Citation: CUI Pei-Pei, FU Ai-Yun, WANG Peng. Topology and Photoluminescence Property of a Neodymium-carboxylate Coordination Polymer Based on a Tripodal Flexible Ligand[J]. Chinese Journal of Structural Chemistry, ;2016, 35(9): 1391-1398. doi: 10.14102/j.cnki.0254-5861.2011-1089 shu

Topology and Photoluminescence Property of a Neodymium-carboxylate Coordination Polymer Based on a Tripodal Flexible Ligand

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a College of Chemistry & Life Science, Dezhou University, Dezhou, Shandong 253023, China;
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b Nanjing National Laboratory of Microstructures, Nanjing University, Nanjing 210093, China

Received Date: 16 December 2015
Available Online: 18 February 2016
Fund Project: Supported by the NSFC(No.21171031) (No.21171031)

A new metal-organic coordination polymer {[Nd(tci)(H₂O)₂]·2H₂O}_n(1) has been synthesized based on the flexible tricarboxylate ligand tris(2-carboxyethyl) isocyanuric acid(H₃tci) and structurally characterized by single-crystal X-ray diffraction analyses, elemental analysis, infrared spectra(IR), powder X-ray diffraction(PXRD) and thermogravimetric analysis(TGA). Complex 1 crystallizes in triclinic, space group P1 with a=9.1648(11), b=9.3326(12), c=12.440(2)Å, C₁₂H₂₀N₃O₁₃ Nd, M_r=558.55, V=886.9(2)Å³, Z=2, D_c=2.092 g·cm^-3, μ=3.006 mm^-1, F(000)=554, 2.56 < θ < 25.00°, λ(MoKα)=0.71073Å, T=293(2) K, the final R=0.0662 and wR=0.2071. X-ray diffraction analysis reveals that complex 1 is a two-dimensional layer, which is further assembled into a three-dimensional supramolecular architecture through hydrogen bonding interactions. The structure of complex 1 can be simplified as a rare 2-periodic uninodal {4⁸·6²} topology and a non-interpenetrating kgd topology. Furthermore, the thermal stability and photoluminescence property of 1 were investigated.
- tripodal flexible ligand,
- topology,
- conformation,
- photoluminescence property
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