Citation: WU Xiang-Wen, YIN Shi, MA Jian-Ping. Syntheses and Crystal Structures of Two New Complexes Generated from 2-((Pyridin-3-ylmethyl)thio)-5-(6-quinolinyl)-1,3,4-oxadiazole and AgI Salts[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1894-1901. doi: 10.14102/j.cnki.0254-5861.2011-1148 shu

Syntheses and Crystal Structures of Two New Complexes Generated from 2-((Pyridin-3-ylmethyl)thio)-5-(6-quinolinyl)-1,3,4-oxadiazole and AgI Salts

  • Corresponding author: MA Jian-Ping, xxgk123@163.com
  • Received Date: 22 January 2016

    Fund Project: National Natural Science Foundation of China 21201112

Figures(9)

  • Two new AgI-complexes have been synthesized based on the semi-rigid ligand 2-((pyridin-3-ylmethyl)thio)-5-(6-quinolinyl)-1,3,4-oxadiazole (L), obtained by the condensation reaction of 5-(6-quinolinyl)-1,3,4-oxadiazole-2-thiol and 3-chloromethyl pyridine hydrochloride. Crystallization of L with AgOTf and AgPF6 in a CH2Cl2/MeOH mixed solvent system at room temperature affords a novel supramolecular[Ag2L2(CF3SO3)2] (I) and a coordination polymer[AgL(PF6)]n (II), respectively. Two complexes were characterized by TGA, X-ray powder and single-crystal diffraction.
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    1. [1]

      Lin W. B, Evans O. R, Xiong R. G, Wang Z. Y. Supramolecular engineering of chiral and acentric 2D networks. Synthesis, structures, and second-order nonlinear optical properties of bis(nicotinato)zinc and bis{3-[2-(4-pyridyl)ethenyl]benzoato} cadmium[J]. J. Am. Chem. Soc, 1998,120:13272-13273. doi: 10.1021/ja983415h

    2. [2]

      Gardner G. B, Kiang Y. H, Lee S, Asgaonkar A, Venkataraman D. Exchange properties of the three-dimensional coordination compound 1,3,5-tris(4-ethynylbenzonitrile) benzene AgO3SCF3[J]. J. Am. Chem. Soc, 1996,118:6946-6953. doi: 10.1021/ja960595r

    3. [3]

      Inoue K, Hayamizu T, Iwamura H, Hashizume D, Ohashi Y. Assemblage and alignment of the spins of the organic trinitroxide radical with a quartet ground state by means of complexation with magnetic metal ions. A molecule-based magnet with three-dimensional structure and high TC of 46 K[J]. J. Am. Chem. Soc, 1996,118:1803-1804. doi: 10.1021/ja952301s

    4. [4]

      Li M, Yao Y, Ding J, Liu L, Qin J. H, Zhao Y. P, Hou H. W, Fan Y. T. Spectroscopic and crystallographic investigations of novel BODIPY-derived metal-organic frameworks[J]. Inorg. Chem, 2015,54:1346-1353. doi: 10.1021/ic502219y

    5. [5]

      Wang K. C, Feng D. W, Liu T. F, Su J, Yuan S, Chen Y. P, Bosch M, Zou X. D, Zhou H. C. A series of highly stable mesoporous metalloporphyrin Fe-MOFs[J]. J. Am. Chem. Soc, 2014,136:13983-13986. doi: 10.1021/ja507269n

    6. [6]

      Kitagawa S, Kitaura R, Noro S. Functional porous coordination polymers[J]. Angew. Chem. Int. Ed, 2004,43:2334-2375. doi: 10.1002/(ISSN)1521-3773

    7. [7]

      Pachfule P, Das R, Poddar P, Banerjec R. Structural, magnetic, and gas adsorption study of a series of partially fluorinated metal-organic frameworks (HF-MOFs)[J]. Inorg. Chem, 2011,50:3855-3865. doi: 10.1021/ic1017246

    8. [8]

