Citation: CHEN Yan-Guo, WANG Qi-Ying, TANG Qiang, HONG Peng, HU Chuan-Qun. Syntheses, Crystal Structures and Fluorescence Properties of Two Mononuclear Copper(II) Compounds[J]. Chinese Journal of Structural Chemistry, ;2016, 35(12): 1885-1893. doi: 10.14102/j.cnki.0254-5861.2011-1142 shu

Syntheses, Crystal Structures and Fluorescence Properties of Two Mononuclear Copper(II) Compounds

  • Corresponding author: CHEN Yan-Guo, chenyg1965@163.com
  • Received Date: 19 January 2016

    Fund Project: Natural Foundation of Hubei Province 2010CDA020Key Foundation of Industry-University-Research Cooperation of Education Department, Hubei Province CXY2009A010Research Fund for the Doctor Program of Hubei University of Technology BSQD12139Ministry of Science and Technology Small and Medium-sized Enterprise Venture Funds 12C26214204453

Figures(6)

  • Two new compounds, 1 ([Cu(IDB)2]Cl2·2CH3CH2OH·2H2O (IDB=N,N-di(2-benzimidazolylmethyl)imine]) and 2 ([Cu(EDTB)]·2[C6H4(OH)COO]·6H2O (EDTB=N,N,N',N'-tetrakis-[(2-benzimidazolyl)methyl]-1,2-ethanediamine]), have been synthesized and their crystal structures were determined by single-crystal X-ray diffraction. Crystal 1 belongs to the triclinic system, space group P>1 with a=9.565(2), b=9.863(2), c=10.252(3)Å, α=81.915, β=88.330, γ=87.347°, V=956.28(40)Å3, Z=1, F(000)=427, Dc=1.419 g/cm3, Mr=817.27 and μ(Mo)=0.764 mm-1. The final R indices (I>2σ(I)):R=0.0505, wR=0.1417; R indices (all data):R=0.0591, wR=0.1525. Crystal 2 is of triclinic system, space group P>1 with a=11.487(3), b=13.396(4), c=17.977(5)Å, α=73.899(5), β=86.629(5), γ=65.018(4)°, V=2403.8(12)Å3, Z=2, F(000)=1072, Dc=1.417 g/cm3, Mr=1025.54, μ(Mo)=0.528 mm-1. The final R indices (I>2σ(I)):R=0.0769, wR=0.163 2; R indices (all data):R=0.0769, wR=0.1632. The two compounds exhibit mononuclear structures. The copper(II) atom of crystal 1 is six-coordinated by four nitrogen atoms of benzimidazole groups and two amine nitrogen atoms from the ligand IDB to adopt a distorted octahedral coordination geometry. The copper(II) atom of crystal 2 is six-coordinated by four nitrogen atoms of benzimidazole groups and two amine nitrogen atoms from the ligand EDTB to show a distorted octahedral coordination geometry. Particularly, the two compounds exhibit fluorescent properties at room temperature in ethanol.
  • 加载中
    1. [1]

      Kostakis G. E, Ako A. M, Powell A. K. Structural motifs and topological representation of Mn coordination clusters[J]. Chem. Soc. Rev, 2010,39:2238-2271. doi: 10.1039/b918192j

    2. [2]

      Hu X. L, Shi P. F, Xu X. Y, Yin F. J, Yang Q, Wang D. Q. The synthesis, structure and property study of mixed-valence tetranuclear copper complex [Cu2L2 ]·[Cu(pht)2 ]2[J]. Chin. Acta Chim. Sinica, 2010,68:487-492.  

    3. [3]

      Hu X. L, Shi P. F, Xu X. Y, Luan Y, Chen J. P, Wang D. Q. The synthesis, crystal structure and DNA-binding studies of Cu(I/II) complex [Cu(en)2]·[Cu(pht)2] 2[J]. Chin. Acta Chim. Sinica, 2009,67:2517-2522.  

