Citation: FENG Chao, HUANG Huan-Huan, ZHANG Duo, ZHAO Hong. One Novel 2D Co(Ⅱ) Polymer with 1,2,3-Triazole Derivative: Crystal Structure, Fluorescence and Hirshfeld Surface Analysis[J]. Chinese Journal of Structural Chemistry, ;2016, 35(9): 1376-1382. doi: 10.14102/j.cnki.0254-5861.2011-1084 shu

One Novel 2D Co(Ⅱ) Polymer with 1,2,3-Triazole Derivative: Crystal Structure, Fluorescence and Hirshfeld Surface Analysis

1.
School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

Received Date: 10 December 2015
Available Online: 26 January 2016
Fund Project: Supported by the financial support of Fundamental Research Funds for the Central Universities(3207045420) Jiangsu Ainaji Neoenergy Science & Technology Co.,Ltd.(8507040091) (3207045420)

One new polymer[Co(L)(H₂O)₂]_n(1) was synthesized by 4-(ethoxycarbonyl)-5-methyl-1H-1,2,3-triazole-1-carboxylic acid(Emtc) under the in situ solvent thermal reaction(H₂L=1-(carboxymethyl)-5-methyl-1H-1,2,3-triazole-4-carboxylic acid). The title complex performs a wave-like 2D framework and the ligand H₂L demonstrates the coordination mode as μ₄-η²:η¹η¹:η¹. The crystal structure has been established by single-crystal X-ray diffraction, and characterized by FT-IR. Fluorescent property was investigated in this work. Hirshfeld surface analysis has also been carried out on 1, and obvious main intermolecular interactions are observed.
- 1H-1,2,3-triazole acid derivative,
- crystal structure,
- fluorescence,
- Hirshfeld surface analysis
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