Citation: YUAN Shuai, ZHANG Yue-Jia, HOU Jin-Yan, LIU Qing-Lin, LI Dong-Ping, LI Yong-Xiu. Syntheses, Crystal Structures and Luminescent Properties of Two Schiff Base Complexes[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 965-972. doi: 10.14102/j.cnki.0254-5861.2011-0992 shu

Syntheses, Crystal Structures and Luminescent Properties of Two Schiff Base Complexes

  • Corresponding author: LI Dong-Ping,  LI Yong-Xiu, 
  • Received Date: 29 September 2015
    Available Online: 21 January 2016

    Fund Project: the Education Department of Jiangxi Province (GJJ12041) (20114BAB213001)

  • Two new transition metal complexes based on chiral Schiff base ligand, namely Zn(L1)2 (1) and Cd(L2)2 (2) (L1 = (R,E)-3-(2-hydroxy-3-methoxybenzylideneamino)propane-1,2-diol, L2= (R,E)-2-((2-hydroxy-1-phenylethylimino)methyl)-6-methoxyphenol), have been synthesized and characterized. Single-crystal X-ray diffractions reveal that both 1 and 2 crystallize in the same monoclinic space group C2. 1 is four-coordinated, while 2 is six-coordinated. Complexes 1 and 2 show fluorescent emission at 479 and 580 nm, respectively. Moreover, 1 and 2 exhibit selective and sensitive recognition toward Zn2+/Cd2+ ions in the methanol solution.
  • 加载中
    1. [1]

      (1) (a) Anbu, S.; Kamalraj, S.; Paul, A.; Jayabaskaran, C.; Pombeiro, A. J. L. The phenanthroimidazole-based dizinc(II) complex as a fluorescent probe for the pyrophosphate ion as generated in polymerase chain reactions and pyrosequencing. Dalton Trans. 2015, 44, 3930–3933. (b) Huerta-Aguilar, C. A.; Pandiyan, T.; Singh, N.; Jayanthi, N. Three novel input logic gates supported by fluorescence studies: organic nanoparticles (ONPs) as chemo-sensor for detection of Zn2+ and Al3+ in aqueous medium. Spectrochim. Acta A 2015, 146, 142–150.

    2. [2]

      (2) Anbu, S.; Ravishankaran, R.; Guedes da Silva, M. F. C.; Karande, A. A.; Pombeiro, A. J. L. Differentially selective chemosensor with fluorescence off-on responses on Cu2+ and Zn2+ ions in aqueous media and applications in pyrophosphate sensing, live cell imaging and cytotoxicity. Inorg. Chem. 2014, 53, 6655–6664.

    3. [3]

      (3) (a) Xia, S. J.; Liu, G.; Pu, S. Z. A highly selective fluorescence sensor for Zn2+ and Cu2+ based on diarylethene with a piperazine-linked amidoquinoline unit. J. Mater. Chem. C 2015, 3, 4023–4029 (b) Arivazhagan, C.; Borthakur, R.; Ghosh, S. Ferrocene and triazole-appended rhodamine based multisignaling sensors for Hg2+ and their application in live cell imaging. Organometallics 2015, 34, 1147-1155.

    4. [4]

      (4) (a) Ding, A. X.; Tang, F.; Wang, T.; Tao, X. T.; Yang, J. X. A α-cyanostilbene-modified Schiff base as efficient turn-on fluorescent chemosensor for Zn2+. J. Chem. Sci., 2015, 3, 375–382. (b) Erdemir, S.; Malkondu, S. A novel “turn on” fluorescent sensor based onhydroxy-triphenylamine for Zn2+ and Cd2+ ions in MeCN. Sensor. Actuat. B-Chem. 2013, 188, 1225–1229. (c) Mummidivarapu, V. V. S.; Bandaru, S.; Yarramala, D. S.; Samanta, K.; Mhatre, D. S.; Rao, C. P. Binding and ratiometric dual ion recognition of Zn2+ and Cu2+ by 1,3,5-tris-amidoquinoline conjugate of calix[6]arene by spectroscopy and its supramolecular features by microscopy. Anal. Chem. 2015, 87, 4988–4995. (d) Li, Z. X.; Zhang, W. Y.; Liu, X. J.; Liu, C. X.; Yu, M. M.; Wei, L. H. Naked-eye-based selective detection of pyrophosphate with a Zn2+ complex in aqueous solution and electrospun nanofibers. RSC Adv. 2015, 5, 25229–25235.

