Citation: WANG Ye-Nan, ZHAO Jun, WANG Hai-Bing, XU Guo-Wang, TANG Ping. A Novel 3D Pillar-layered Co(II)-MOF with (4,8)-Connected Topology: Synthesis, Structure and Magnetic Properties[J]. Chinese Journal of Structural Chemistry, ;2016, 35(5): 774-780. doi: 10.14102/j.cnki.0254-5861.2011-0956 shu

A Novel 3D Pillar-layered Co(II)-MOF with (4,8)-Connected Topology: Synthesis, Structure and Magnetic Properties

  • Corresponding author: ZHAO Jun, 
  • Received Date: 24 August 2015
    Available Online: 13 November 2015

    Fund Project:

  • By using "pillaring" strategy, a new Co(II)-MOF, [Co2(abtc)(bimb)2]·2H2O (1, H4abtc = 3,3',5,5'-azobenzenetetracarboxylic acid, bimb = 4,4'-bis(imidazole-1-ylmethyl)bi-phenyl), has been solvothermally synthesized and structurally characterized. The structural determination revealed that 1 features a 3D pillar-layered framework with (4,8)-connected {44.62}{48.620} topology based on dinuclear Co(II)-SBUs. The magnetic investigation shows that the dominant antiferromagnetic coupling is observed in compound 1.
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    1. [1]

      (1) Carlucci, L.; Ciani, G.; Proserpio, D. M. Polycatenation, polythreading and polyknotting in coordination network chemistry. Coord. Chem. Rev. 2003, 246, 247-289.

    2. [2]

      (2) Batten, S. R.; Robson, R. Interpenetrating nets: ordered, periodic entanglement. Angew. Chem. Int. Ed. 1998, 37, 1460-1494.

    3. [3]

      (3) Rosi, N. L.; Eckert, J.; Eddaoudi, M.; Vodak, D. T.; Kim, J.; O’Keeffe, M.; Yaghi, O. M. Hydrogen storage in microporous metal-organic frameworks. Science 2003, 300, 1127-1129.

    4. [4]

      (4) Xu, G.; Yamada, T.; Otsubo, K.; Sakaida, S.; Kitagawa, H. Facile ""modular assembly"" for fast construction of highly oriented crystalline MOF nanofilm. J. Am. Chem. Soc. 2012, 134, 16524-16527.

    5. [5]

      (5) (a) Noro, S. I.; Kitagawa, S.; Kondl, M.; Seki, K. A new methane adsorbent porous coordination polymer [{CuSiF6(4,4'-bipyridine)2}n]. Angew. Chem. Int. Ed. 2000, 39, 2081-2084.

    6. [6]

      (b) Pang, J. D.; Jiang, F. L.; Wu, M. Y.; Liu, C. P.; Su, K. Z.; Lu, W. G.; Yuan, D. Q; Hong, M. C. A porous metal-organic framework with ultrahigh acetylene uptake capacity under ambient conditions. Nat. Commun. 2015, 6, 7575.

    7. [7]

      (c) Xu, G.; Otsubo, K.; Yamada, T.; Sakaida, S.; Kitagawa, H. Superprotonic conductivity in a highly oriented crystalline metal-organic framework nanofilm. J. Am. Chem. Soc. 2013, 135, 7438-7441.

    8. [8]

      (d) Xu, G.; Yang, Q. D.; Wang, F. Y.; Zhang, W. F.; Tang, Y. B.; Wong, N. B.; Lee, S. T.; Zhang, W. J.; Lee, C. S. Core/sheath organic nanocable constructed with a master-slave molecular pair for optically switched memories. Adv. Mater. 2011, 23, 5059-5063.

    9. [9]

      (6) Li, D. S.; Wu, Y. P.; Zhao, J.; Zhang, J.; Lu, J. Y. Metal-organic frameworks based upon non-zeotype 4-connected topology. Coord. Chem. Rev. 2014, 261, 1-27.

    10. [10]

      (7) Li, L. N.; Wang, S. Y.; Chen, T. L.; Sun, Z. H.; Luo, J. H.; Hong, M. C. Solvent-dependent formation of Cd(II) coordination polymers based on a C2-symmetric tricarboxylate linker. Cryst. Growth Des. 2012, 12, 4109-4115.

    11. [11]

      (8) Zhao, J. P.; Han, S. D.; Zhao, R.; Yang, Q.; Chang, Z.; Bu, X. H. Tuning the structure and magnetism of heterometallic sodium(1+)-cobalt(+2) formate coordination polymers by varying the metal ratio and solvents. Inorg. Chem. 2013, 52, 2862-2869.

    12. [12]

      (9) Yang, G. P.; Hou, L.; Luan, X. J.; Wu, B.; Wang, Y. Y. Molecular braids in metal-organic frameworks. Chem. Soc. Rev. 2012, 41, 6992-7000.

    13. [13]

      (10) Bataille, T.; Bracco, S.; Comotti, A.; Costantino, F.; Guerri, A.; Ienco, A.; Marmottni, F. Solvent dependent synthesis of micro-and nano-crystalline phosphinate based 1D tubular MOF: structure and CO2 adsorption selectivity. CrystEngComm. 2012, 14, 7170-7173.