    4. [4]

      Hu X. L, Xu X., Xu T. T, Wang D. Q. (5,5-Diphenylhydantoinato-κN3)[trisi(3-aminoprepyl)amine]copper(II) 5,5-diphenylhydantoinate methnol solvate[J]. Acta Cryst, 2006,62:2352-2353.

    5. [5]

      Hu X. L, Xu X. Y, Xu T. T, Wang D. Q. Trans-bis(5,5-diphenylhydantoinato-?N3)bis(furfurylamine-N)copper(II) 5,5-dipheny-lhydantoindisolvate[J]. Acta Cryst, 2006,62:2974-2975.

    6. [6]

      Ren Y. H, Dong J. L, Wang Z. W, Ren J. G. Synthesis and crystal structure of the azo copper(II)-complex[J]. Chin. J. Struct. Chem, 2011,30:376-379.  

    7. [7]

      Kocaka A, Yilmazc H, Faizb O, Andacc O. Experimental and theoretical studies on Cu(II) complex of N,N'-disalicylidene-2,3-diaminopyridine ligand reveal indirect evidence for DNA intercalation[J]. Polyhedron, 2016,104:106-115. doi: 10.1016/j.poly.2015.11.037

    8. [8]

      Venkatramaiah N, Firmino D. G, Paz F. A, Tome J. P. C. Fast detection of nitroaromatics using phosphonate pyrene motifs as dual chemosensors[J]. Chem. Commun, 2014,50:9683-9686. doi: 10.1039/C4CC03980G

    9. [9]

      Bazzicalupi C, Caltagirone C, Cao Z. F, Chen Q. B, Natale C. D, Garau A, Lippolis V, Lvova L, Liu H. L, Paolesse R, Zaccheroni N. Multimodal use of new coumarin-based fluorescent chemosensors: towards highly selective optical sensors for Hg2+ probing[J]. Chem. Eur. J, 2013,19:14639-14653. doi: 10.1002/chem.v19.43

    10. [10]

      Nejati K, Rezvani Z, Seyedahmadian M. The synthesis, characterization, thermal and optical properties of copper, nickel, and vanadyl complexes derived from azo dyes[J]. Dyes Pigm, 2009,83:304-311. doi: 10.1016/j.dyepig.2009.05.007

    11. [11]

      Cui Y. J, Xu H, Yue Y. F, Guo Z. Y, Yu J. C, Chen Z. X, Gao J. K, Yang Y, Qian G. D, Chen B. L. A luminescent mixed-lanthanide metal-organic framework thermometer[J]. J. Am. Chem. Soc, 2012,134:3979-3982. doi: 10.1021/ja2108036

    12. [12]

      Lan Y. Q, Jiang H. L, Li S. L, Xu Q. Solvent-induced controllable synthesis, single-crystal to single-crystal transformation and encapsulation of Alq3 for modulated luminescence in (4,8)-connected metal-organic frameworks[J]. Inorg. Chem, 2012,51:7484-7491. doi: 10.1021/ic202635a

    13. [13]

      Chen Y. G, Liao Z. R, Li W. K, Li D. F, Mei F. S, Wei Y. G. Synthesis, crystal structure and the activity about catalytic urea hydrolysis of [Ni(IDB)2][C6H4(OH)COO]·ClO4·CH3CH2OH·H2O[J]. Acta Chim. Sinica, 2000,58:1191-1195.  

    14. [14]

      Hendriks H. M. J, Bokkel H. W. O, Reedijk J. Synthesis, characterization and complex formation of N,N,N',N'-tetrakis--[(2-benzimidazolyl) methyl]-1,2-ethanediamine, a new hexadentate ligand[J]. Recl Trav Chim. Pays-Bas, 1979,98:499-500.