    5. [5]

      (5) Parthiban, C.; Elango, K. P. Amino-naphthoquinone and its metal chelates for selective sensing offluoride ions. Sensor. Actuat. B-Chem. 2015, 215, 544–552.

    6. [6]

      (6) Yang, Q. Z.; Wu, L. Z.; Zhang, H.; Chen, B.; Wu, Z. X.; Zhang, L. P.; Tung, C. H. A luminescent chemosensor with specific response for Mg2+. Inorg. Chem. 2004, 43, 5195–5197.

    7. [7]

      (7) (a) Lin, H.; Emin, M.; Schmittel, M. Comparison of ruthenium(II) and cyclometalated iridium(III) azacrown ether phenanthroline hybrids for the detection of metal cations by electrochemiluminescence. Dalton Trans. 2010, 39, 5130–5138. (b) Chall, S.; Mati, S. S.; Konar, S.; Singharoy, D.; Bhattacharya, S. C. An efficient, Schiff-base derivative for selective fluorescence sensing of Zn2+ ions: quantum chemical calculation appended by real sample application and cell imaging study. Org. Biomol. Chem. 2014, 12, 6447–6456.

    8. [8]

      (8) Lee, S. A.; Lee, J. J.; Shin, J. W.; Min, K. S.; Kim, C. A colorimetric chemosensor for the sequential detection of copper(II) and cysteine. Dyes Pigments 2015, 116, 131–138.

    9. [9]

      (9) (a) Wu, L. M.; Li, Q.; Jin, L. F.; Zhou, Z. Q. Synthesis and structure of the acylhydrazone Schiff base. Chin. J. Struct. Chem. 2010, 9, 1399–1403. (b) Jin, R. Y.; Sun, X. H.; Liu, Y. F.; Chen, B.; Shen, S. Q.; Ma, H. X. Synthesis, structure and biological activity of 5-benzyl-4-amino-1,2,4-triazole-3-thione Schiff base. Chin. J. Struct. Chem., 2014, 2, 253–257. (c) Li, F. R.; Zhang, X.; Wang, D. D.; Xue, Z. N.; Ma, Y. K. Syntheses, crystal structures and antibacterial activities of Schiff base ligand and its nickel(II) complex. Chin. J. Struct. Chem. 2014, 9, 1367–1374. (d) Hu, J. F.; Qin, Y. R.; Li, Y.; Liu, W.; Wang, Y.; Li, Y. H. Syntheses, structures, and luminescent properties of new ZnII–YIII and ZnII–LnIII Schiff base complexes. Chin. J. Struct. Chem., 2015, 8, 1273–1280.

    10. [10]

      (10) (a) Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures. University of Göttingen, Germany 1997. (b) Sheldrick, G. M. SHELXL-97, Program for Crystal Structure Refinement. University of Gottingen, Germany 1997.

    11. [11]

      (11) (a) Ying, S. M.; Chen, F.; Huang, X. H.; Xie, J. Y. Synthesis, crystal structure and photoluminescence of a 2D two-fold interpenetrating Cd(II) coordination polymer based on a flexible reduced Schiff base ligand. Chin. J. Struct. Chem. 2013, 2, 193–198. (b) Huang, C.; Wu, J.; Chen, D. M.; Zhang, Q. L.; Zhu, B. X. Syntheses and crystal structures of Cd(II) and Zn(II) complexes containing 2-acetylpyridine-o-aminobenzoylhydrazone ligand. Chin. J. Inorg. Chem. 2015, 1, 109–113.

    12. [12]

      (12) (a) Santana, M. D.; Garcia-Bueno, R.; Garcia, G.; Piernas, M. J.; Perez, J.; Garcia, L.; Lopez-Garcia, I. Benzazolate complexes of pentacoordinate nickel(II). Synthesis, spectroscopic study and luminescent response towards metal cations, Polyhedron 2013, 61, 161–171. (b) Tong, Y. P.; Zheng, S. L.; Chen, X. M. Syntheses, structures, photoluminescence and theoretical studies of a class of beryllium(II) compounds of aromatic N,O-chelate ligands. Inorg. Chem. 2005, 44, 4270–4275.

    13. [13]

      (13) Chen, P.; Meyer, T. J. Medium effects on charge transfer in metal complexes. Chem. Rev. 1998, 98, 1439–1477.

