Citation: CHANG Fouzi, MEMON Najm, AHMED Muhammad Naeem, TAHIR Muhammad Nawazc, MEMON Shahabuddin, CHANG Abdul Sattar, BHANGER Muhammad Iqbald, CHANDIO Anwer. Synthesis, Crystal Structure and Antimicrobial Activity of {[Bis(pyridine-kN)bis(3,5-dinitrosalicylato k-O,O')Zn(II)][bis(pyridine-kN)Zn(II)]}[J]. Chinese Journal of Structural Chemistry, ;2016, 35(5): 705-712. doi: 10.14102/j.cnki.0254-5861.2011-1055 shu

Synthesis, Crystal Structure and Antimicrobial Activity of {[Bis(pyridine-kN)bis(3,5-dinitrosalicylato k-O,O')Zn(II)][bis(pyridine-kN)Zn(II)]}

a.
a. National Centre of Excellence in Analytical Chemistry, University of Sindh, Jamshoro, Pakistan;
b.
b. Department of Chemistry, The University of Azad Jammu and Kashmir, Muzaffarabad 13100, Pakistan;
c.
c. Department of Physics, University of Sargodha, Sargodha, Pakistan;
d.
d. HEJ Research Institute of Chemistry, ICCBS, University of Karachi, Pakistan

Corresponding author: CHANG Fouzi,
Received Date: 20 November 2015
Available Online: 6 April 2016
Fund Project: Supported by Higher Education Science Foundation of Jiangsu Province (No. 15KJB150031) (No. 15KJB150031) State Key Laboratory of Structural Chemistry Fund (No. 20150009) (No. 20150009)

A novel {[bis(pyridine-kN)bis(3,5-dinitrosalicylato k-O,O')Zn(II)][bis(pyridine-kN)Zn(II)]} (C₃₄H₂₄N₈O₁₄Zn₂) was synthesized by a self-assemble method at room temperature. The molecular structure was determined by single-crystal X-ray analysis. The compound crystallizes in the monoclinic system, space group P2₁/n with a = 12.2156, b = 13.5696, c = 22.5602 Å, β = 90.061°, Z = 4 and V = 3739.6(3) Å³. The new 1D binuclear coordination polymer {[bis(py-kN)bis(3,5-dinitrosal k-O,O¢) Zn(II)][bis(py-kN)Zn(II)]} resulted from two different types of moieties. The polymer[bis(py-kN)bis(3,5-dinitrosal k-O,O')Zn(II)] unit is connected with [bis(py-kN) Zn(II)] by zigzag topology. One zinc(II) cation has a six-fold coordination environment, in which the metal atom is connected with four oxygen atoms of two 3,5-dinitrosalicylic acids to form equatorial bonds and two nitrogen atoms of pyridine to generate the axial bonds. Other four-fold nucleus contain two Zn–O bonds from different 3,5-dinitrosalicylic acids and two bonds with the N-atom of pyridine. Antimicrobial assay results indicated that the compound showed moderate activities against different bacterial and fungal strains.
- crystal structure,
- antimicrobial,
- pyridine,
- C–H…π interactions
1. [1]
  (1) Erxleben, A. Structures and properties of Zn(II) coordination polymers. Coord. Chem. Rev. 2003, 246, 203-228.
2. [2]
  (2) Al-Sudani, A. R. H. Dichlorido {8-[2-(dimethylamino) ethylamino] quinoline-k³N, N', N''} zinc. Acta Cryst. E 2014, 70-70.
3. [3]
  (3) Gembickya, M.; Moncol, J.; Lebruskova, K.; Martiska, L.; Valigura, D. Copper(II) 3,5-dinitrosalicylate the unique system for co-crystal formation by gentle changes in preparation procedure. Acta Chimica Slovaca 2008, 1, 290-300.
4. [4]
  (4) Valigura, D.; Melnik, M.; Koman, M.; Martiska, L.; Korabik, M.; Mrozinsky, J.; Glowiak, T. Structural confirmation of the 3,5-dinitrosalicylato anion coordination ability to metal ion crystal structure, spectral and magnetic properties of the [Cu₃{3,5-(NO₂)2sal^-2}₂{3,5-(NO₂)₂sal^-1}2(H₂O)₄]×4H₂O. Polyhedron 2004, 23, 2447-2456.
5. [5]
  (5) Yan, J. B.; Song, W. D.; Hao, W.; Li-Li, J. Poly [(l-3,5-dinitro-2-oxidobenzoato)-(µ-3-hydroxypyridine) copper(II)]. Acta Crystallogr. E 2008, 64, 651-652.
6. [6]
  (6) Kose, D. A.; Nedim, A.; Sahin, A.; Buyukgungor, O. A mononuclear, mixed (salicylato) (nicotinamide) complex of Zn(II) with penta and hexa-coordination sites a novel framework structure. J. Iran. Chem. Soc. 2012, 9, 591-597.
7. [7]
  (7) Choi, S. B.; Jhon, Y. H.; Ko, N.; Yang, J. K. Poly[bis(µ₄-2,3,5,6-tetrafluorobenzene-1,4-dicarboxylato-k⁴O¹:O¹':O⁴:O⁴')bis-(tetrahydrofuran-kO)dizinc]. Acta Cryst. E 2013, 70, m3-m3.
8. [8]
  (8) Stachova, P.; Valigura, D.; Koman, M.; Melnik, M.; Korabik, M.; Mrozinski, J.; Glowiak, T. Crystal structure, magnetic and spectral properties of tetrakis(nitrobenzoato)di(aqua)dicopper(II) dehydrate. Polyhedron 2004, 23, 1303-1308.
9. [9]
  (9) Lemoine, P.; Viossat, B.; Dung, N. H.; Tomas, A.; Morgant, G.; Greenaway, F.; Sorenson, T.; John, R. J. Synthesis, crystal structures, and anti-convulsant activities of ternary [ZnII(3,5-diisopropylsalicylate)2], [ZnII(salicylate)2] and [ZnII(aspirinate)2] complexes. J. Inorg. Biochem. 2004, 98, 1734-1749.
10. [10]
  (10) Zhu, L. G.; Kitagawa, S.; Miyasaka, H.; Chang, H. C. Syntheses and crystal structures of three one-dimensional copper(II) complexes constructed by salicylate and 4,4-bipyridine ladder, zig-zag, and linear polymeric assembly. J. Inorg. Chimica Acta 2003, 355, 121-126.
11. [11]
  (11) Brownless, N. J.; Edward, D. A.; Mahon, M. F. Some complexes derived from zinc salicylate of 3,5-di-tert-butylsalicylate. The crystal structure of (2, 2%-bipyridyl) (methanol) (O-salicylato) (O,O%salicylato)zinc. J. Inorg. Chimica Acta 1999, 287, 89-94.
12. [12]
  (12) He, X.; Li, Y. N.; Li, G. H.; Li, Y. Z.; Zhang, P.; Xu, J. N.; Wang, Y. Synthesis, crystal structure and magnetic properties of a new 1D cobalt(II) complex with 1,10-phenanthroline and 3,5-dinitrosalicylate acid ligands. J. Inorg. Chem. Comm. 2005, 8, 983-987.
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