Citation: WU Xiang-Wen, YIN Shi, MA Jian-Ping. Syntheses and Crystal Structures of Two New Complexes Generated from 2-((Pyridin-3-ylmethyl)thio)-5-(6-quinolinyl)-1,3,4-oxadiazole and Ag^I Salts[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1894-1901. doi: 10.14102/j.cnki.0254-5861.2011-1148 shu

Syntheses and Crystal Structures of Two New Complexes Generated from 2-((Pyridin-3-ylmethyl)thio)-5-(6-quinolinyl)-1,3,4-oxadiazole and Ag^I Salts

College of Chemistry, Chemical Engineering and Materials Science, Collaborative Innovation Center of Functionalized Probes for Chemical Imaging in Universities of Shandong, Key Laboratory of Molecular and Nano Probes, Ministry of Education, Shandong Provincial Key Laboratory of Clean Production of Fine Chemicals, Shandong Normal University, Jinan 250014, China

Corresponding author: MA Jian-Ping, xxgk123@163.com
Received Date: 22 January 2016
Accepted Date: 25 October 2016

Fund Project: National Natural Science Foundation of China 21201112

Figures(9)

Two new Ag^I-complexes have been synthesized based on the semi-rigid ligand 2-((pyridin-3-ylmethyl)thio)-5-(6-quinolinyl)-1,3,4-oxadiazole (L), obtained by the condensation reaction of 5-(6-quinolinyl)-1,3,4-oxadiazole-2-thiol and 3-chloromethyl pyridine hydrochloride. Crystallization of L with AgOTf and AgPF₆ in a CH₂Cl₂/MeOH mixed solvent system at room temperature affords a novel supramolecular[Ag₂L₂(CF₃SO₃)₂] (I) and a coordination polymer[AgL(PF₆)]_n (II), respectively. Two complexes were characterized by TGA, X-ray powder and single-crystal diffraction.
- crystal structure,
- coordination polymer,
- 1,3,4-oxadiazole,
- quinolinyl
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Syntheses and Crystal Structures of Two New Complexes Generated from 2-((Pyridin-3-ylmethyl)thio)-5-(6-quinolinyl)-1,3,4-oxadiazole and AgI Salts

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通讯作者: 陈斌, bchen63@163.com

Syntheses and Crystal Structures of Two New Complexes Generated from 2-((Pyridin-3-ylmethyl)thio)-5-(6-quinolinyl)-1,3,4-oxadiazole and Ag^I Salts