    14. [14]

      (14) Zheng, S. L.; Yang, J. H.; Yu, X. L.; Chen, X. M.; Wong, W. T. Syntheses, structures, photoluminescence, and theoretical studies of d10 metal complexes of 2,2'-dihydroxy-[1,1']binaphthalenyl-3,3'-dicarboxylate. Inorg. Chem. 2004, 43, 830–838.

  • 加载中
    1. [1]

      LI Fei-RanZHANG XinWANG Dong-DongXUE Zhi-NaMA Ying-Ke . Syntheses, Crystal Structures and Antibacterial Activities of Schiff Base Ligand and Its Nickel(Ⅱ) Complex. Chinese Journal of Structural Chemistry, 2014, 33(9): 1367-1374.

    2. [2]

      Yi YI Xiao Qiang WEI Ming Gui XIE Zhi Yun LU . Synthesis and Color-tunable Fluorescence Properties of Schiff Base Zinc (II) Complexes Used as Electroluminescent Materials. Chinese Chemical Letters, 2004, 15(5): 525-528.

    3. [3]

      Xiao Qiang WEI Zhi Yun LU Ping ZOU Ming Gui XIE . Synthesis of Two Blue-light-emitting Complexes with Schiff Base Calixarene as the Ligand. Chinese Chemical Letters, 2003, 14(3): 263-266.

    4. [4]

      Yan CAI Ming Qing CHEN Juan XU Pin Fang WU Akashi MITSURU Xiao Hua HUANG . Synthesis and Characterization of Samarium (Ⅲ) Containing Poly-(N-vinylacetamide) Complex. Chinese Chemical Letters, 2004, 15(9): 1109-1112.

    5. [5]

      MAO Pan-DongYAN Ling-LingWU Wei-NaSONG Yi-HeYAO Bi-Xin . Ni (Ⅱ)/Cu (Ⅱ)/Zn (Ⅱ) Complexes Baded on a Bis (pyrrol-2-yl-methyleneamine) Ligand:Syntheses, Characterization, Fluorescence Properties and Crystal Structures of Ni (Ⅱ)/Cu (Ⅱ) Complexes. Chinese Journal of Inorganic Chemistry, 2016, 32(5): 879-883. doi: 10.11862/CJIC.2016.098

    6. [6]

      Gholamhossein GrivaniAbbase GhavamiVálav EignerMichal DušekAliakbar Dehno Khalaji . A new oxidovanadium(IV) Schiff base complex containing asymmetric tetradentate ONN'O' Schiff base ligand: Synthesis, characterization, crystal structure determination, thermal study and catalytic activity. Chinese Chemical Letters, 2015, 26(6): 779-784. doi: 10.1016/j.cclet.2015.03.014

    7. [7]

      Chen WeixingWang TingZhang YunfeiLi ShuyingZhou HongweiJia YanlinJin Xilang . A Seminaphthorhodafluor-Based Fluorescent Probe for H2S Detection and Its Application. Chinese Journal of Organic Chemistry, 2020, 40(9): 2956-2962. doi: 10.6023/cjoc202006001

    8. [8]

      Ayse ERCAG Sema Oztürk YILDIRIM Mehmet AKKURT Mahmure Ustün OZGUR Frank W. HEINEMANN . Novel Isatin-Schiff Base Cu (H) and Ni(H) Complexes. X-ray Crystal Structure of Bis[3-(4-hexylphenylimino)-1H-indol-2(3H)-one]-dichlorocopper(H) Complex. Chinese Chemical Letters, 2006, 17(2): 243-246.

    9. [9]

      Zhao Ming XUE Yu Peng TIAN Dong WANG Min Hua JIANG . One-and Two-photon Excited Fluorescence of Zinc(Ⅱ), Cadmium(Ⅱ) Complexes Containing Phenothiazine Ligand. Chinese Chemical Letters, 2003, 14(5): 525-528.

