Citation: ZHOU Yuan, YOU Ge-Yun, PENG Hao, HE Hong-Wu. Synthesis, Characterization, X-ray Crystal Structure and Herbicidal Activity of (E)-2-(2,4-Dichlorophenoxy)-1- (5,5-dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)vinyl 2-(2,4-Dichlorophenoxy)acetate[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 857-862. doi: 10.14102/j.cnki.0254-5861.2011-1051 shu

Synthesis, Characterization, X-ray Crystal Structure and Herbicidal Activity of (E)-2-(2,4-Dichlorophenoxy)-1- (5,5-dimethyl-2-oxido-1,3,2-dioxaphosphinan-2-yl)vinyl 2-(2,4-Dichlorophenoxy)acetate

1.
Key Laboratory of Pesticide and Chemical Biology, Ministry of Education and College of Chemistry, Central China Normal University, Wuhan 430079, China

Corresponding author: PENG Hao,
Received Date: 12 November 2015
Available Online: 1 April 2016
Fund Project: and excellent doctorial dissertation cultivation grant from Central China Normal University (No. 2015YBYB116) (No. 2014CFA111)

A new crystal of (E)-2-(2,4-dichlorophenoxy)-1-(5,5-dimethyl-2-oxido-1,3,2-dioxa- phosphinan-2-yl)vinyl 2-(2,4-dichlorophenoxy)acetate has been determined by single-crystal X-ray diffraction. The compound crystallizes in triclinic, space group P with a = 7.9393(17), b = 11.974(3) Å, c = 13.532(3) Å, α = 90.937(4), β = 101.998(3), γ = 101.363(4)°, V = 1231.5(5) Å³, D_c = 1.500 Mg/m³, Z = 2, F(000) = 568 and μ = 0.585 mm^-1. The molecular packing in the crystal is the result of C(10)–H(10)…O(5) hydrogen bond, as well as weak π-π stacking interactions. The herbicidal activity results indicated that the title compound 3 showed 80~100% inhibitory activities against all of the tested weeds at a dosage of 150 g·ai/ha.
- X-ray crystallography,
- phosphonate,
- (E)-vinyl acetate,
- herbicidal activity
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