  • 加载中
    1. [1]

      ZHAO Wei-XingWEN Pu-HongWANG YanJIANG LuanFENG Guo-DongLI Zong-Xiao . Synthesis, Crystal Structure and Physical Properties of a Novel Cadmium(II) Supramolecular 3D Framework. Chinese Journal of Structural Chemistry, 2015, 34(5): 786-793. doi: 10.14102/j.cnki.0254-5861.2011-0576

    2. [2]

      YAN LiLIU Wei . Synthesis, Crystal Structure and Luminescence Study of a New Two-dimensional Mn(II) Coordination Polymer. Chinese Journal of Structural Chemistry, 2016, 35(11): 1770-1776. doi: 10.14102/j.cnki.0254-5861.2011-1163

    3. [3]

      ZHANG Si-FangLI Jun . Effect of Anionic Ancillary Ligands on Terpyridine Based Coordination Polymers: Synthesis, Crystal Structure and Fluorescence Property. Chinese Journal of Structural Chemistry, 2016, 35(5): 811-817. doi: 10.14102/j.cnki.0254-5861.2011-0946

    4. [4]

      WANG Rong-MingWANG Zhi-YingZHANG Xiao-WeiZHANG Liang-Liang . Solvothermal Synthesis, Crystal Structure and Properties of a 3D Organically Amine Templated Lanthanide Sulfate. Chinese Journal of Structural Chemistry, 2014, 33(7): 1043-1049.

    5. [5]

      WANG Rong-MingZHANG Ming-HuiLIU Xiao-QingLIU Xiao-BinWANG WenSUN Dao-Feng . Synthesis, Crystal Structure and Luminescence of a Trinuclear Magnesium Coordination Polymer Based on a Triangle Flexible Carboxylic Ligand. Chinese Journal of Structural Chemistry, 2015, 34(8): 1288-1294. doi: 10.14102/j.cnki.0254-5861.2011-0691

    6. [6]

      JIANG Da-YuSUI WeiLIU BoWANG Qing-Wei . A Novel Three-dimensional(4,4)-Connected Coordination Polymer Based on Benzotriazole and Thiophene-2,5-dicarboxylic Acid: Synthesis, Crystal Structure,and Luminescence Properties. Chinese Journal of Structural Chemistry, 2016, 35(9): 1445-1450. doi: 10.14102/j.cnki.0254-5861.2011-1136

    7. [7]

      KULAI IhorMALLET-LADEIRA SoniaKOVTUNENKO VolodymyrVOITENKO Zoia . One-pot Synthesis and X-ray Structure Determination of 7-(Diethylamino)-3-(4-aminophenyl)coumarin. Chinese Journal of Structural Chemistry, 2015, 34(12): 1841-1844. doi: 10.14102/j.cnki.0254-5861.2011-0842

    8. [8]

      LU Wen-GuanWANG Xiao-BingLIU Hong-WenHONG Xian-Lan . Two Coordination Polymers Constructed by Cd(II) and Zn(II) with in situ Generated 5-(3-Pyridyl)tetrazolate Ligand: Syntheses, Crystal Structures and Luminescence Properties. Chinese Journal of Structural Chemistry, 2016, 35(3): 383-391. doi: 10.14102/j.cnki.0254-5861.2011-0859

    9. [9]

      LI WeiLI Chang-HongLI Yu-LinLI Heng-Feng . Synthesis, Crystal Structure, Fluorescence, Thermal Stability and Magnetic Properties of the Dinuclear Manganese(II) Complex [Mn2(L)2(2,2'-bipy)2(H2O)5]2·3H2O. Chinese Journal of Structural Chemistry, 2015, 34(6): 973-978. doi: 10.14102/j.cnki.0254-5861.2011-0776

    10. [10]

      SUN JieLI Yan-MinLIU Yu-JingWANG Yan-HuaZHOU Ju-Hua . Solvothermal Synthesis, Crystal Structure and Luminescent Properties of a 3D MOF Based on 4,6-Dimethyl-5-nitroisophthalic Acid. Chinese Journal of Structural Chemistry, 2014, 33(12): 1854-1859. doi: 10.14102/j.cnki.0254-5861.2011-0532

