Citation:
SUN Xiao-Fei, PAN Hui, LI Xiao-Ju. A Metal-organic Framework Containing Octanuclear Zn(Ⅱ) Clusters Constructed by 5-Methoxyisophthalate and Flexible Bis(imidazolyl) Ligand[J]. Chinese Journal of Structural Chemistry,
;2016, 35(9): 1406-1412.
doi:
10.14102/j.cnki.0254-5861.2011-1115
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The hydrothermal reaction of 5-methoxyisophthalic acid(MeO-H2ip), 1,3-bis(2-methylimidazol-1'-yl)propane(bmip) and Zn(NO3)2·6H2O in the presence of NaOCH3 gave rise to a three-dimensional(3-D) metal-organic framework containing octanuclear Zn(II) units,[Zn4(MeO-ip)3(OH)2(bmip)]n. Single-crystal X-ray diffraction analysis reveals that the complex crystallizes in the triclinic space group P1 with a=11.348(3), b=14.163(4), c=15.088(4)Å, α=108.537(2), β=106.542(2), γ=103.106(1)°, V=2065.4(9)Å3, Z=2, Mr=334.62, Dc=1.740 g·cm-3, μ=2.375 mm-1, S=1.015, F(000)=1096, the final R=0.0272 and wR=0.0715 for 8929 observed reflections(I>2σ(I)). The complex is thermally stable up to 370℃, and exhibits photoluminescent emission at 450 nm on 350 nm excitation.
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