Citation:
YUAN Shuai, ZHANG Yue-Jia, HOU Jin-Yan, LIU Qing-Lin, LI Dong-Ping, LI Yong-Xiu. Syntheses, Crystal Structures and Luminescent Properties of Two Schiff Base Complexes[J]. Chinese Journal of Structural Chemistry,
;2016, 35(6): 965-972.
doi:
10.14102/j.cnki.0254-5861.2011-0992
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Two new transition metal complexes based on chiral Schiff base ligand, namely Zn(L1)2 (1) and Cd(L2)2 (2) (L1 = (R,E)-3-(2-hydroxy-3-methoxybenzylideneamino)propane-1,2-diol, L2= (R,E)-2-((2-hydroxy-1-phenylethylimino)methyl)-6-methoxyphenol), have been synthesized and characterized. Single-crystal X-ray diffractions reveal that both 1 and 2 crystallize in the same monoclinic space group C2. 1 is four-coordinated, while 2 is six-coordinated. Complexes 1 and 2 show fluorescent emission at 479 and 580 nm, respectively. Moreover, 1 and 2 exhibit selective and sensitive recognition toward Zn2+/Cd2+ ions in the methanol solution.
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Keywords:
- fluorescence,
- Schiff base,
- complex,
- probe
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