    10. [10]

      LI Chang-HongLI WeiLI Heng-FengTAN Xiong-Wen . Crystal Structure, Fluorescence and Thermal Stability Properties of a Dinuclear Copper(Ⅱ) Complex [Cu2(L)2(phen)2]·5H2O (H2L=Bicycle[2.2.1] hept-2-en-5,6-dicarboxylic acid). Chinese Journal of Structural Chemistry, 2015, 34(12): 1922-1926. doi: 10.14102/j.cnki.0254-5861.2011-0952

    11. [11]

      LI WeiLI Chang-HongLI Yu-LinLI Heng-Feng . Synthesis, Crystal Structure, Fluorescence, Thermal Stability and Magnetic Properties of the Dinuclear Manganese(II) Complex [Mn2(L)2(2,2'-bipy)2(H2O)5]2·3H2O. Chinese Journal of Structural Chemistry, 2015, 34(6): 973-978. doi: 10.14102/j.cnki.0254-5861.2011-0776

    12. [12]

      HOU Xu-FengZHAO Xiao-LeiZHANG LuWU Wei-NaWANG Yuan . Co(Ⅱ)/Zn(Ⅱ)/Cu(Ⅱ) Complexes Containing Hydrazone Ligand Bearing Pyrazine Unit: Syntheses, Crystal Structures and Fluorescence Properties. Chinese Journal of Inorganic Chemistry, 2018, 34(1): 201-205. doi: 10.11862/CJIC.2018.005

    13. [13]

      Alekha Kumar SutarYasobanta DasSasmita PattnaikAnita RoutarayNibedita NathPrasanta RathTungabidya Maharana . Novel polystyrene-anchored zinc complex:Efficient catalyst for phenol oxidation. Chinese Journal of Catalysis, 2014, 35(10): 1701-1708. doi: 10.1016/S1872-2067(14)60113-3

    14. [14]

      YAN LiLI Chuan-BiCUI DiZHANG Yi-Ying . Hydrothermal Synthesis, Crystal Structure, Thermal Stability and Photophysical Property of a Novel Zinc Complex with Mixed Ligands. Chinese Journal of Structural Chemistry, 2015, 34(2): 221-226. doi: 10.14102/j.cnki.0254-5861.2011-0446

    15. [15]

      LI You-GuiHAN LeiMA GangZHU Cheng-Feng . Synthesis, Structure and Property of One Bis(benzimidazolin-2-ylidene) Arene-mercury(Ⅱ) Complex. Chinese Journal of Structural Chemistry, 2014, 33(11): 1610-1616. doi: 10.14102/j.cnki.0254-5861.2011-0325

    16. [16]

      Mei Fang Yin Ti Feng Jiao Ming Hua Liu . Acidichromism in the LB film of bolaform Schiff base. Chinese Chemical Letters, 2007, 18(1): 30-32. doi: 10.1016/j.cclet.2006.11.008

    17. [17]

      Xiao Bing WAN Chuan Ming JIN Xun GUO Guo Yuan LU . Synthesis of Schiff Base Calix[4]arene Crowns. Chinese Chemical Letters, 2002, 13(8): 699-700.

    18. [18]

      LIU ChengLIU Qi-HuiGE Shu-BaoWU Gang . Synthesis, Structure and Properties of a New Lead(Ⅱ) Complex of 1,3-Benzenedicarboxylic Acid, 1,10-Phenanthroline and Its Thermal Decomposition to PbO Micro-crystal Particles. Chinese Journal of Structural Chemistry, 2014, 33(5): 713-720.

    19. [19]

      PAN Jian-TingDING Ai-XiangYANG Jia-XiangHUANG Jian-YanKONG Lin . Pyridine-contained α-Cyanostilbenzene Schiff Base: Preparation, Crystal Structure and Photoluminescence. Chinese Journal of Structural Chemistry, 2015, 34(2): 215-220. doi: 10.14102/j.cnki.0254-5861.2011-0463

    20. [20]

      Ke Qiang DING Zhen Bin JIA Qing Fei WANG Na TIAN Ru Ting TONG Xin Kui WANG Hui Bo SHAO . Electrochemical Impedance Study of Schiff Base by Means of Self-assembled Monolayer. Chinese Chemical Letters, 2001, 12(12): 1101-1104.

Metrics
  • PDF Downloads(1)
  • Abstract views(1562)
  • HTML views(24)

通讯作者: 陈斌, bchen63@163.com
  • 1. 

    沈阳化工大学材料科学与工程学院 沈阳 110142

  1. 本站搜索
  2. 百度学术搜索
  3. 万方数据库搜索
  4. CNKI搜索
Address:Zhongguancun North First Street 2,100190 Beijing, PR China Tel: +86-010-82449177-888
Powered By info@rhhz.net

/

DownLoad:  Full-Size Img  PowerPoint
Return