Citation:
WANG Ye-Nan, ZHAO Jun, WANG Hai-Bing, XU Guo-Wang, TANG Ping. A Novel 3D Pillar-layered Co(II)-MOF with (4,8)-Connected Topology: Synthesis, Structure and Magnetic Properties[J]. Chinese Journal of Structural Chemistry,
;2016, 35(5): 774-780.
doi:
10.14102/j.cnki.0254-5861.2011-0956
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By using "pillaring" strategy, a new Co(II)-MOF, [Co2(abtc)(bimb)2]·2H2O (1, H4abtc = 3,3',5,5'-azobenzenetetracarboxylic acid, bimb = 4,4'-bis(imidazole-1-ylmethyl)bi-phenyl), has been solvothermally synthesized and structurally characterized. The structural determination revealed that 1 features a 3D pillar-layered framework with (4,8)-connected {44.62}{48.620} topology based on dinuclear Co(II)-SBUs. The magnetic investigation shows that the dominant antiferromagnetic coupling is observed in compound 1.
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Keywords:
- Co(II)-MOF,
- pillar-layered,
- (4,
- 8)-connected,
- magnetic properties
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