Citation: YUAN Shuai, ZHANG Yue-Jia, HOU Jin-Yan, LIU Qing-Lin, LI Dong-Ping, LI Yong-Xiu. Syntheses, Crystal Structures and Luminescent Properties of Two Schiff Base Complexes[J]. Chinese Journal of Structural Chemistry, ;2016, 35(6): 965-972. doi: 10.14102/j.cnki.0254-5861.2011-0992 shu

Syntheses, Crystal Structures and Luminescent Properties of Two Schiff Base Complexes

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Department of Chemistry, Nanchang University, Nanchang 330031, China

Corresponding author: LI Dong-Ping, LI Yong-Xiu,
Received Date: 29 September 2015
Available Online: 21 January 2016
Fund Project: the Education Department of Jiangxi Province (GJJ12041) (20114BAB213001)

Two new transition metal complexes based on chiral Schiff base ligand, namely Zn(L₁)₂ (1) and Cd(L₂)₂ (2) (L₁= (R,E)-3-(2-hydroxy-3-methoxybenzylideneamino)propane-1,2-diol, L₂= (R,E)-2-((2-hydroxy-1-phenylethylimino)methyl)-6-methoxyphenol), have been synthesized and characterized. Single-crystal X-ray diffractions reveal that both 1 and 2 crystallize in the same monoclinic space group C₂. 1 is four-coordinated, while 2 is six-coordinated. Complexes 1 and 2 show fluorescent emission at 479 and 580 nm, respectively. Moreover, 1 and 2 exhibit selective and sensitive recognition toward Zn²⁺/Cd²⁺ ions in the methanol solution.
- fluorescence,
- Schiff base,
- complex,
- probe
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