Citation: WU Xiang-Wen, YIN Shi, MA Jian-Ping. Syntheses and Crystal Structures of Two New Complexes Generated from 2-((Pyridin-3-ylmethyl)thio)-5-(6-quinolinyl)-1,3,4-oxadiazole and AgI Salts[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1894-1901. doi: 10.14102/j.cnki.0254-5861.2011-1148 shu

Syntheses and Crystal Structures of Two New Complexes Generated from 2-((Pyridin-3-ylmethyl)thio)-5-(6-quinolinyl)-1,3,4-oxadiazole and AgI Salts

  • Corresponding author: MA Jian-Ping, xxgk123@163.com
  • Received Date: 22 January 2016
    Accepted Date: 25 October 2016

    Fund Project: National Natural Science Foundation of China 21201112

Figures(9)

  • Two new AgI-complexes have been synthesized based on the semi-rigid ligand 2-((pyridin-3-ylmethyl)thio)-5-(6-quinolinyl)-1,3,4-oxadiazole (L), obtained by the condensation reaction of 5-(6-quinolinyl)-1,3,4-oxadiazole-2-thiol and 3-chloromethyl pyridine hydrochloride. Crystallization of L with AgOTf and AgPF6 in a CH2Cl2/MeOH mixed solvent system at room temperature affords a novel supramolecular[Ag2L2(CF3SO3)2] (I) and a coordination polymer[AgL(PF6)]n (II), respectively. Two complexes were characterized by TGA, X-ray powder and single-crystal diffraction.
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