    11. [11]

      OUYANG MiaoLI Jia-MingJIANG Yi-MinLIU Xu-HuiZHANG Hui-YingLIAO Bei-Ling . Synthesis and Crystal Structure of a New 2D O-bridged Copper(Ⅱ) Coordination Polymer Constructed from Sulfonate-derived Schiff Base. Chinese Journal of Structural Chemistry, 2015, 34(2): 299-305. doi: 10.14102/j.cnki.0254-5861.2011-0493

    12. [12]

      TAI Xi-ShiWANG XinYOU Hai-Ying . Synthesis, Crystal Structure and Antitumor Activity of a New Zn(II) Complex Based on N-Acetyl-L-phenylalanine and 1,10-Phenanthroline. Chinese Journal of Structural Chemistry, 2016, 35(4): 586-590. doi: 10.14102/j.cnki.0254-5861.2011-0910

    13. [13]

      Ju Tao LIU Xiao Hong WANG Jing Fu LIU . Synthesis and Crystal Structure of a Novel Compound of (C2N2H8O2) H6V10O28. Chinese Chemical Letters, 2004, 15(7): 859-862.

    14. [14]

      HU Xi-LanSHI Peng-FeiJIANG QinXU Rui-BoYIN Fu-JunWANG Da-Qi . Synthesis, Crystal Structure and Property of a Binuclear Copper Complex[Cu2L2(pht)2]2·H2O. Chinese Journal of Structural Chemistry, 2014, 33(9): 1281-1286.

    15. [15]

      PANG TaoWANG HuiWU XueWU LinZHAO Zhi-YongWU Gen-Hua . Synthesis, Crystal Structure and Fluorescence of a Bicyclic Product Containing Chromene and Propargylamine Skeleton. Chinese Journal of Structural Chemistry, 2016, 35(8): 1277-1282. doi: 10.14102/j.cnki.0254-5861.2011-1069

    16. [16]

      FENG ChaoHUANG Huan-HuanZHANG DuoZHAO Hong . One Novel 2D Co(Ⅱ) Polymer with 1,2,3-Triazole Derivative: Crystal Structure, Fluorescence and Hirshfeld Surface Analysis. Chinese Journal of Structural Chemistry, 2016, 35(9): 1376-1382. doi: 10.14102/j.cnki.0254-5861.2011-1084

    17. [17]

      Xiao Mei WANG Guang Yong ZHOU Wen Tao YU Min Hua JIANG . Synthesis, Structure of a Symmetrically Substituted Stilbene with Strong Two-photon Absorption and Up-converted Blue Fluorescence. Chinese Chemical Letters, 2001, 12(11): 1001-1004.

    18. [18]

      Peng WANG Xiao Yan JING Jun WANG Guo Yi ZHU . Synthesis, Electrochemistry, and Fluorescence of Two Ru(phen)32+-based Surfactants. Chinese Chemical Letters, 1999, 10(6): 505-506.

    19. [19]

      Yi YI Xiao Qiang WEI Ming Gui XIE Zhi Yun LU . Synthesis and Color-tunable Fluorescence Properties of Schiff Base Zinc (II) Complexes Used as Electroluminescent Materials. Chinese Chemical Letters, 2004, 15(5): 525-528.

    20. [20]

      LI Jia-MingSHI Zhong-FengHE Kun-Huan . Synthesis, Structure, and Surface Photo-electric Properties of a New Zn(II) Coordination Complex Constructed from 2-(1H-benzotriazol-1-yl)acetic Acid and 1,10-Phenanthroline Ligands. Chinese Journal of Structural Chemistry, 2016, 35(1): 135-142. doi: 10.14102/j.cnki.0254-5861.2011-0797

Metrics
  • PDF Downloads(0)
  • Abstract views(3415)
  • HTML views(61)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return