition Mechanism of Potassium Nitroformate. Chinese Journal of Structural Chemistry, 2016, 35(4): 514-520. doi: 10.14102/j.cnki.0254-5861.2011-0982
7. [7]
  Xin Hua XU , Hong Yi ZHOU , Da Hui WANG . Catalytic Dechlorination of Chlorobenzene in Water by Pd/Fe System. Chinese Chemical Letters, 2003, 14(7): 700-703.
8. [8]
  Yu LI , Ying-Fen ZHUANG , Yan-Lai ZHANG , An-Sheng FENG , Xun-Zhong ZOU . Syntheses, Crystal Structures, Luminescence and Catalytic Activity of Manganese(Ⅱ) and Cadmium(Ⅱ) Coordination Polymers Based on 2, 3-Dihydroxy-terephthalic Acid. Chinese Journal of Inorganic Chemistry, 2021, 37(6): 1135-1142. doi: 10.11862/CJIC.2021.132
9. [9]
  YANG Qing-Xiang , LEI Li-Ling , WANG Qing-Qing , WANG Fang-Cao , WANG Cong , DONG Meng-Guo , LI Yin-Ping , CHEN Zhi-Jun . Synthesis and Catalytic Performance for Oxidative Cyclization Reaction of Oil-Dispersible Core-Shell Fe₃O₄@MnO Nanocomposites. Chinese Journal of Inorganic Chemistry, 2020, 36(2): 385-391. doi: 10.11862/CJIC.2020.032
10. [10]
  Yi-Fen LUO , Lian-Jie ZHAI , Fu-Qiang BI , Huan HUO , Xiang-Zhi LI , Bo-Zhou WANG . A Novel Energetic Ionic Salt: Hydroxylammonium Potassium 3, 3'-Dinitro-5, 5'-bis-1, 2, 4-triazole-1, 1'-diolate Dihydrate. Chinese Journal of Structural Chemistry, 2020, 39(1): 96-103. doi: 10.14102/j.cnki.0254-5861.2011-2363
11. [11]
  CHENG Yong , SUN Fei-Fei , FENG Qi-Chun , ZHOU Ying-Hua . Synthesis of CuNPs@Cu(Ⅱ)-AMTD Metal-Organic Gel Composites with High Catalytic Activities. Chinese Journal of Inorganic Chemistry, 2018, 34(3): 551-559. doi: 10.11862/CJIC.2018.059
12. [12]
  LIU Lei-Li , LI Feng-Sheng , TAN Ling-Hua , LI Min , YANG Yi . Effect of Nanometer Metal Powders on the Thermal Decomposition of Ammonium Perchlorate. Chinese Journal of Applied Chemistry, 2004, 21(5): 488-492.
13. [13]
  Dan WU , Yun-Long ZHONG , Shao-Yan LU , Chun-Juan GAO , Ze-Jiang WANG , Xi-Ping HUANG . Synthesis via Precursor Method and Shape Evolution of Basic Magnesium Carbonate. Chinese Journal of Structural Chemistry, 2020, 39(3): 543-550. doi: 10.14102/j.cnki.0254–5861.2011–2456
14. [14]
  Zhang Ming , Zhao Fengqi , Yang Yanjing , Li Hui , Zhang Jiankan , Ma Wenzhe , Gao Hongxu , Li Na . Shape-Dependent Catalytic Activity of Nano-Fe₂O₃ on the Thermal Decomposition of TKX-50. Acta Physico-Chimica Sinica, 2020, 36(6): 1904027-0. doi: 10.3866/PKU.WHXB201904027
15. [15]
  GUO Tao , HUANG Xiao-Chuan , TANG Wang , WANG Zi-Jun , LIU Min , QIU Shao-Jun . Crystal Structure and Thermal Behavior of a Novel Cocrystal Consisting of 3,3'-Dinitrimino-5,5'-Bis(1H-1,2,4-triazole), H₂O and (CH₃)₂SO. Chinese Journal of Structural Chemistry, 2016, 35(4): 537-544. doi: 10.14102/j.cnki.0254-5861.2011-0883
16. [16]
  JIANG Qi-Ying , DENG Hong-Quan , SHEN Juan , ZHONG Guo-Qing . Synthesis,Characterization and Thermal Decomposition of Complex PrBi(edta)(NO₃)₂·6.5H₂O. Chinese Journal of Applied Chemistry, 2008, 25(8): 983-985.
17. [17]
  TANG Shuang-Ling , LIU Zu-Liang , ZHOU Xin-Li , LÜ Chun-Xu . Detonation Safety of Modified Ammonium Nitrate Ⅰ.The Influences of Calcium Carbonate and Magnesium Sulfate. Chinese Journal of Applied Chemistry, 2004, 21(1): 64-69.
18. [18]
  HONG Wei-Liang , DIAO Li-Hui , LIU Jian-Hong , ZHAO Feng-Qi , TIAN De-Yu , WANG Fang . Preparation of SnO₂-CuO Nanoparticles and Their Catalytic Activity in Thermal Decomposition of Cyclotrimethylene Trinitramine. Chinese Journal of Applied Chemistry, 2004, 21(8): 775-778.
19. [19]
  Zhang Ting , Li Cuicui , Wang Wei , Guo Zhaoqi , Pang Aimin , Ma Haixia . Construction of Three-Dimensional Hematite/Graphene with Effective Catalytic Activity for the Thermal Decomposition of CL-20. Acta Physico-Chimica Sinica, 2020, 36(6): 1905048-0. doi: 10.3866/PKU.WHXB201905048
20. [20]
  Luo Yan-Sheng , Chen Jing-Lin , Zeng Xue-Hua , Qiu Lu , Hua Li , Liu Sui-Jun , Wen He-Rui . A highly stable and luminescent mononuclear Cu(Ⅰ) bis-{5-tert-butyl-3-(6-methyl-2-pyridyl)-1H-1,2,4-triazole} complex. Chinese Chemical Letters, 2017, 28(5): 1027-1030. doi: 10.1016/j.cclet.2016.12.015

Get Citation

PDF

XML

Metrics

PDF Downloads(0)
Abstract views(6080)
HTML views(205)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142