Citation: DONG Jin-Long, SU Feng, SONG Zhena, LI Hao-Yang, REN Yue-Hong, REN Jian-Guo. Crystal Structure of the Coordination Polymer of Sodium with Hydrazone Derivant of Acetoacetanilide[J]. Chinese Journal of Structural Chemistry, ;2016, 35(4): 521-528. doi: 10.14102/j.cnki.0254-5861.2011-1024 shu

Crystal Structure of the Coordination Polymer of Sodium with Hydrazone Derivant of Acetoacetanilide

1.
a Department of Chemistry, Taiyuan Normal University, Taiyuan 030031, China;
2.
b School of Chemistry and Chemical Engineering, Shanxi University, Taiyuan 030006, China;
3.
c Institute of Molecular Science, Key Laboratory of Chemical Biology and Molecular Engineering of the Education Ministry, Shanxi University, Taiyuan 030006, China

Received Date: 21 October 2015
Available Online: 8 December 2015
Fund Project: This work was supported by the Soft Science project of Shanxi Province (No. 2013041020-03) (No. 2013041020-03)the National Natural Science Foundation of China (No. 51174275) (No. 51174275)

One new polymer,[Na(NPHSNPAB)(CH₃OH)]_n, where NPHSNPAB stands for Nphenyl-2-[2-hydroxy-3-sulfo-5-nitrophenylhydrazone]butadione-1,3, has been synthesized and characterized by ¹H NMR and FTIR spectroscopy and single-crystal X-ray diffraction. For this complex:C₁₇H₁₇N₄NaO₉S, M_r=476.39, triclinic system, space group P1, a=8.8741(18), b=10.942(2), c=12.039(2) Å, α=65.74(3), β=77.49(3), γ=84.30(3)°, V=1040.3(4) Å³, Z=2, Dc=1.521 g/cm³, λ=0.71073 Å, F(000)=492, S=1.106, R=0.0614 and wR=0.1423 for 2945 observed reflections with I > 2(I). X-ray structural analysis revealed that the structure of NPHSNPAB framework was almost planar by C-H…O, N-H…O, O-H…O, and O-H…S hydrogen bonds. Moreover, sodium(I) center was bound by six O and one N atoms, forming the coordination polymer. The molecular packing diagram showed complicated hydrogen bonds and π…π stacking interaction in the polymer. The average bond distance of the two dicyclic units (3.768 Å) indicated strong π…π stacking interaction. The complex displays greenyellow emission at room temperature.
- sodium(I) complex,
- polymer,
- hydrazone derivant,
- crystal structure,
- hydrogen bonds,
- π∙∙∙π stacking interaction
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沈阳化工大学材料科学与工程学院沈阳 110142