    14. [14]

      (11) O’Keeffe, M.; Yaghi, O. M. Deconstructing the crystal structure of metal-organic frameworks and related materials into their underlying nets. Chem. Rev. 2012, 112, 675-702.

    15. [15]

      (12) Zhao, J.; Wang, Y. N.; Dong, W. W.; Wu, Y. P.; Li, D. S.; Liu, B.; Zhang, Q. C. A new surfactant-introduction strategy for separating the pure single-phase of metal-organic frameworks. Chem. Commun. 2015, 51, 9479-9482.

    16. [16]

      (13) Du, M.; Li, C. P.; Chen, M.; Ge, Z. W.; Wang, X.; Wang, L.; Liu, C. S. Divergent kinetic and thermodynamic hydration of a porous Cu(II) coordination polymer with exclusive CO2 sorption selectivity. J. Am. Chem. Soc. 2014, 136, 10906-10901.

    17. [17]

      (14) Férey, G. Microporous solids: from organically template inorganic skeletons to hybrid frameworks…ecumenism in chemistry. Chem. Mater. 2001, 13, 3084-3098.

    18. [18]

      (15) Wen, Y. H, Sheng, T. L.; Sun, Z. H.; Xue, Z. Z.; Wang, Y. L.; Wang, Y.; Hu, S. M.; Ma, X.; Wu, X. T. A combination of the ""pillaring"" strategy and chiral induction: an approach to prepare homochiral three-dimensional coordination polymers from achiral precursors. Chem. Commun. 2014, 50, 8320-8323.

    19. [19]

      (16) Kondo, M.; Okubo, T.; Asami, A.; Noro, S.; Yoshitomi, T.; Kitagawa, S.; Ishii, T.; Matsuzaka, H.; Seki, K. Rational synthesis of stable channel-like cavities with methane gas adsorption properties: [{Cu2(pzdc)2(L)}n] (pzdc = pyrazine-2,3-dicarboxylate, L = a pillar ligand). Angew. Chem. Int. Ed. 1999, 38, 140-143.

    20. [20]

      (17) Eubank, J. F.; Wojtas, L.; Hight, M. R.; Bousquet, T.; Kravtsov, V. C.; Eddaoudi, M. The next chapter in MOF pillaring strategies: trigonal heterofunctional ligands to access targeted high-connected three dimensional nets, isoreticular platforms. J. Am. Chem. Soc. 2011, 133, 17532-17535.

    21. [21]

      (18) Cao, L. H.; Li, H. Y.; Zang, S. Q.; Hou, H. W.; Mak, T.

    22. [22]

      (4,4)-Connected self-penetrating pillared-layered metal-organic framework based on a nanosized flexible aromatic carboxylic acid ligand. Cryst. Growth Des. 2012, 12, 4299-4301.

    23. [23]

      (19) Jiang, H. L.; Tatsu, Y.; Lu, Z. H.; Xu, Q. Non-, micro-, and mesoporous metal-organic framework isomers: reversible transformation, fluorescence sensing, and large molecule separation. J. Am. Chem. Soc. 2010, 132, 5586-5587.

    24. [24]

      (20) Zhao, J.; Li, D. S.; Ke, X. J.; Liu, B.; Zou, K.; Hu, H. M. Auxiliary ligand-directed structural variation from 2D-3D polythreaded net to 3-fold interpenetrating 3D pillar-layered framework: syntheses, crystal structures and magnetic properties. Dalton Trans. 2012, 41, 2560-2563.

    25. [25]

      (21) Li, D. S.; Wu, Y. P.; Zhang, P.; Du, M.; Zhao, J.; Li, C. P.; Wang, Y. Y. An unprecedented eight-connected self-penetrating coordination framework based on cage-shaped [Pb6(µ4-O)2(O2C)8] clusters. Cryst. Growth Des. 2010, 10, 2037-2040.

    26. [26]

      (22) Zhao, J.; Dong, W. W.; Wu, Y. P.; Wang, Y. N.; Wang, C.; Li, D. S.; Zhang, Q. C. Two (3,6)-connected porous metal-organic frameworks based on linear trinuclear [Co3(COO)6] and paddlewheel dinuclear [Cu2(COO)4] SBUs: gas adsorption, photocatalytic behavior, and magnetic properties. J. Mater. Chem. A 2015, 3, 6962-6969.

    27. [27]

      (23) Li, D. S.; Zhao, J.; Wu, Y. P.; Bai, L.; Du, M. Co5/Co8-cluster-based coordination polymers showing high connected self-penetrating networks: syntheses, crystal structures, and magnetic properties. Inorg. Chem. 2013, 52, 8091-8098.

    28. [28]

      (24) Selwood, P. W. Magnetochemistry, Interscience 1956, New York .

    29. [29]

      (25) Rigaku. CrystalClear version 2.0, RigakuCorporation 2009, Tokyo, Japan.

    30. [30]

      (26) Sheldrick, G. M. SHELXS-97, Program for the Solution of Crystal Structures. University of Göttingen 1997, Germany.

    31. [31]

      (27) Sheldrick, G. M. SHELXL-97, Program for the Refinement of Crystal Structures. University of Göttingen 1997, Germany.

    32. [32]

      (28) Blatov, V. A. Nanocluster analysis of intermetallic structures with the program package. Struct. Chem. 2012, 23, 955-963.

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