Citation: YANG He, JIANG Yang, XU Bo, LI Cun-Cheng. Synthesis, Crystal Structure and Luminescent Property of a New Indium(III) Coordination Polymer[J]. Chinese Journal of Structural Chemistry, ;2016, 35(11): 1723-1727. doi: 10.14102/j.cnki.0254-5861.2011-1153 shu

Synthesis, Crystal Structure and Luminescent Property of a New Indium(III) Coordination Polymer

1.
Key Laboratory of Chemical Sensing & Analysis in Universities of Shandong(University of Jinan), School of Chemistry and Chemical Engineering, University of Jinan, Jinan 250022, China

Corresponding author: XU Bo, LI Cun-Cheng,
Received Date: 25 January 2016
Available Online: 10 March 2016
Fund Project: Supported by the National Natural Science Foundation of China (No. 21301069) (No. 21301069)

A new coordination complex[In(pda)_1.5(bpy)]_n (1, H₂pda=1,4-phenylenediacetic acid, bpy=2,2'-bipyridine) has been synthesized under hydrothermal conditions and characterized by IR spectrum, elemental analysis, PXRD and single-crystal X-ray diffraction analysis. Crystal data for the title complex are as follows:monoclinic system, space group P2₁/n with a=11.8015(7), b=15.9551(10), c=11.8858(8) Å, β=94.844(6)°, V=2230.0(2) Å³, M_r=559.25, Z=4, F(000)=1124, D_c=1.666 g/cm³, μ(MoKα)=1.106 mm^-1, R=0.0269 and wR=0.0569 for 4534 observed reflections with I>2σ(I). Complex 1 displays a 3D supermolecular structure based on the 1D zizag chains. Fluorescence spectrum measurement indicates that complex 1 shows strong fluorescence emission with a maximum peak at 447 nm in the solid state at room temperature.
- coordination complex,
- crystal structure,
- luminescence,
- indium
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