Citation: WANG Lei, LI Wen-Xuan, YE Dan-Dan, GU Xiao-Min, SHAN Yue-Xia, NI Liang. Synthetic Assembly of Inorganic-organic Polyoxometalate Hybrid Structures Employing Noncovalent Interactions between 5,6-Substituted 1,10-Phenanthroline Derivative Ligands[J]. Chinese Journal of Structural Chemistry, ;2016, 35(11): 1655-1665. doi: 10.14102/j.cnki.0254-5861.2011-1082 shu

Synthetic Assembly of Inorganic-organic Polyoxometalate Hybrid Structures Employing Noncovalent Interactions between 5,6-Substituted 1,10-Phenanthroline Derivative Ligands

1.
School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013, China

Corresponding author: WANG Lei,
Received Date: 10 December 2015
Available Online: 11 April 2016
Fund Project: This work was supported by the National Natural Science Foundation of China (No. 21507047) (No. 21507047) Postdoctoral Science Foundation of China (No. 2015M571695) (No. 2015M571695) Postdoctoral Science Foundation of Jiangsu Province (No. 1401176C) (No. 1401176C)the Programs of Senior Talent Foundation of Jiangsu University (No. 14JDG053) (No. 14JDG053)

A new strategy for the synthesis of polyoxometalate-based (POM-based) metalorganic materials was developed. The approach takes the advantage of the ability of phenanthroline derivative base to build strong noncovalent interactions. Three POM-based metal-organic compounds,[Mn(MOPIP)₂(OH)₂][Mn(MOPIP)₂(OH)(SiW₁₂O₄₀)]·6H₂O (1),[Cu₂(MOPIP)₂(OH)₂(H₂O)]₂-(SiW₁₂O₄₀)·5H₂O (2) and [Co(Mo₂O₇)(MOPIP)]_n (3) (MOPIP=2-(4-methoxyphenyl)-1H-imidazo[4,5-f][1,10]phenanthroline), were synthesized under hydrothermal conditions. Single-crystal X-ray analysis reveals that compound 1 displays a mononuclear cluster. These clusters are interconnected by a framework of π…π stacking interactions to from a chain and layer structure. Compound 2 shows a multinuclear cluster with Keggin-type polyoxoanions[SiW₁₂O₄₀]^4- as building blocks. Strong hydrogen bonding interactions extend these multinuclear clusters into a two-dimensional layer. Compound 3 is a coordination polymer, in which [Mo₂O₇]^2- polyoxoanions connect the Co(Ⅱ) ions running along the direction of one of the crystallographic axes to from a linear chain. Adjacent chains are further assembled into a two-dimensional network by strong hydrogen bonding interactions. The main structural traits in all of the compounds are that polyoxometalate acts as inorganic building blocks and connect metal ions to form cluster structure and coordination polymer. In addition, the photocatalytic activities and mechanism of compounds 1~3 on the degradation of Rhodamine B (RhB) under UV irradiation have been investigated in detail.
- polyoxometalates,
- crystal structure,
- fluorescence,
- catalytic properties
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