Citation: SUN Xiao-Fei, PAN Hui, LI Xiao-Ju. A Metal-organic Framework Containing Octanuclear Zn(Ⅱ) Clusters Constructed by 5-Methoxyisophthalate and Flexible Bis(imidazolyl) Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(9): 1406-1412. doi: 10.14102/j.cnki.0254-5861.2011-1115 shu

A Metal-organic Framework Containing Octanuclear Zn(Ⅱ) Clusters Constructed by 5-Methoxyisophthalate and Flexible Bis(imidazolyl) Ligand

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a College of Chemistry and Chemical Engineering, Fujian Normal University, Fuzhou 350007, China;
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b Fujian Key Laboratory of Polymer Materials, College of Materials Science and Engineering, Fujian Normal University, Fuzhou 350007, China

Corresponding author: LI Xiao-Ju,
Received Date: 3 January 2016
Available Online: 25 February 2016
Fund Project: This work was supported by the Natural Science Foundation of Fujian Province (2015J01038) (2015J01038) Provincial Education Department of Fujian (JA12070) (JA12070)State Key Laboratory of Structural Chemistry (20150015) (20150015)

The hydrothermal reaction of 5-methoxyisophthalic acid(MeO-H₂ip), 1,3-bis(2-methylimidazol-1'-yl)propane(bmip) and Zn(NO₃)₂·6H₂O in the presence of NaOCH₃ gave rise to a three-dimensional(3-D) metal-organic framework containing octanuclear Zn(II) units,[Zn₄(MeO-ip)₃(OH)₂(bmip)]_n. Single-crystal X-ray diffraction analysis reveals that the complex crystallizes in the triclinic space group P1 with a=11.348(3), b=14.163(4), c=15.088(4)Å, α=108.537(2), β=106.542(2), γ=103.106(1)°, V=2065.4(9)Å³, Z=2, M_r=334.62, D_c=1.740 g·cm^-3, μ=2.375 mm^-1, S=1.015, F(000)=1096, the final R=0.0272 and wR=0.0715 for 8929 observed reflections(I>2σ(I)). The complex is thermally stable up to 370℃, and exhibits photoluminescent emission at 450 nm on 350 nm excitation.
- carboxylate ligand,
- hydrothermal reaction,
- crystal structure,
- metal clusters zinc(Ⅱ)
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