      Dong Y. B, Zhang Q, Wang L, Ma J. P, Huang R. Q, Shen D. Z, Chen D. Z. Organometallic coordination polymers generated from bent bis(acetylenylphenyl)oxadiazole ligands and Ag(I) salts[J]. Inorg. Chem, 2005,44:6591-6608. doi: 10.1021/ic0508223

    9. [9]

      Dong Y. B, Xu H. X, Ma J. P, Huang R. Q. Silver(I) coordination polymers based on a nano-sized bent bis(3-acetylenylphenyl-(4-cyanophenyl))oxadiazole ligand: the role of ligand isomerism and the templating effect of polyatomic anions and solvent intermediates[J]. Inorg. Chem, 2006,45:3325-3343. doi: 10.1021/ic052158w

    10. [10]

      Wu X. W, Zhang D, Ma J. P. Two different one-dimensional supramolecular chains formed from the reaction of 2-[1-(pyridin-4-ylmethyl)-1H-benzimidazol-2-yl] quinoline with two different precursors, Co(NO3)2 and CoCl2[J]. Acta Cryst, 2014,C70:522-527.  

    11. [11]

      Wu X. W, Wu W. F, Yin S, Ma J. P. Syntheses and structures of one CuI-containing coordination polymer and two macrocyclic supramolecular complexes based on flexible1,3,4-oxadiazole-containing ligands[J]. Acta Cryst, 2015,C71:683-689.  

    12. [12]

      Zheng Y, Li J. R, Du M, Zou R. Q, Bu X. H. Novel silver(I) coordination polymers with a series of bis(arylthio)ether ligands bearing a trans-2-butene backbone[J]. Crystal Growth & Design, 2005,5:215-222.  

    13. [13]

      Jing X. M, Zhou X. Y, Zhao T. T, Huo Q. S, Liu Y. L. Construction of lanthanide-organic frameworks from 2-(pyridine-3-yl)-1H-4,5-imidazole dicarboxyl-ate and oxalate[J]. Crystal Growth & Design, 2012,12:4225-4229.

    14. [14]

      Wu X. W, Wu W. F, Yin S, Ma J. P. A double helix coordination polymer generated from 2-((pyridin-4-ylmethyl)thio)- 5-(quinoline-2-yl)-1,3,4-oxadiazole and AgI salts[J]. Chin. J. Struct. Chem, 2015,34:1496-1502.  

    15. [15]

      Sheldrick, G. M. SHELXS 97, Program for Crystal Structure Solution. University of Gottingen, Germany, 1997.

    16. [16]

      Sheldrick, G. M. SHELXL-97, Program for X-ray Crystal Structure Refinement. University of Gottingen, Germany, 1997.

    17. [17]

      Dong Y. B, Cheng J. Y, Ma J. P, Huang R. Q, Smith M. D. Self-assembly of {Ag2N4}-core-containing coordination polymers from AgX (X = NO3 -, ClO4 -, and PF6 -) and oxadiazole-bridged 4,4'- and 3,3'-biphenylamine ligands[J]. Crystal Growth & Design, 2005,5:585-591.

    18. [18]

      Dong Y. B, Cheng J. Y, Huang R. Q, Smith M. D, zur Loye H. C. Self-assembly of coordination polymers from AgX (X = SbF6 -, PF6 -, and CF3SO3 -) and oxadiazole-containing ligands[J]. Inorg. Chem, 2003,42:5699-5706. doi: 10.1021/ic034306t

    19. [19]

      He L, Ma D. X, Duan L, Wei Y. G, Qiao J, Zhang D. Q, Dong G. F, Wang L. D, Qiu Y. Control of intramolecular π-π stacking interaction in cationic iridium complexes via fluorination of pendant phenyl rings[J]. Inorg. Chem, 2012,51:4502-4510. doi: 10.1021/ic2021325

    20. [20]

      Dong Y. B, Sun T, Ma J. P, Zhao X. X, Huang R. Q. Ag(I) and Cu(II) discrete and polymeric complexes based on single and double-armed oxadiazole-bridging organic clips[J]. Inorg. Chem, 2006,45:10613-10628. doi: 10.1021/ic0612552

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